List of Contributors
Preface
Chapter 1. Lamb-DIP Spectroscopy
1.1 Hyperfine Structure in the Electronic Spectrum of I2
References
Chapter 2. Microwave Spectra
2.1 Microwave Spectroscopy
Introduction
Development of Techniques
Molecular Structure
Nuclear Quadrupole Coupling
Zeeman Effect in Diamagnetic Molecules
Internal Rotation and Other Large-Amplitude Motions
Vibration-Rotation Interactions
References
2.2 Rotational Levels of Free Radicals
Introduction
Microwave and Electron Resonance Spectra of the OH Radical
Recent Pure Microwave and Electron Resonance Studies
Molecular-Beam and RF/Optical Double-Resonance Methods
Conclusions and Possible Future Developments
References
2.3 Information on Rotational Energy Transfer from Microwave Line Broadening
References
2.4 Rotational Spectra of Molecules with Two Internal Degrees of Freedom
References
2.5 Interstellar Molecules and the Interstellar Medium
References
Chapter 3. Infrared Spectra
3.1 High-Resolution Infrared Spectroscopy of Planetary Atmospheres
Introduction
The Outer Planets
The Inner Planets
Future Research
References
3.2 Vibration-Rotation Structure in Asymmetric- and Symmetric-Top Molecules
Introduction
Asymmetric Tops
Symmetric Tops
Discussion
References
3.3 Molecular Laser Emissions in the Infrared
Introduction
References
Basic Observational Data
Laser Spectra and Molecular Structure
References
Bibliography
Chapter 4. Electronic Spectra
4.1 Progress in Electronic Spectroscopy of Polyatomic Molecules
Introduction and Scope
Triatomic Dihydrides BH2, CH2, NH2 , OH2, AlH2, SiH2, PH2, SH2, AsH2
Carbon Dioxide, Carbon Disulfide, and Their Ions CO2, CO2+, CS2, CS2+
Acetylene C2H2
Boron Trifluoride BF3
Formaldehyde H2CO
Ethylene C2H4
Ethane C2H6
Benzene C6H6
Methinophosphide and Pyrazine HCP and p-C4H4N2
Naphthalene C10H8
Anthracene C14H10
Conclusion and Outlook
References
4.2 Rotational Line Strengths: The O2+b4Σg--a4Πu Band System
Introduction
The Rotational Structure of the O2+ First Negative Bands
Experimental Line Strengths
Comparison with Calculated Line Strengths
References
4.3 A Chrestomathy of Energy Transfer Research on Iodine
References
4.4 Nuclear Hyperfine Structure in the Electronic Spectra of Diatomic Molecules
Introduction
Theoretical
Experimental
Summary
References
Chapter 5. Matrix Spectra
5.1 Infrared and Ultraviolet Spectroscopic Studies of Free Radicals and Molecular Ions Isolated in Inert Solid Matrices
General Discussion
Diatomic Free Molecules
Triatomic Free Radicals
Tetratomic Free Radicals
Pentatomic Free Radicals
Molecular Ions
References
Chapter 6. Biophysics
6.1 The Competition among Biprotonic Phototautomerism, Excimer Formation, and Proton Tunneling in DNA Base-Pairs
Rapid Excitation Phenomena in Η-Bonded Base-Pairs
Proton Tunneling and Molecular Excimer Formation
Biprotonic Phototautomerism
Temperature Dependence of Phototautomerism
Tautomer Excitation Frequencies of Purines
Potential Energy Functions for Tautomerism of Η-Bonded Base-Pairs
Biological Implications
Summary
References
Chapter 7. Instrumental Techniques
7.1 Fourier Spectroscopy
Introduction
Theory
Instruments
References
7.2 Grille Spectrometers
Introduction
Simplified Theory of a Grille Spectrometer
Problems Encountered in an Actual Grille Spectrometer
Special Properties of Some Types of Grilles
References
7.3 Large Plane Gratings for High-Resolution Infrared Spectrographs
Introduction
Grating Equation
Echelles
Wavelength Calibration Techniques
References
Chapter 8. Tables of Standard Data
Table I. Fundamental Physical Constants
Table II. Defined Quantities and Standard Prefixes
Table III. Conversion Factors
Tables IV-X. Wavelength Standards
Table XI. Atomic Mass, Nuclear Spin, and Abundance (or Half-Life) of Each Element
Table XII. 1969 Table of Atomic Weights
References
Author Index
Index of Molecular Species
Subject Index