Metal—Ammonia Solutions - 1st Edition - ISBN: 9780408701228, 9781483136233

Metal—Ammonia Solutions

1st Edition

Proceedings of an International Conference on the Nature of Metal-Ammonia Solutions: Colloque Weyl II

Authors: Unknown Author
eBook ISBN: 9781483136233
Imprint: Butterworth-Heinemann
Published Date: 1st January 1970
Page Count: 520
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Metal-Ammonia Solutions contains the proceedings of an International Conference on the Nature of Metal-Ammonia Solutions Colloque Weyl II held at Cornell University in Ithaca, New York, on June 15-19, 1969. The papers explore the nature of metal-ammonia solutions and cover topics ranging from the dilemma of metal-ammonia models to the magnetic properties of metal-ammonia solutions, the reactions of such solutions, and solid metal-ammonia compounds. This monograph is comprised of 39 chapters and begins with an overview of models for the concentration dependence of the properties of dilute metal-ammonia solutions. The discussion then turns to a continuous dielectric model for the solvated dielectron in dielectric media; elementary electronic excitations in insulating liquids; and magnetic properties of metal-ammonia solutions. The chapters that follow focus on the kinetics of the reaction between sodium and ethanol in liquid ammonia; electrons trapped in solids; metal-nonmetal transition and phase separation; and optical spectra of alkali metal-ammonia solutions. This text will be a valuable resource for chemists and chemistry students.

Table of Contents


List of Participants

The Dilemma of Metal - Ammonia Models

A Model for the Solvated Dielectron in Dielectric Media

Studies of the Species (e2-2)am

Metal-Ammonia Solutions VI—The Nature of the 1.5 μ Band

Elementary Electronic Excitations in Insulating Liquids

The Magnetic Properties of Metal-Ammonia Solutions

A Proton Resonance Study of Metal-Ammonia Solutions

Intermetallic Solutes in Liquid Ammonia

Magnetic Resonance and Susceptibility Measurements on Sodium-Hexamethylphosphoramide (HMPA) Solutions

Lithium-7 Knight Shifts for Lithium in Ammonia and Lithium in Methylamine

Reactions of Metal-Ammonia Solutions

The Decomposition of Dilute Solutions of Sodium and Potassium in Liquid Ammonia at — 78°C: Kinetics and Mechanism

Kinetics of the Reaction of Sodium with Ethanol in Liquid Ammonia

Pressure Effects in Metal-Ammonia Solutions

Effect of Pressure and Metal Concentration on Magnetic Properties of Ammonia Solutions

The Structure of Li (NH3)4

Thermoelectric Power and Thomson Coefficient in the Intermediate Range of Concentrations

Properties of Concentrated Metal-Ammonia Solutions

Optical Properties of Concentrated Metal-Ammonia Solutions

Mécanisme de Relaxation Spin—Réseau des Electrons Solvatés

Electrons Trapped in Solids

Electron and Nuclear Resonance Studies of Lithium-Amine Solutions

Optical and Electron Spin Resonance Studies of Solutions of Potassium in Tetrahydrofuran

The Metal-Nonmetal Transition and Phase Separation

The Acoustic Properties of Metal-Ammonia Solutions

Solid Metal-Ammonia Compounds

Field-Dependent Conductance in Sodium-Liquid Ammonia Solutions II—Semi-conductor Behavior at the Electrodes

Positron Annihilation in Concentrated Metal-Ammonia Solutions

Some Optical Properties of the Hydrated Electron

Electron Spin Resonance Studies of Concentrated Alkali Metal-Ammonia Solutions

Conductivity of Concentrated Metal-Ammonia Solutions

Optical Absorption Spectra of Alkali Metal Solutions in Amines and Ethers

Short Communications

The Reaction of e- with Na+ in Ethylenediamine

Simultaneous Observation of Absorption and e.s.r. Spectra of HMPA - Potassium Metal Solutions

Calculation of the Excess Volume in Dilute Metal-Ammonia Solutions

The Volume Expansion of Solutions of Lithium in Methylamine at -45°C

Preparation of Deuteroammonia

The Conductance of Dilute Metal-Ammonia and Metal-Amine Solutions

Optical Spectra of Alkali Metal-Ammonia Solutions



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