Metal-Ammonia Solutions contains the proceedings of an International Conference on the Nature of Metal-Ammonia Solutions Colloque Weyl II held at Cornell University in Ithaca, New York, on June 15-19, 1969. The papers explore the nature of metal-ammonia solutions and cover topics ranging from the dilemma of metal-ammonia models to the magnetic properties of metal-ammonia solutions, the reactions of such solutions, and solid metal-ammonia compounds. This monograph is comprised of 39 chapters and begins with an overview of models for the concentration dependence of the properties of dilute metal-ammonia solutions. The discussion then turns to a continuous dielectric model for the solvated dielectron in dielectric media; elementary electronic excitations in insulating liquids; and magnetic properties of metal-ammonia solutions. The chapters that follow focus on the kinetics of the reaction between sodium and ethanol in liquid ammonia; electrons trapped in solids; metal-nonmetal transition and phase separation; and optical spectra of alkali metal-ammonia solutions. This text will be a valuable resource for chemists and chemistry students.
Preface List of Participants The Dilemma of Metal - Ammonia Models A Model for the Solvated Dielectron in Dielectric Media Studies of the Species (e2-2)am Metal-Ammonia Solutions VI—The Nature of the 1.5 μ Band Elementary Electronic Excitations in Insulating Liquids The Magnetic Properties of Metal-Ammonia Solutions A Proton Resonance Study of Metal-Ammonia Solutions Intermetallic Solutes in Liquid Ammonia Magnetic Resonance and Susceptibility Measurements on Sodium-Hexamethylphosphoramide (HMPA) Solutions Lithium-7 Knight Shifts for Lithium in Ammonia and Lithium in Methylamine Reactions of Metal-Ammonia Solutions The Decomposition of Dilute Solutions of Sodium and Potassium in Liquid Ammonia at — 78°C: Kinetics and Mechanism Kinetics of the Reaction of Sodium with Ethanol in Liquid Ammonia Pressure Effects in Metal-Ammonia Solutions Effect of Pressure and Metal Concentration on Magnetic Properties of Ammonia Solutions The Structure of Li (NH3)4 Thermoelectric Power and Thomson Coefficient in the Intermediate Range of Concentrations Properties of Concentrated Metal-Ammonia Solutions Optical Properties of Concentrated Metal-Ammonia Solutions Mécanisme de Relaxation Spin—Réseau des Electrons Solvatés Electrons Trapped in Solids Electron and Nuclear Resonance Studies of Lithium-Amine Solutions Optical and Electron Spin Resonance Studies of Solutions of Potassium in Tetrahydrofuran The Metal-Nonmetal Transition and Phase Separation The Acoustic Properties of Metal-Ammonia Solutions Solid Metal-Ammonia Compounds Field-Dependent Conductance in Sodium-Liquid Ammonia Solutions II—Semi-conductor Behavior at the Electrodes Positron Annihilation in Concentrated Metal-Ammonia Solutions Some Optical Properties of the Hydrated Electron Electron Spin Resonance Studies of Concentrated Alkali Metal-Ammonia Solutions Conductivity of Concentrated Metal-Ammonia Solutions Optical Absorption Spectra of Alkali Metal Solutions in Amines and Ethers Short C
- No. of pages:
- © Butterworth-Heinemann 1970
- 1st January 1970
- eBook ISBN: