Physical Methods in Heterocyclic Chemistry V6

Physical Methods in Heterocyclic Chemistry V6

1st Edition - January 28, 1974

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  • Editor: A Katritzky
  • eBook ISBN: 9780323156141

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Physical Methods in Heterocyclic Chemistry, Volume VI discusses several topics including bond energies, electron-spin resonance, microwave spectroscopy, and photoelectron spectroscopy. This book explores the thermochemical applications to heterocyclic chemistry. Comprised of five chapters, this volume starts with an overview of the technique of photoelectron spectroscopy. This text then illustrates the various potentialities of photoelectron spectroscopy by discussing four examples taken from the field of heterocyclic compounds. Other chapters determine the magnitudes as well as the lines of action of electric dipole moments in the molecular framework. This book discusses as well the emission of light by individual molecules in solution, particularly heterocyclic molecules, which are electronically excited as a result of the absorption of visible or ultraviolet light. The final chapter deals with the aspects of heats of combustion, heats of hydrogenation, heats of formation, and bond energies. Heterocyclic chemists, chemists, biochemists, molecular biologists, and researchers will find this book extremely useful.

Table of Contents

  • Contributors to Volume VI


    Preface to Volumes I and II

    Preface to Volumes III, IV, and V

    Contents of Other Volumes

    ∙1∙ UV Photoelectron Spectra of Heterocyclic Compounds

    I. Method

    II. Application of PE Spectroscopy

    ∙2∙ Microwave Spectroscopy of Heterocyclic Molecules

    I. Introduction

    II. Three-Membered Rings

    III. Four-Membered Rings

    IV. Five-Membered Rings with Aromatic Character

    V. Partially and Fully Saturated Five-Membered Rings

    VI. Aromatic Six-Membered Rings

    VII. Partially and Fully Saturated Six-Membered Rings

    VIII. Future Developments

    ∙3∙ ESR Spectroscopy of Heterocyclic Radicals

    I.ESR Parameters

    II. Heteroalicyclic Radicals

    III. Heteroaromatic Radicals

    IV. Miscellaneous Radicals

    V. Appendix

    ∙4∙ Fluorescence and Phosphorescence of Heterocyclic Molecules

    I. Introduction

    II. Photophysical Processes in Isolated Electronically Excited Molecules

    III. The Effect of Molecular Structure on Fluorescence and Phosphorescence Spectra

    IV. Solvent Influences on Fluorescence and Phosphorescence Spectra

    V. The Influence of Acidity or Basicity on Molecular Luminescence

    ∙5∙ Some Applications of Thermochemistry to Heterocyclic Chemistry

    I. Introduction

    II. Enthalpies of Formation

    III. Chemical Equilibration

    IV. Ring Strain in Heterocyclic Compounds

    V. Resonance Energies of Heterocyclic Compounds

    Author Index

    Cumulative Author Index

    Cumulative Subject Index

Product details

  • No. of pages: 318
  • Language: English
  • Copyright: © Academic Press 1974
  • Published: January 28, 1974
  • Imprint: Academic Press
  • eBook ISBN: 9780323156141

About the Editor

A Katritzky

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