Physical Organic Chemistry — 3 - 1st Edition - ISBN: 9780080211978, 9781483280585

Physical Organic Chemistry — 3

1st Edition

Plenary Lectures Presented at the Third IUPAC Conference on Physical Organic Chemistry, Montpellier, France, 6 - 10 September, 1976

Editors: A. Fruchier
eBook ISBN: 9781483280585
Imprint: Pergamon
Published Date: 1st January 1977
Page Count: 112
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9780080211978 Physical Organic Chemistry - 3 (Montpellier, 1976) is a collection of plenary lectures presented at the Third IUPAC Conference on Physical Organic Chemistry, held in Montpellier, France on September 6-10, 1976.

This book is composed of nine chapters and begins with an examination of the concept of absolute equilibrium acidity scale and its application to structure-activity relationship evaluation. The succeeding chapters deal with micellar catalysis and inhibition, as well as the application of quantum chemical ab initio methods to CO, CS, and related double bonds. These topics are followed by discussions of the hydrolysis of acetals and hemiacetals; the mechanisms and catalysis in vinyl ester hydrolysis; and the acid-base catalysis of carbonyl and acyl group reactions. The final chapters explore the strain energy modeling of simple and crowded aliphatic ketones. These chapters also look into the stereochemistry of dissolving metal reduction of ketones and the hydrolysis of phosphate esters.

This book will be of value to physical chemists and physical chemistry researchers and students.

Table of Contents

Equilibrium of Carbon Acids

Micellar Catalysis and Inhibition

Quantum Chemical Studies of CO, CS and Related Double Bonds

Some Mechanistic Studies on the Hydrolysis of Acetals and Hemiacetals

Mechanisms and Catalysis in Vinyl Ester Hydrolysis

General Acid-base Catalysis of Carbonyl and Acyl Group Reactions

Strain Energy Modeling of Simple and Crowded Aliphatic Ketones: Spectroscopic Properties

Stereochemistry of Dissolving Metal Reduction of Ketones

The Hydrolysis of Phosphate Esters


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© Pergamon 1977
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About the Editor

A. Fruchier

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