Metal Oxides and Related Solids for Electrocatalytic Water Splitting

1st Edition - May 5, 2022
Editor: Junlei Qi
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 8 5 7 3 5 - 2
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 8 9 8 0 6 - 5

Metal Oxides and Related Solids for Electrocatalytic Water Splitting reviews the fundamentals and strategies needed to design and fabricate metal oxide-based electroca… Read more

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Metal Oxides and Related Solids for Electrocatalytic Water Splitting reviews the fundamentals and strategies needed to design and fabricate metal oxide-based electrocatalysts. After an introduction to the key properties of transition metal oxides, materials engineering methods to optimize the performance of metal-oxide based electrocatalysts are discussed. Strategies reviewed include defect engineering, interface engineering and doping engineering. Other sections cover important categories of metal-oxide (and related solids) based catalysts, including layered hydroxides, metal chalcogenides, metal phosphides, metal nitrides, metal borides, and more.

Each chapter introduces important properties and material design strategies, including composite and morphology design. There is also an emphasis on cost-effective materials design and fabrication for optimized performance for electrocatalytic water splitting applications. Lastly, the book touches on recently developed in-situ characterization methods applied to observe and control the material synthesis process.

Cover Image
Title Page
Copyright
Table of Contents
Contributors
The Metal Oxides Book Series Edited by Ghenadii Korotcenkov
Preface to the series
Series editor biography
Preface to the volume
About the volume editor
Acknowledgments
Section 1 Introduction to metal oxide-based electrocatalysis
Chapter 1 Introduction to water splitting technologies
1.1 Where is the demand?
1.2 The source of hydrogen production
1.3 The methods to achieve water splitting
1.4 The general catalytic principles
1.5 Fundamentals of water electrocatalysis
1.6 The design of electrolyzers
1.7 Conclusion and perspective
References
Chapter 2 The fundamentals of metal oxides for electrocatalytic water splitting
2.1 Introduction
2.2 Description and definition of metal oxides
2.3 Classification of metal oxides
2.4 The basic properties of metal oxide
2.5 Research methods for metal oxides
2.6 Summary and outlook
References
Chapter 3 Features of design and fabrication of metal oxide-based electrocatalysts
3.1 Introduction
3.2 The synthetic methods of metal oxide-based electrocatalysts
3.3 Basic design principles of metal oxides for efficient electrocatalysts
3.4 Summary and prospects
Conflict of Interest
References
Chapter 4 Noble metal oxide based electrodes interfaces design for application in water splitting
4.1 Introduction
4.2 Types, properties, and synthesis methods of noble metal oxide
4.3 Performance optimization strategies of noble metal oxide
4.4 Applications of noble metals and their oxides
4.5 Conclusion and perspectives
References
Section 2 Transition metal oxides and their prospects for application in water splitting
Chapter 5 Structure and basic properties of transition metal oxides designed for application in water splitting
5.1 Transition metal oxides in water splitting
5.2 Spinel-type oxides
5.3 Perovskite oxides
5.4 Amorphous metal oxides
5.5 Rock–salt-type transition metal oxides
5.6 Lithium-transition metal oxides
5.7 Hybrid oxides
References
Chapter 6 Defect engineering for modifying transition metal oxides
6.1 Introduction
6.2 The type, introduction, and characterizations of defects
6.3 The roles of defects in electrocatalysts
6.4 Defect engineering metal oxides and other solids
6.5 Summary and prospects
References
Chapter 7 Interfaces joining for modifying transition metal oxides
7.1 Introduction
7.2 Overview of transition metal oxides
7.3 Types of interfaces
7.4 Preparation of interface modified transition metal oxides
7.5 Interface design strategy
7.6 The role of interface engineering in water splitting
7.7 Specific use of interface process
7.8 Summary and outlook
References
Chapter 8 Doping engineering toward metal oxides for water splitting
8.1 Introduction
8.2 Pure metal oxide materials
8.3 Cation doped oxide materials
8.4 Anion doped oxide materials
8.5 Co-doped oxide materials
8.6 Single atom doped oxide materials
8.7 Summary and prospects
References
Section 3 Other approaches to developing electrocatalysts for water splitting
Chapter 9 Layered hydroxides as electrocatalysts for water splitting
9.1 Recent developments and improvements on layered double hydroxides water splitting electrocatalysts
9.2 Synthesis method of layered double hydroxides material
9.3 Design strategies for improving the performance of water splitting of layered double hydroxides
9.4 Future perspectives
References
Chapter 10 Metal oxy compounds heterogeneous interfaces joining for water splitting
10.1 What is metal oxy compounds?
10.2 The classification of metal oxy compounds
10.3 The application for HER
10.4 The modification toward metal oxy compounds
10.5 Summary and outlook
References
Chapter 11 Metal phosphide based electrocatalysts for water splitting
11.1 Phosphide-based electrocatalysts for water splitting
11.2 Syntheses of phosphate-based electrocatalysts
11.3 Other emerging routes
11.4 Conclusion and perspectives
References
Chapter 12 Metal-organic framework (MOF)-derived electrocatalysts for water splitting
12.1 Introduction
12.2 Synthesis strategies of MOFs
12.3 MOF-derived metal oxide
12.4 Summary and prospects
References
Chapter 13 In-situ characterizations for application in water splitting
13.1 What is in-situ characterizations
13.2 The mainstream in-situ characterizations
13.3 Summary and outlook
References
Chapter 14 Summary and outlook
Index

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Junlei Qi