Organic Functional Group Analysis

Organic Functional Group Analysis

International Series of Monographs on Analytical Chemistry, Volume 8

1st Edition - January 1, 1963

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  • Author: F. E. Critchfield
  • eBook ISBN: 9781483136127

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Description

Organic Functional Group Analysis deals with versatile and reliable chemical methods for the analysis of most of the more common organic functional groups. The minimum number of methods required to solve the maximum number of problems is presented. The scope and known limitations of each method are discussed so that analytical chemists can decide whether the method under consideration can be applied to their particular problem. The methods are either titrimetric or colorimetric in nature. This volume is comprised of 11 chapters and begins with an overview of the analytical methods used for organic functional groups, including both titrimetric and colorimetric methods. The discussion then turns to the properties of acids and bases; selection of the best acid-base method for a particular purpose; and some of the more useful acid-base methods. Subsequent chapters explore methods for the determination of nitrogen compounds such as amines and amides; carbonyl compounds and derivatives; hydroxyl compounds such as tertiary alcohols; unsaturated compounds; 1,2-epoxy compounds; esters and peroxides; carboxylic acid anhydrides; and sulfur compounds. This book is intended for analytical chemists.

Table of Contents


  • Preface

    1. Introduction

    Techniques

    2. Acids and Bases

    Selection of Acid-Base Method

    Differentiations

    Indicators

    Methods

    References

    3. Nitrogen Compounds

    Amines

    Amides

    Miscellaneous

    References

    4. Carbonyl Compounds and Derivatives

    Hydroxylamine Hydrochloride-Triethanolamine Methods

    Hydroxylamine Hydrochloride-Dimethylethanolamine Method

    Hydroxylammonium Formate

    Mercurimetric Determination of Aldehydes

    2,4,-Dinitrophenylhydrazine Colorimetric Method

    Summary

    References

    5. Hydroxyl Compounds

    Acylation Methods

    Cleavage of 1,2-Glycols

    Hydrogen Bromide Method for Tertiary Alcohols (and Diols)

    Bromination Method for Aromatic Hydroxyl Compounds

    Colorimetric Methods

    Summary

    References

    6. Unsaturated Compounds

    Halogenation Methods

    Morpholine Method

    Mercuric Acetate Method

    Silver Perchlorate Method

    Summary

    References

    7. 1,2-Epoxy Compounds

    Indirect Hydrogen Bromide Method

    Direct Hydrogen Bromide Method

    Pyridine Hydrochloride Method

    Morpholine Method

    Colorimetric Method

    Summary

    References

    8. Esters

    Saponification with Aqueous Potassium Hydroxide

    Saponification in the Presence of Phenylhydrazine

    Saponification with Potassium Hydroxide in Diethylene Glycol

    Hydroxamic Acid Colorimetric Method

    Summary

    References

    9. Carboxylic acid Anhydrides

    Aniline-Sodium Hydroxide Method

    Morpholine Method

    Morpholine-Carbon Disulfide Method

    Hydroxamic Acid Colorimetric Method

    Summary

    References

    10. Peroxides

    Sodium Iodide-Acetic Anhydride Method

    Hydrogen Iodide-Acetic Acid Method

    Ceric Ammonium Sulfate Method

    Colorimetric Sodium Iodide-Acetic Anhydride Method

    Summary

    References

    11. Sulfur Compounds

    Titration of Mercaptans with Mercuric Perchlorate

    Iodometric Method for Mercaptans

    Potassium Bromate Method for Sulfides and Disulfides

    Acid Hydrolysis of Alkyl Sulfates

    Titration of Surface Active Sulfates and Sulfonates with Cetyl Pyridinium Bromide

    Colorimetric Method for Surface Active Sulfates and Sulfonates

    References

    Index

Product details

  • No. of pages: 196
  • Language: English
  • Copyright: © Pergamon 1963
  • Published: January 1, 1963
  • Imprint: Pergamon
  • eBook ISBN: 9781483136127

About the Author

F. E. Critchfield

About the Editors

R. Belcher

L. Gordon

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