Nitration of Hydrocarbons and Other Organic Compounds - 1st Edition - ISBN: 9780080091549, 9781483184388

Nitration of Hydrocarbons and Other Organic Compounds

1st Edition

Authors: A. V. Topchiev
eBook ISBN: 9781483184388
Imprint: Pergamon
Published Date: 1st January 1959
Page Count: 336
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Description

Nitration of Hydrocarbons and Other Organic Compounds tackles various concerns in the process of substituting hydrogen atoms in the aromatic or heterocyclic nucleus, or in saturated hydrocarbon, by nitro groups. The title first covers the nitration of aromatic and heterocyclic compounds with nitric acid and nitrating mixture, and then proceeds to discussing the mechanism of the nitration of aromatic compounds with nitric acid and nitrating mixture. Next, the selection deals with the nitration of saturated, aromatic-aliphatic and unsaturated hydrocarbons with nitric acid. The text also talks about the nitration with nitrogen oxides, along with the nitration of amines. The last chapter details the nitration of organic compounds with organic and inorganic nitrates and nitroxyl. The book will be of great interest to students, researchers, and practitioners of organic chemistry.

Table of Contents


Introduction

I. Nitration of Aromatic and Heterocyclic Compounds with Nitric Acid and Nitrating Mixture

1. Nitration with Nitric Acid

2. Nitration with a Mixture of Nitric and Sulphuric Acids

3. Nitration with Nitric Acid and Glacial Acetic Acid or Acetic Anhydride

4. Nitration in the Presence of Catalysts

5. The Catalytic Action of Nitrous Acid in Nitration

II. The Mechanism of the Nitration of Aromatic Compounds with Nitric Acid and Nitrating Mixture

III. Nitration of Saturated, Aromatic-Aliphatic and Unsaturated Hydrocarbons with Nitric Acid

1. Properties of Nitroparaffins

2. Preparation of Mononitroparaffins and Nitro Compounds of the Aliphatic-Aromatic Series

3. Preparation of Polynitroparaffins

4. Properties of Nitroolefines

5. Nitration of Unsaturated Hydrocarbons

IV. Nitration of Amines

V. Nitration with Nitrogen Oxides

A. Nitration with Nitrogen Oxides without Catalysts

1. Nitration in the Liquid Phase

2. Nitration in the Vapor Phase

3. Nitration of Aromatic Compounds with Nitrous Fumes

4. Nitration of Aliphatic-Aromatic and Aliphatic Hydrocarbons with Nitrogen Oxides

B. Nitration with Nitrogen Oxides in the Presence of Catalysts

VI. Nitration of Organic Compounds with Organic and Inorganic Nitrates and Nitroxyl Chloride

1. Nitration with Organic Nitrates

2. Nitration with Inorganic Nitrates

3. Nitration with Nitroxyl Chloride

Author Index

Subject Index

Details

No. of pages:
336
Language:
English
Copyright:
© Pergamon 1959
Published:
Imprint:
Pergamon
eBook ISBN:
9781483184388

About the Author

A. V. Topchiev