Practical Heterocyclic Chemistry

Practical Heterocyclic Chemistry

1st Edition - January 1, 1968

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  • Authors: A. O. Fitton, R. K. Smalley
  • eBook ISBN: 9781483270791

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Description

Practical Heterocyclic Chemistry focuses on experiments, methodologies, processes, reactions, and transformations involved in practical heterocyclic chemistry. The manuscript first offers information on five-membered systems containing one heteroatom and benzoderivatives of five-membered systems containing one heteroatom, including 2,5 – dimethylpyrrole, 2,5 – dimethylthiophen, carbazole, indigotin, and 2-phenylindole. The text then elaborates on five-membered systems containing more than one heteroatom and benzoderivatives of five-membered systems containing more than one heteroatom, as well as benzimidazole, benzotriazole, and 2,4,5 – triphenyloxazole. The publication ponders on six-membered systems containing one heteroatom and benzoderivatives of six-membered systems containing one heteroatom. Discussions focus on 4-nitropyridine N-oxide, 6-chloroquinoline, 2-methyl-4-quinolone, and xanthone. The manuscript is highly recommended for chemists and readers interested in practical heterocyclic chemistry.

Table of Contents


  • Contents

    Introduction

    Preface

    Chapter l: Five-Membered Systems Containing One Heteroatom

    2,4-Diethoxycarbonyl-3,5-dimethylpyrrole

    2,5-Dimethylpyrrole

    4,5 -Diphenyl-2-Methylfuran-3 -Carboxylic Acid

    2,5-Dimethylthiophen

    Chapter 2: Benzoderivatives of Five-Membered Systems Containing One Heteroatom

    Carbazole

    1,2,3,4-Tetrahydrocarbazole

    2,3-Dioxoindoline (Isatin)

    Indigotin (Indigo)

    2-Phenylindole

    2-Benzoylbenzofuran (2-Benzoylcoumarone)

    5-Hydroxycyclo-Octano[b]coumaran

    2 -Methylcoumaran

    5-Chloro-3-Methylbenzo [b] thiophen

    Chapter 3: Five-Membered Systems Containing More Than One Heteroatom

    2,4-Dioxoimidazolidine (Hydantoin)

    4,5-Diphenylimidazole (4,5-diphenylglyoxaline)

    2-Methyl-Δ2-Imidazoline

    3,5-Dimethylpyrazole

    3-Methyl-1-phenyl-5-pyrazolone

    l,3,5-Triphenyl-Δ2-pyrazoline

    3,5-Dimethylisoxazole

    3 -Phenyl-5-isoxazolone

    4-Benzylidene-2-phenyl-5-oxazolone

    Cyclohexanespiro-2'-(l',3'-oxazolidine)

    2-Methyl-Δ2-oxazoline

    2,4,5-Triphenyloxazole

    p-Chlorophenylsydnone

    3,4-Dimethyl-l,2,5-oxadiazole (3,4-dimethylfurazan)

    2,5-Diphenyl-l,3,4-oxadiazole

    2,4-Dimethylthiazole

    2-Methyl-Δ2-thiazoline

    Chapter 4: Benzoderivatives of Five-membered Systems Containing More Than One Heteroatom

    Benzimidazole

    1,2-Dihydro-2-oxobenzimidazole (benzimidazolone)

    6-Nitroindazole

    l-Aminobenzotriazole

    Benzotriazole

    l-(p-Nitrophenyl)-4,5,6,7-tetrahydrobenzotriazole

    3-Methyl-5-nitrobenzisoxazole

    3 -Phenylbenzo-2,1 -isoxazole (3-phenylanthranil)

    2-Methylbenzoxazole

    2-Methyl-6-nitrobenzoxazole

    Benzo-2,1,3-oxadiazole 1-oxide (benzofuroxan)

    5(6)-Chlorobenzo-2,1,3 -oxadiazole 1-oxide [5(6)-chlorobenzofuroxan]

