
Optimizing Thermal, Chemical, and Environmental Systems
Description
Key Features
- Summarizes recent achievements of advanced optimization techniques
- Links exergy definitions in reversible systems with classical problems of extremum work
- Includes practical problems and illustrative examples to clarify applications
- Provides a unified description of classical and work-assisted heat and mass exchangers
- Written by a first-class expert in the field of advanced methods in thermodynamics
Readership
Scientists in academia and industry, chemical engineers, and students in (electro)chemistry, biotechnology, and ecology
Table of Contents
1. Outline of Classical Optimization Methods
1.1 Applying Mathematical and Engineering Knowledge in Optimization
1.2 Unconstrained Problems for Function of Several Variables
1.3 Equality Constraints and Lagrange Multipliers
1.4 Methods of Mathematical Programming
1.5 Methods of Dynamic Optimization
1.6 Iterative Search Approaches
1.7 Some Stochastic Optimization Techniques2. Finite Rate Optimization of Steady Thermal Units
2.1 Optimization Syntheses Toward Thermodynamic Limits
2.2 Maximizing Power Produced by a Finite Resource at Flow
2.3 Maximizing Cumulative Power
2.4 Discussion and Concluding Remarks3. Neural Networks for Emission Prediction of Dust Pollutants
3.1 Introduction
3.2 Aims, Scope, and Assumptions
3.3 Experimental Data
3.4 Artificial Neural Networks
3.5 Emission Prediction With Multilayer Perceptron Method
3.6 Working Parameters of the Artificial Neural Network Model
3.7 Prediction Results
3.8 Emission Prediction by a Hybrid Model
3.9 Work Parameters of the Radial Base Function Network
3.10 Prediction Results
3.11 Summary and Conclusions4. Neural NetworksdA Review of Applications
4.1 Introduction: General Issues
4.2 Training, Modeling, and Simulation
4.3 Performance Prediction, Optimization, and Related Issues
4.4 Hybrid and Fuzzy Systems5. Uncontrolled FluideSolid Systems in Chemistry
5.1 Mass Penetration
5.2 Heterogeneous Process Regimes
5.3 GaseSolid Noncatalytic Reactions
5.4 Kinetic Analysis of Contact (Catalytic) Reactions (Szarawara et al., 1991, Chapter 5)
5.5 Kinetics of Surface Process
5.6 External Diffusion
5.7 Internal Diffusion
5.8 Catalyst Deactivation
5.9 Cascades of Tank Reactors
5.10 Reactor With the Product Recycle
5.11 Chemical Networks6. Maximum Power in Homogeneous Chemical Systems
6.1 Introduction 175
6.2 Macro-Kinetics of Transport Phenomena and Chemical Reactions
6.3 Equations of Nonlinear Macro-Kinetics
6.4 Correspondence With Classical Chemical Kinetics
6.5 Inclusion of Nonlinear Transport Phenomena
6.6 Continuous Description of Chemical Kinetics and Transport
6.7 Principles of Power Production in Chemical Systems
6.8 Power Yield in Nonisothermal Chemical Engines
6.9 Nonisothermal Engines in Terms of Carnot Variables
6.10 Entropy Production in Steady Systems
6.11 Dynamical Dissipative Availabilities
6.12 Characteristics of Steady Isothermal Engines
6.13 Plausible Models of Dynamic Power Generators
6.14 Computational Algorithm for the Dynamical Process
6.15 Results of Computations
6.16 Some Additional Comments
6.17 Complex Systems With Internal Dissipation7. Maximum Conversion in Processes With Chemical Reactions
7.1 Optimal Temperature Profile for a Single Reversible Chemical Reaction
7.2 Optimization of Consecutive Reactions in a Batch or Tubular Reactor
7.3 Parallel and Consecutive-Parallel Reactions in a Tubular or Batch Reactor8. Reactors With Catalyst Decay and Regeneration
8.1 Mathematical Model for Kinetics of Reaction and Deactivation
8.2 Optimal Temperature Strategy for Single Catalytic Reaction in a Batch Reactor and Moving Bed Reactors
8.3 Tubular Reactor With Fixed Catalyst Bed and Optimal ReactioneRegeneration Cycle
8.4 Discussion
8.5 System of Consecutive-Parallel Reactions in Reactors With Catalyst Deactivation9. Fuel Cells and Other Electrochemical Systems
9.1 Introduction
9.2 Electrochemical Engines
9.3 Entropy Production and Power Limits in Fuel Cells
9.4 Calculation of Operational Voltage
9.5 Thermodynamic Account of Current-Dependent and -Independent Imperfections
9.6 Evaluation of Mass Flows, Power Output, and Efficiency
9.7 Quality Characteristics and Feasibility Criteria
9.8 Some Experimental Results
9.9 Evaluating Power Limits in Thermo-Electro-Chemical Engines
9.10 Hybrid Systems
9.11 Unsteady States, Dynamic Units, and Control Problems
9.12 Biological Fuel Cells and Hydrogen Sources
9.13 Anode-Supported Solid Oxide Fuel Cell for Determination of Poisoning Limits10. Optimizing Circulation Reactor With Deactivating Catalyst
10.1 Introducing the Problem of Optimal Temperatures in Circulation Reactors
10.2 Formulation of the Optimization Problem
10.3 Shapes of Optimal Temperature Profiles
10.4 Results of Numerical Calculations
10.5 Summarizing Remarks11. Optimizing Reactore - Regenerator System With Catalytic Parallel-Consecutive Reactions
11.1 Introduction
11.2 Mathematical Model of Catalyst Deactivation
11.3 Mathematical Model of Chemical Reactions
11.4 Process Profit Flux
11.5 Optimization Problem and Computational Algorithm
11.6 Some Results
11.7 Conclusions12. Maximum Principle and Other Criteria of Dynamic OptimizationdAn Unconventional Approach
12.1 Introducing the Standard Form of the Continuous Optimization Problem
12.2 Dynamic Programming Investigation of Optimal Quality Function
12.3 Continuous Maximum Principle
12.4 Solving Methods for Maximum Principle Equations
12.5 Discrete Versions of Maximum Principle
12.6 Classification and Comparison of Various Computational Methods for Optimization of Functionals
Product details
- No. of pages: 452
- Language: English
- Copyright: © Elsevier 2017
- Published: November 13, 2017
- Imprint: Elsevier
- Paperback ISBN: 9780128135822
- eBook ISBN: 9780128135839
About the Authors
Stanislaw Sieniutycz
Affiliations and Expertise
Zbigniew Szwast
Affiliations and Expertise
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