Physical Methods in Heterocyclic Chemistry

Physical Methods in Heterocyclic Chemistry

Volume IV

1st Edition - January 28, 1971

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  • Editor: A. R. Katritzky
  • eBook ISBN: 9781483273198

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Description

Physical Methods in Heterocyclic Chemistry, Volume IV, discusses the application of physical methods to organic chemistry, and in particular to heterocyclic chemistry. Since the publication in 1963 of the first two volumes of this treatise, the application of physical methods to organic chemistry, and in particular to heterocyclic chemistry, has proceeded apace. The importance of physical methods to structure determination and to the understanding of inter- and intramolecular interactions has increased no less than the flood of new work. Heterocyclic chemists are thus faced with the necessity of having more to comprehend for the efficient execution of their own work. The present volume includes chapters on electric dipole moments and heteroaromatic reactivity, which originally appeared in Volume I, and chapters on nuclear quadrupole resonance, nuclear magnetic resonance, and infrared spectra, which originally formed part of Volume II. Also included is one new topic: dielectric absorption.

Table of Contents


  • Contributors to Volume IV

    Preface

    Preface to Volumes I and II

    Contents of Other Volumes

    1 Dielectric Absorption of Heterocyclic Molecules

    I. Introduction

    II. Factors Influencing the Relaxation Time

    III. Parameters Evaluated from Dielectric Data

    IV. Application of Dielectric Data to Heterocyclic Systems

    2 Nuclear Quadrupole Coupling Constants

    I. General Introduction

    II. Results

    III. Microwave Spectra

    3 Heteroaromatic Reactivity

    I. Introduction

    II. Compounds with One Six-Membered Heteroaromatic Ring

    III. Compounds with One Five-Membered Heteroaromatic Ring

    IV. Application of Molecular Orbital Theory

    V. Application of Linear Free Energy Relationships

    Addendum

    4 Nuclear Magnetic Resonance Spectra

    I. General Introduction

    II. Small Rings

    III. Heteroaromatic Compounds with Five-Membered Rings

    IV. Compounds with Six-Membered Heterocyclic Rings

    5 Recent Applications of Electric Dipole Moments to Heteroeyelic Systems

    I. Introduction

    II. Recent Methods Employed in Dipole Moment Measurement

    III. Theoretical Calculation of Dipole Moments

    IV. Application of Theoretical Dipole Moment Studies to the Elucidation of Molecular Behavior and Structure

    V. Application of Experimental Dipole Moments

    VI. Molecular Interaction

    VII. Conclusion

    6 Infrared Spectroscopy of Heterocycles

    I. Introduction

    II. Small Rings

    III. Five-Membered Rings with One Heteroatom

    IV . Five-Membered Rings with Two or More Heteroatoms

    V. Six-Membered Rings; Nonaromatic, without Carbonyl Groups

    VI. Six-Membered Rings with Carbonyl Groups

    VII. Aromatic Six-Membered Rings without Carbonyl Groups

    VIII. Seven-Membered and Larger Rings

    IX. Compounds Containing Heteroatoms Other than Oxygen, Nitrogen, and Sulfur

    X. Substituent Vibrations

    Author Index

    Subject Index

Product details

  • No. of pages: 496
  • Language: English
  • Copyright: © Academic Press 1971
  • Published: January 28, 1971
  • Imprint: Academic Press
  • eBook ISBN: 9781483273198

About the Editor

A. R. Katritzky

Affiliations and Expertise

School of Chemical Sciences, University qf East Anglia, Norwich, England

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