    2-Phenylbenzo-1,3-diaza-2-borole

    2-Phenylbenzo-l,3-diaza-2-phosphole 2-oxide

    2-Phenylbenzo-l,3-oxaza-2-borole

    2-Phenylbenzothiazole

    Benzo-2,1,3 -thiadiazole

    Chapter 5: Six-membered Systems Containing One Heteroatom

    3-Chloro-2,6-dimethylpyridine

    3,5-Diethoxycarbonyl-2,6-dimethyl-4-(m-nitrophenyl)pyridine

    4-Nitropyridine N-oxide

    3-Cyano-4,6-dimethyl-2-pyridone: Method 1

    3-Cyano-4,6-dimethyl-2-pyridone: Method 2

    3,5-Diacetyl-l,4-dihydro-2,4,6-trimethylpyridine

    4-Pyridone-2,6-dicarboxylic acid (chelidamic acid)

    3-Acetyl-3,4-dihydro-6-methyl-4-oxo-α-pyrone (dehydroacetic acid)

    2,6-Dimethyl-y-pyrone

    6-Isobutenyl-4-methyl-a-pyrone

    Chapter 6: Benzoderivatives of Six-membered Systems Containing One Heteroatom

    3 -Methyl-1-phenylisoquinoline

    6-Chloroquinoline

    4-Methyl-2-phenylquinoline

    2,4,6-Trimethylquinoline

    2-Methyl-4-quinolone

    4-Methyl-2-quinolone

    4-Phenyl-2-quinolone

    9-Acridone

    Phenanthridine

    6-Phenanthridone

    Chromone-2-carboxylic Acid

    2-Methyl-5,6,7,8-tetrahydrochromone

    7-Hydroxy-4-methylcoumarin (4-methylumbelliferone)

    Benzo [f]chroman-4-one

    Benzo [f]chromone

    Xanthone

    Chapter 7: Six-membered Systems Containing More Than One Heteroatom

    4-Cyano-2,3-dihydro-5,6-diphenyl-3-oxopyridazine

    2,4-Dioxo-6-methyl-l,2,3,4-tetrahydropyrimidine (6 -methyluracil)

    Hexahydro-2,4,6-trioxopyrimidine (barbituric acid)

    2,5 -Dioxopiperazine

    Pyrazine-2,3-dicarboxylic acid

    Hexahydro-1,3,5-tri-p-tolyl-s-triazine

    Chapter 8: Benzoderivatives of Six-membered Systems Containing More Than One Heteroatom

    4-Cinnolone

    Quinazoline

    3 - Amino-3,4-dihydro-2-methyl-4-oxoquinazoline

    3,4-Dihydro-1-hydroxy-4-oxophthalazine

    3,4-Dihydro-1 -methyl-4-oxophthalazine

    Dibenzo [a,c]phenazine

    3,4-Dihydro-4-oxo-l ,2,3-benzotriazine: Method 1

    3,4-Dihydro-4-oxo-1,2,3 -benzotriazine: Method 2

    2-Ethy1-4-0X0-3,1 -benzoxazine

    2,3 -Dihydro-3-oxo-1,4-benzoxazine (benzo-3-morpholone): Method 1

    2,3 -Dihydro-3-oxo-1,4-benzoxazine (benzo-3-morpholone): Method 2

    2,4-Dinitrophenoxazine

    Phenothiazine

    2-Oxo-l,4-benzodioxan

    Phenoxathiin

    Chapter 9: Miscellaneous Systems

    Cyclohexa-2,5-diene-4-one-spiro-2'-oxetano[3',4']cyclo-octane

    4,6-Dinitrobenzimidazo [1,2-α]pyridine

    2-Phenylimidazo[l,2-α]pyridine

    2,3,4,5-Tetrahydropyrido[l,2-a]-benzimidazole

    l,4-Dihydro-endo-l,4-oxanaphthalene

    Bibliography

    Subject Index

Product details

  • No. of pages: 166
  • Language: English
  • Copyright: © Academic Press 1968
  • Published: January 1, 1968
  • Imprint: Academic Press
  • eBook ISBN: 9781483270791

About the Authors

A. O. Fitton

R. K. Smalley

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