Organolithiums: Selectivity for Synthesis, Volume 23

1st Edition

Authors: Jonathan Clayden
Hardcover ISBN: 9780080432625
eBook ISBN: 9780080538167
Imprint: Pergamon
Published Date: 1st July 2002
Page Count: 400
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Table of Contents

  • Foreword
  • Acknowledgements
    • Publisher Summary
  • Abbreviations
    • Publisher Summary
  • Chapter 1: Introduction
    • 1.1 Scope and Overview
    • 1.2 Organolithiums in solution
  • Chapter 2: Regioselective Synthesis of Organolithiums by Deprotonation
    • 2.1 General points
    • 2.2 Lithiation α to heteroatoms
    • 2.3 Ortholithiation
    • 2.4 Lateral Lithiation
    • 2.5 Remote lithiation, and β-lithiation of non-aromatic compounds
    • 2.6 Superbases435
    • 2.7 Cooperation, competition and regioselectivity
  • Chapter 3: Regioselective Synthesis of Organolithiums by X-Li Exchange
    • 3.1 Halogen-lithium exchange
    • 3.2 Tin-lithium exchange
    • 3.3 Chalcogen-lithium exchange
    • 3.4 Phosphorus-lithium exchange
  • Chapter 4: Regioselective Synthesis of Organolithiums by C–X Reduction
    • 4.1 Reductive lithiation of alkyl and aryl halides
    • 4.2 Reductive lithiation of C–O bonds9
    • 4.3 Reductive lithiation of C–N bonds
    • 4.4 Reductive lithiation of C–S bonds
    • 4.5 Reductive lithiation of C–C bonds and π-bonds
  • Chapter 5: Stereoselective and Stereospecific Synthesis of Organolithiums
    • 5.1 Configurational Stability of Organolithiums
    • 5.2 Stereospecific synthesis of organolithiums by X-Li exchange
    • 5.3 Diastereoselective deprotonation
    • 5.4 Enantioselective Deprotonation
  • Chapter 6: Stereoselective and Stereospecific Substitution Reactions of Organolithiums
    • 6.1 Stereospecific reactions of organolithium compounds
    • 6.2 Stereoselective substitution in the presence of chiral ligands
  • Chapter 7: Regio- and Stereoselective Addition Reactions of Organolithiums
    • 7.1 Intermolecular ad

Details

No. of pages:
400
Language:
English
Copyright:
© Pergamon 2002
Published:
Imprint:
Pergamon
eBook ISBN:
9780080538167
Hardcover ISBN:
9780080432625

About the Authors

Jonathan Clayden Author

Affiliations and Expertise

Department of Chemistry University of Manchester Manchester UK