Practical Heterocyclic Chemistry - 1st Edition - ISBN: 9781483232478, 9781483270791

Practical Heterocyclic Chemistry

1st Edition

Authors: A. O. Fitton R. K. Smalley
eBook ISBN: 9781483270791
Imprint: Academic Press
Published Date: 1st January 1968
Page Count: 166
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Description

Practical Heterocyclic Chemistry focuses on experiments, methodologies, processes, reactions, and transformations involved in practical heterocyclic chemistry.
The manuscript first offers information on five-membered systems containing one heteroatom and benzoderivatives of five-membered systems containing one heteroatom, including 2,5 – dimethylpyrrole, 2,5 – dimethylthiophen, carbazole, indigotin, and 2-phenylindole. The text then elaborates on five-membered systems containing more than one heteroatom and benzoderivatives of five-membered systems containing more than one heteroatom, as well as benzimidazole, benzotriazole, and 2,4,5 – triphenyloxazole. The publication ponders on six-membered systems containing one heteroatom and benzoderivatives of six-membered systems containing one heteroatom. Discussions focus on 4-nitropyridine N-oxide, 6-chloroquinoline, 2-methyl-4-quinolone, and xanthone.
The manuscript is highly recommended for chemists and readers interested in practical heterocyclic chemistry.

Table of Contents


Contents

Introduction

Preface

Chapter l: Five-Membered Systems Containing One Heteroatom

2,4-Diethoxycarbonyl-3,5-dimethylpyrrole

2,5-Dimethylpyrrole

4,5 -Diphenyl-2-Methylfuran-3 -Carboxylic Acid

2,5-Dimethylthiophen

Chapter 2: Benzoderivatives of Five-Membered Systems Containing One Heteroatom

Carbazole

1,2,3,4-Tetrahydrocarbazole

2,3-Dioxoindoline (Isatin)

Indigotin (Indigo)

2-Phenylindole

2-Benzoylbenzofuran (2-Benzoylcoumarone)

5-Hydroxycyclo-Octano[b]coumaran

2 -Methylcoumaran

5-Chloro-3-Methylbenzo [b] thiophen

Chapter 3: Five-Membered Systems Containing More Than One Heteroatom

2,4-Dioxoimidazolidine (Hydantoin)

4,5-Diphenylimidazole (4,5-diphenylglyoxaline)

2-Methyl-Δ2-Imidazoline

3,5-Dimethylpyrazole

3-Methyl-1-phenyl-5-pyrazolone

l,3,5-Triphenyl-Δ2-pyrazoline

3,5-Dimethylisoxazole

3 -Phenyl-5-isoxazolone

4-Benzylidene-2-phenyl-5-oxazolone

Cyclohexanespiro-2'-(l',3'-oxazolidine)

2-Methyl-Δ2-oxazoline

2,4,5-Triphenyloxazole

p-Chlorophenylsydnone

3,4-Dimethyl-l,2,5-oxadiazole (3,4-dimethylfurazan)

2,5-Diphenyl-l,3,4-oxadiazole

2,4-Dimethylthiazole

2-Methyl-Δ2-thiazoline

Chapter 4: Benzoderivatives of Five-membered Systems Containing More Than One Heteroatom

Benzimidazole

1,2-Dihydro-2-oxobenzimidazole (benzimidazolone)

6-Nitroindazole

l-Aminobenzotriazole

Benzotriazole

l-(p-Nitrophenyl)-4,5,6,7-tetrahydrobenzotriazole

3-Methyl-5-nitrobenzisoxazole

3 -Phenylbenzo-2,1 -isoxazole (3-phenylanthranil)

2-Methylbenzoxazole

2-Methyl-6-nitrobenzoxazole

Benzo-2,1,3-oxadiazole 1-oxide (benzofuroxan)

5(6)-Chlorobenzo-2,1,3 -oxadiazole 1-oxide [5(6)-chlorobenzofuroxan]

2-Phenylbenzo-1,3-diaza-2-borole

2-Phenylbenzo-l,3-diaza-2-phosphole 2-oxide

2-Phenylbenzo-l,3-oxaza-2-borole

2-Phenylbenzothiazole

Benzo-2,1,3 -thiadiazole

Chapter 5: Six-membered Systems Containing One Heteroatom

3-Chloro-2,6-dimethylpyridine

3,5-Diethoxycarbonyl-2,6-dimethyl-4-(m-nitrophenyl)pyridine

4-Nitropyridine N-oxide

3-Cyano-4,6-dimethyl-2-pyridone: Method 1

3-Cyano-4,6-dimethyl-2-pyridone: Method 2

3,5-Diacetyl-l,4-dihydro-2,4,6-trimethylpyridine

4-Pyridone-2,6-dicarboxylic acid (chelidamic acid)

3-Acetyl-3,4-dihydro-6-methyl-4-oxo-α-pyrone (dehydroacetic acid)

2,6-Dimethyl-y-pyrone

6-Isobutenyl-4-methyl-a-pyrone

Chapter 6: Benzoderivatives of Six-membered Systems Containing One Heteroatom

3 -Methyl-1-phenylisoquinoline

6-Chloroquinoline

4-Methyl-2-phenylquinoline

2,4,6-Trimethylquinoline

2-Methyl-4-quinolone

4-Methyl-2-quinolone

4-Phenyl-2-quinolone

9-Acridone

Phenanthridine

6-Phenanthridone

Chromone-2-carboxylic Acid

2-Methyl-5,6,7,8-tetrahydrochromone

7-Hydroxy-4-methylcoumarin (4-methylumbelliferone)

Benzo [f]chroman-4-one

Benzo [f]chromone

Xanthone

Chapter 7: Six-membered Systems Containing More Than One Heteroatom

4-Cyano-2,3-dihydro-5,6-diphenyl-3-oxopyridazine

2,4-Dioxo-6-methyl-l,2,3,4-tetrahydropyrimidine (6 -methyluracil)

Hexahydro-2,4,6-trioxopyrimidine (barbituric acid)

2,5 -Dioxopiperazine

Pyrazine-2,3-dicarboxylic acid

Hexahydro-1,3,5-tri-p-tolyl-s-triazine

Chapter 8: Benzoderivatives of Six-membered Systems Containing More Than One Heteroatom

4-Cinnolone

Quinazoline

3 - Amino-3,4-dihydro-2-methyl-4-oxoquinazoline

3,4-Dihydro-1-hydroxy-4-oxophthalazine

3,4-Dihydro-1 -methyl-4-oxophthalazine

Dibenzo [a,c]phenazine

3,4-Dihydro-4-oxo-l ,2,3-benzotriazine: Method 1

3,4-Dihydro-4-oxo-1,2,3 -benzotriazine: Method 2

2-Ethy1-4-0X0-3,1 -benzoxazine

2,3 -Dihydro-3-oxo-1,4-benzoxazine (benzo-3-morpholone): Method 1

2,3 -Dihydro-3-oxo-1,4-benzoxazine (benzo-3-morpholone): Method 2

2,4-Dinitrophenoxazine

Phenothiazine

2-Oxo-l,4-benzodioxan

Phenoxathiin

Chapter 9: Miscellaneous Systems

Cyclohexa-2,5-diene-4-one-spiro-2'-oxetano[3',4']cyclo-octane

4,6-Dinitrobenzimidazo [1,2-α]pyridine

2-Phenylimidazo[l,2-α]pyridine

2,3,4,5-Tetrahydropyrido[l,2-a]-benzimidazole

l,4-Dihydro-endo-l,4-oxanaphthalene

Bibliography

Subject Index

Details

No. of pages:
166
Language:
English
Copyright:
© Academic Press 1968
Published:
Imprint:
Academic Press
eBook ISBN:
9781483270791

About the Author

A. O. Fitton

R. K. Smalley

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