N-Benzoylphenylhydroxylamine and Its Analogues

1st Edition - January 1, 1972
Author: A. K. Majumdar
Editors: R. Belcher, H. Freiser
Language: English
eBook ISBN:
9 7 8 - 1 - 4 8 3 2 - 7 8 6 3 - 6

International Series of Monographs in Analytical Chemistry, Volume 50: N-Benzoylphenylhydroxylamine and its Analogues covers the analytical applications of the organic… Read more

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International Series of Monographs in Analytical Chemistry, Volume 50: N-Benzoylphenylhydroxylamine and its Analogues covers the analytical applications of the organic hydroxylamine derivatives. This book is composed of seven chapters, and starts with a brief historical account of the uses of organic reagents in inorganic analysis. The next chapter discusses some basic physico-chemical factors associated with the constitution of a good reagent, including some fundamental ideas about the type and nature of the principal reactive and other groupings in the ligand. A chapter deals with the inclusion of the methods of preparation and properties of N-benzoylphenylhydroxylamine (BPHA) and its analogues and derivatives, and their reactions with different metal ions. These topics are followed by descriptions of the various types of analytical applications of BPHA and its analogues, such as gravimetry, spectrophotometry, and solvent extraction, as well as their applications in titrimetry and paper chromatography. This book is of value to analytical and organic chemists.

Preface

1. Introduction

Organic Reagents in Inorganic Analysis

References

2. The Effect of Atomic Groupings and Substituents on Reagents

Cupferrons

Hydroxytriazenes

Hydroxamic Acids

Hydroxylamines

References

3. Preparation and Properties of N-Benzoylphenylhydroxylamine and its Analogues 30

N-Benzoylphenylhydroxy lamine {BPHA)

N-Substituted Phenylhydroxylamines

N-Acetylphenylhydroxylamine

N-2-Thiophenecarbonyl-p-tolylhydroxylamine

Spectral Characteristics of p-TTHA and PTHA

N-Benzoyl-o-tolylhydroxylamine

H-Benzoyl-p-tolylhydroxylamine and N-benzoyl-m-tolylhydroxylamine

N-Cinnamoylphenylhydroxylamine

N-Phenylacetylphenylhydroxylamine

N-Benzoyl-p-chlorophenylhydroxylamine

N-Salicylphenylhydroxylamine

N-Acetylsalicylphenylhydroxylamine

N-Benzoylmethylhydroxylamine

N-Substituted Arylhydroxylamines

N-Thiobenzoylphenylhydroxylamine (TBPHA)

References

4. Gravimetric Determination of the Elements with N-Benzoylphenylhydroxylamine and its Analogues

1. Applications of N-Benzoylphenylhydroxylamine

2. Applications of N-Cinnamoylphenylhydroxylamine

3. Applications of N-Benzoyl-o-tolylhydroxylamine

4. Application of N-Salicylphenylhydroxylamine

5. Application of N-Acetylsalicylphenylhydroxylamine

6. Applications of Thiobenzoylphenylhydroxylamine

References

5. Spectrophotometric Determination of the Elements with N-Benzoylphenylhydroxylamine and its Analogues

1. N-Benzoylphenylhydroxyfamine as a Spectrophotometric Reagent

2. N-Acetylphenylhydrïxyfamine as a Spectrophotometric Reagent

3. N-Benzoylmethylhydroxylamine as a Spectrophotometric Reagent

4. N-2-Thiophenecarbonyl-p-tolylhydroxylamine and N-2-thiophenecarbonylphenylhydroxylamine as Spectrophotometric Reagents

5. N-Cinnamoylphenylhydroxylamine as a Spectrophotometric Reagent

6. N-Benzoyl-p-tolylhydroxylamine as a Spectrophotometric Reagent

7. N-Benzoyl-o-tolylhydroxylamine as a Spectrophotometric Reagent

8. N-Benzoyl-p-chlorophenylhydroxyfamine as a Spectrophotometric Reagent

9. N-Benzoyl-o-tolylhydroxy famine and Other Aromatic Hydroxylamines as Spectrophotometric Reagents

10. N-Furoylphenylhydroxylamine as a Spectrophotometric Reagent

11. N-Acetylsalicylphenylhydroxyfamine as a Spectrophotometric Reagent

12. N-Arylhydroxyfamines as Spectrophotometric Reagents

References

6. Separation of Elements by Solvent Extraction with N-Benzoylphenylhydroxylamine

The Separation of Thorium and Uranium from Lanthanum

Simultaneous Separation of Iron and Small Amounts of Titanium from Aluminium

Separation of Scandium from the Lanthanides, Zirconium and Titanium

Extraction of Aluminium from Complex Mixtures including Uranium-based Fuels and Stainless Steels

Extraction of Thorium and Separation from the Lanthanides

Extraction of Tungsten

Extraction of Zirconium

Separation of Niobium from Tantalum

The Separation of Niobium and Tantalum Extraction of Niobium, Tantalum, Titanium, Zircoaium and Vanadium from Sulphuric Acid

Separation of Protactinium from Niobium, Titanium, Zirconium and Hafnium

Separation of Protactinium from Other Elements

Separation of Niobium from Zirconium

Separation of Tin and Antimony from Indium

Separation of Gallium, Indium, Thallium, Germanium, Tin and Lead

Separation of Protactinium from Niobium, Tantalum and Other Elements

Separation of Niobium and Tantalum Fluorocomplexes

Separation of Plutonium from Uranium, Americium, Zirconium and Other Fission Products

Separation of Protactinium from Neutron-irradiated Thorium

Separation of Arsenic, Antimony, Bismuth and Tin

Extraction of Thallium as a Function of pH and BPHA Concentration

Separation of Bismuth from Lead

Extraction of Copper, Iron, Lead, Nickel, Cobalt and Cadmium

Extraction of Zinc, Mercury, Bismuth, Manganese, Aluminium, Chromium and Silver

Extraction of Several Common Metal Ions

Extraction and Determination of Beryllium in Silicates

Separation of Elements from Hydrochloric Acid. Application to the Extraction of Niobium and Zirconium from Uranium

Separation of Cations by Extraction

Extraction of Germanium and Separation from Gallium

References

7. Titrimetric and Paper Chromatographic Applications of N-Benzoylphenylhydroxylamine

Determination of Iron

Determination of Scandium and Zirconium

Determination of Vanadium(V) in the Presence of Fluoride, Phosphate, Titanium, Molybdenum and Manganese

Determination of Iron and Copper in the Presence of Many Other Ions by Using an Extractive End-point Procedure

Determination of Indium, Thallium and Thorium with Iron-BPHA as a Metallochromic Indicator

N-Benzoylphenylhydroxylamine as a Titrant for the Determination of Zirconium

Amperometric Determination of Titanium, Zirconium, Gallium, Scandium and Other Elements

Amperometric Determination of Gallium in Arsenides and Phosphides

Amperometric Determination of Niobium

Paper Chromatographic Separation of Metal Ions

References

Index