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Organic Chemistry, Volume 28: Organic Syntheses with Noble Metal Catalysts provides information pertinent to the catalysis by noble metals, which is presented in a form as to be of use to those interested in organic synthesis. This book discusses the mechanistic aspects of reactions.
Organized into nine chapters, this volume begins with an overview of catalytic dehydrogenation over platinum metals, which provides a convenient method for synthesis of organic compounds. This text then examines the mechanisms and kinetics of homogeneous hydrogenation. Other chapters consider the oxidation of organic compounds in the presence of noble metal catalysts that may affect a variety of changes, including introduction of alcohol, epoxide, carbonyl, and halogen functions into the molecule. This book discusses as well the differences between osmium tetroxide and ruthenium tetroxide in their reactions with organic compounds. The final chapter deals with noble metal catalysts.
This book is a valuable resource for synthetic organic chemists.
Chapter 1. Dehydrogenation
Formation of New Bonds
Dehydrogenation of Ketones to Phenols
Dealkylation and Isomerization
Hydrogen Exchange Processes
Loss of Functional Groups
Chapter 2. Homogeneous Hydrogenation
Chapter 3. Oxidation
Oxidation of Olefins in Aqueous Systems
Oxidation of Olefins in Nonaqueous Systems
Oxidation of Complex Olefins
Oxidation of Alkylaromatics
Oxidation of Alcohols
Chapter 4. Osmium and Ruthenium Tetroxides as Oxidation Catalysts
Metal Chlorates as Oxidants
Peroxides as Oxidants
Air as Oxidant
Periodate as Oxidant
Hypochlorite as Oxidant
Hexacyanoferrate as Oxidant
Oxidation of Aromatics
Oxidation of Alcohols
Oxidation of Olefins
Oxidation of Acetylenes
Ruthenium Tetroxide-Sodium Hypochlorite
Chapter 5. Isomerization
Chapter 6. Oligomerizations, Telomerizations, and Condensations
Oligomerization of Olefins
Oligomerization of Substituted Olefins
Telomerization of Olefins
Oligomerization of Dienes
Addition of Dienes to Olefins
Oligomerization of Acetylenes
Telomerization of Dienes
Chapter 7. Carbonylation and Hydroformylation
Carbonylation of Dienes
Carbonylation of Olefinic Compounds
Chapter 8. Decarbonylation and Desulfonylation
Esters and Acids
Chapter 9. Silicon Chemistry
Catalysts for Hydrosilylation of Olefins
Addition of Silanes to Olefins
Addition of Silanes to Diolefins
Addition of Silanes to Substituted Olefins
Hydrosilylation of Acetylenes
Addition to the Nitroso Function
Addition of Aminosilicon Hydrides to Olefins
Carbon-Silicon Bond Cleavage
- No. of pages:
- © Academic Press 1973
- 28th January 1973
- Academic Press
- eBook ISBN:
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