Physical Methods in Heterocyclic Chemistry V6 - 1st Edition - ISBN: 9780124011069, 9780323156141

Physical Methods in Heterocyclic Chemistry V6

1st Edition

Editors: A Katritzky
eBook ISBN: 9780323156141
Imprint: Academic Press
Published Date: 28th January 1974
Page Count: 318
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Description

Physical Methods in Heterocyclic Chemistry, Volume VI discusses several topics including bond energies, electron-spin resonance, microwave spectroscopy, and photoelectron spectroscopy. This book explores the thermochemical applications to heterocyclic chemistry.
Comprised of five chapters, this volume starts with an overview of the technique of photoelectron spectroscopy. This text then illustrates the various potentialities of photoelectron spectroscopy by discussing four examples taken from the field of heterocyclic compounds. Other chapters determine the magnitudes as well as the lines of action of electric dipole moments in the molecular framework. This book discusses as well the emission of light by individual molecules in solution, particularly heterocyclic molecules, which are electronically excited as a result of the absorption of visible or ultraviolet light. The final chapter deals with the aspects of heats of combustion, heats of hydrogenation, heats of formation, and bond energies. Heterocyclic chemists, chemists, biochemists, molecular biologists, and researchers will find this book extremely useful.

Table of Contents


Contributors to Volume VI

Preface

Preface to Volumes I and II

Preface to Volumes III, IV, and V

Contents of Other Volumes

∙1∙ UV Photoelectron Spectra of Heterocyclic Compounds

I. Method

II. Application of PE Spectroscopy

∙2∙ Microwave Spectroscopy of Heterocyclic Molecules

I. Introduction

II. Three-Membered Rings

III. Four-Membered Rings

IV. Five-Membered Rings with Aromatic Character

V. Partially and Fully Saturated Five-Membered Rings

VI. Aromatic Six-Membered Rings

VII. Partially and Fully Saturated Six-Membered Rings

VIII. Future Developments

∙3∙ ESR Spectroscopy of Heterocyclic Radicals

I.ESR Parameters

II. Heteroalicyclic Radicals

III. Heteroaromatic Radicals

IV. Miscellaneous Radicals

V. Appendix

∙4∙ Fluorescence and Phosphorescence of Heterocyclic Molecules

I. Introduction

II. Photophysical Processes in Isolated Electronically Excited Molecules

III. The Effect of Molecular Structure on Fluorescence and Phosphorescence Spectra

IV. Solvent Influences on Fluorescence and Phosphorescence Spectra

V. The Influence of Acidity or Basicity on Molecular Luminescence

∙5∙ Some Applications of Thermochemistry to Heterocyclic Chemistry

I. Introduction

II. Enthalpies of Formation

III. Chemical Equilibration

IV. Ring Strain in Heterocyclic Compounds

V. Resonance Energies of Heterocyclic Compounds

Author Index

Cumulative Author Index

Cumulative Subject Index

Details

No. of pages:
318
Language:
English
Copyright:
© Academic Press 1974
Published:
Imprint:
Academic Press
eBook ISBN:
9780323156141

About the Editor

A Katritzky

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