Organic Synthesis

Organic Synthesis

First International Conference on Organic Synthesis

1st Edition - January 1, 1975

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  • Editors: A. Bruylants, L. Ghosez, H.G. Viehe
  • eBook ISBN: 9781483156170

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Description

Organic Synthesis is a collection of papers dealing with synthetic tools, the effect of pressure on the electronic states of organic solids, and some novel approaches to alkylations. Some papers explain the cyclopropanation of silyl enol ethers and the two-phase reactions in the chemistry of carbanions and halocarbenes as useful tools in organic synthesis. One paper investigates the "biogenetic-type" synthesis of the bicyclic penicillin-cephalosporin antibiotics from an acyclic tripeptide equivalent. Another paper explains the advantages of the two-phase system to generate trihalomethylanions and dihalocarbenes as it allows the investigator to carry out all the reactions typical for these species easily. The system also readily applies to the reactions of some carbanions with aromatic nitrocompounds. Thallium(III) nitrate (TTN) can be used as an oxidant in organic synthesis; reactions that follow it use include the oxidations and oxidative rearrangements of olefins, acetylenes, ketones and compounds containing carbon-nitrogen double bonds. Another paper presents some examples that use singlet oxygen in synthetic organic chemistry. This collection is useful for researchers, technicians, and scientists whose works involve organic chemistry, analytical chemistry, and other related fields of chemistry, such as physical chemistry and inorganic chemistry.

Table of Contents


  • Opening Remarks

    The Cyclopropanation of Silyl Enol Ethers. A Powerful Synthetic Tool

    Chiral Recognition in Complexation of Guests by Designed Host Molecules

    The Importance of Conformation of the Tetrahedral Intermediate in the Hydrolysis of Esters and Amides

    The Effect of Pressure on the Electronic States of Organic Solids

    Asymmetric Catalysis by Chiral Rhodium Complexes in Hydrogenation and Hydrosilylation Reactions

    Synthetic Studies in the Field of Natural Products

    Two-Phase Reactions in the Chemistry of Carbanions and Halocarbenes. A Useful Tool in Organic Synthesis

    Applications of Thallium(III) nitrate (TTN) to organic synthesis

    Singlet Oxygen: A Reagent in Organic Synthesis

    The Use of Polymeric Reagents in Organic Synthesis

    Industrial Synthesis of Terpene Compounds

    The Use of Kinetically Generated Unstable Enolate Ions in the Regiospecific Formation of Carbon-Carbon Bonds. Specific Applications to Annelation Processes

    Novel Approaches to Alkylations

Product details

  • No. of pages: 278
  • Language: English
  • Copyright: © Butterworth-Heinemann 1975
  • Published: January 1, 1975
  • Imprint: Butterworth-Heinemann
  • eBook ISBN: 9781483156170

About the Editors

A. Bruylants

L. Ghosez

H.G. Viehe

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