Organic Syntheses with Noble Metal Catalysts

Organic Syntheses with Noble Metal Catalysts

1st Edition - January 1, 1973

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  • Author: Paul N. Rylander
  • eBook ISBN: 9780323162616

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Description

Organic Chemistry, Volume 28: Organic Syntheses with Noble Metal Catalysts provides information pertinent to the catalysis by noble metals, which is presented in a form as to be of use to those interested in organic synthesis. This book discusses the mechanistic aspects of reactions. Organized into nine chapters, this volume begins with an overview of catalytic dehydrogenation over platinum metals, which provides a convenient method for synthesis of organic compounds. This text then examines the mechanisms and kinetics of homogeneous hydrogenation. Other chapters consider the oxidation of organic compounds in the presence of noble metal catalysts that may affect a variety of changes, including introduction of alcohol, epoxide, carbonyl, and halogen functions into the molecule. This book discusses as well the differences between osmium tetroxide and ruthenium tetroxide in their reactions with organic compounds. The final chapter deals with noble metal catalysts. This book is a valuable resource for synthetic organic chemists.

Table of Contents


  • Preface

    Chapter 1. Dehydrogenation

    Catalysts

    Experimental Procedures

    Aromatization

    Formation of New Bonds

    Dehydrogenation of Ketones to Phenols

    Dealkylation and Isomerization

    Hydrogen Exchange Processes

    Loss of Functional Groups

    References

    Chapter 2. Homogeneous Hydrogenation

    Catalysts

    Olefins

    Sulfur Compounds

    Labeling

    Diminished Disproportionation

    Asymmetric Hydrogenations

    Miscellaneous

    References

    Chapter 3. Oxidation

    Oxidation of Olefins in Aqueous Systems

    Oxidation of Olefins in Nonaqueous Systems

    Oxidation of Complex Olefins

    Oxidative Coupling

    Acetoxylation

    Oxidation of Alkylaromatics

    Oxidation of Alcohols

    Oxidative Dehydrogenation

    N-Dealkylation

    References

    Chapter 4. Osmium and Ruthenium Tetroxides as Oxidation Catalysts

    Osmium Tetroxide

    Metal Chlorates as Oxidants

    Peroxides as Oxidants

    Air as Oxidant

    Periodate as Oxidant

    Hypochlorite as Oxidant

    Hexacyanoferrate as Oxidant

    Disproportionation

    Ruthenium Tetroxide

    Oxidation of Aromatics

    Oxidation of Alcohols

    Oxidation of Olefins

    Oxidation of Acetylenes

    Ruthenium Tetroxide-Sodium Hypochlorite

    References

    Chapter 5. Isomerization

    Double-Bond Migration

    Configurational Changes

    Skeletal Isomerization

    Aromatizations

    Valence Isomerization

    References

    Chapter 6. Oligomerizations, Telomerizations, and Condensations

    Oligomerization of Olefins

    Oligomerization of Substituted Olefins

    Telomerization of Olefins

    Oligomerization of Dienes

    Addition of Dienes to Olefins

    Oligomerization of Acetylenes

    Telomerization of Dienes

    Condensations

    References

    Chapter 7. Carbonylation and Hydroformylation

    Catalysts

    Acetylenes

    Amines

    Azides

    Alcohols

    Halogen Compounds

    Olefins

    Carbonylation of Dienes

    Carbonylation of Olefinic Compounds

    Nitro Compounds

    References

    Chapter 8. Decarbonylation and Desulfonylation

    Decarbonylation

    Aliphatic Aldehydes

    Unsaturated Aldehydes

    Aromatic Aldehydes

    Acid Halides

    Aroyl Cyanides

    Ketones

    Anhydrides

    Alcohols

    Ethers

    Esters and Acids

    β-Ketoamides

    Formate Esters

    Desulfonylation

    References

    Chapter 9. Silicon Chemistry

    Catalysts for Hydrosilylation of Olefins

    Addition of Silanes to Olefins

    Addition of Silanes to Diolefins

    Addition of Silanes to Substituted Olefins

    Hydrosilylation of Acetylenes

    Addition to the Nitroso Function

    Addition of Aminosilicon Hydrides to Olefins

    Dehydrogenation

    Acid Halides

    Carbon-Silicon Bond Cleavage

    References

    Author Index

    Subject Index

Product details

  • No. of pages: 344
  • Language: English
  • Copyright: © Academic Press 1973
  • Published: January 1, 1973
  • Imprint: Academic Press
  • eBook ISBN: 9780323162616

About the Author

Paul N. Rylander

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