
Membrane Reactors for Energy Applications and Basic Chemical Production
Description
Key Features
- Provides comprehensive coverage of membrane reactors as presented by a world-renowned team of experts
- Includes discussions of the use of membrane reactors in ammonia production and the dehydrogenation of alkanes to alkenes
- Tackles the use of membrane reactors in syngas, hydrogen, and basic chemical production
- Keen focus placed on the industry, particularly in the use of membrane reactor technologies in energy
Readership
R&D managers in chemical engineering companiesdeveloping membrane reactors for energy applications and basic chemical production; Postgraduates working on membrane reactors for energy applications and basic chemical production (departments of chemistry; engineering; energy).
Table of Contents
- Related titles
- List of contributors
- Woodhead Publishing Series in Energy
- Preface
- Part One. Membrane reactors for syngas and hydrogen production
- 1. Water gas shift membrane reactors
- 1.1. Water gas shift in conventional reactors
- 1.2. Traditional water gas shift (WGS) process
- 1.3. Catalysts for the WGS reaction
- 1.4. Models for the kinetic interpretation of WGS
- 1.5. WGS regime in Fischer–Tropsch synthesis
- 1.6. Membrane reactor technology for the WGS reaction
- 1.7. Conclusion
- 2. Membrane reactors for methane steam reforming (MSR)
- 2.1. Introduction
- 2.2. Methane steam reforming (MSR) kinetic
- 2.3. MSR and catalysts
- 2.4. MSRs and membrane reactors (MRs)
- 2.5. Conclusion and future trends
- 3. Membrane reactors for autothermal reforming of methane, methanol, and ethanol
- 3.1. Introduction: hydrogen production
- 3.2. Methane and other sources for hydrogen
- 3.3. Conventional processes for autothermal reforming
- 3.4. The membrane reactor concepts: packed beds versus fluidized beds
- 3.5. Modeling aspects
- 3.6. Conclusions and future trends
- 4. Membrane reactors for dry reforming of methane
- 4.1. Introduction
- 4.2. Solid catalysts for methane dry reforming in traditional and membrane reactors
- 4.3. Membrane reactors: why to use them
- 4.4. Membrane reactors for methane dry reforming
- 4.5. Thermal request: a difficult challenge
- 4.6. Methane dry reforming: conclusion and remarks
- 5. Membrane reactors for hydrogen production from coal
- 5.1. Introduction
- 5.2. Traditional reactors for hydrogen production from coal and the advantages of membrane reactors
- 5.3. Catalysts for coal gasification
- 5.4. Membrane reactors for hydrogen production from coal
- 5.5. Future trends
- 5.6. Sources of further information and advice
- 6. Membrane reactors for the conversion of methanol and ethanol to hydrogen
- 6.1. Introduction
- 6.2. Membrane reactors (MRs)
- 6.3. Ethanol reforming in membrane reactors
- 6.4. Methanol reforming in membrane reactors
- 6.5. Conclusion and future trends
- 7. Membrane reactors for the decomposition of H2O, NOx and CO2 to produce hydrogen
- 7.1. Introduction
- 7.2. Membrane reactors for H2O decomposition
- 7.3. Membrane reactors for nitrous oxide decomposition
- 7.4. Membrane reactors for CO2 decomposition
- 7.5. The main challenges
- 7.6. Conclusion and future trends
- 8. Membrane reactors for steam reforming of glycerol and acetic acid to produce hydrogen
- 8.1. Introduction
- 8.2. Membrane reactor technology
- 8.3. Glycerol steam reforming reaction for hydrogen production
- 8.4. Acetic acid steam reforming reaction for hydrogen production
- 8.5. Conclusion and future trends
- 9. Membrane reactors for biohydrogen production and processing
- 9.1. Overview
- 9.2. Feedstock
- 9.3. Fermentative biohydrogen: microorganisms and enzymatic systems
- 9.4. Biohydrogen reactors
- 9.5. Conclusions and future trends
- 1. Water gas shift membrane reactors
- Part Two. Membrane reactors for other energy applications
- 10. Membrane reactors for biodiesel production and processing
- 10.1. Introduction
- 10.2. Conventional methods for biodiesel production
- 10.3. Catalysts used in conventional methods
- 10.4. Weak points of conventional methods in biodiesel production
- 10.5. Membrane technology as process intensification in biodiesel production
- 10.6. Membrane technology: production and separation of biodiesel
- 10.7. Merits and limitations of using membrane reactors in biodiesel production
- 10.8. Other considerations
- 10.9. Stability of biodiesel
- 10.10. Conclusion
- 11. Membrane reactors for bioethanol production and processing
- 11.1. Introduction
- 11.2. Bioethanol from different feedstocks: environmental impact assessment
- 11.3. Pretreatment of lignocellulosic biomass: physicochemical versus biological pretreatment
- 11.4. Recovery of side products during lignocellulose pretreatment
- 11.5. Bioethanol recovery from fermentation broths and process intensification
- 11.6. Dehydration of water/alcohol mixtures
- 11.7. Consolidation of unit processes
- 11.8. Summary and future outlook
- 12. Membrane reactors for biogas production and processing
- 12.1. Introduction
- 12.2. Basic principles of anaerobic digestion
- 12.3. Membrane bioreactor for biogas production
- 12.4. Membrane fouling
- 12.5. Progress in other applications for biogas production
- 12.6. Conclusions
- 13. The use of membranes in oxygen and hydrogen separation in integrated gasification combined cycle (IGCC) power plants
- 13.1. Introduction
- 13.2. Coal gasification technology for power generation and hydrogen production
- 13.3. Integration of oxygen membranes in integrated gasification combined cycle (IGCC) plants
- 13.4. Integration of hydrogen membranes in IGCC plants
- 13.5. Processes for treatment of CO2-rich streams from hydrogen separation membrane modules
- 13.6. Conclusions and future trends
- 14. Membrane reactors for the desulfurization of power plant gas emissions and transportation fuels
- 14.1. Introduction
- 14.2. Membrane reactors for the desulfurization of gases
- 14.3. Membrane reactors for the desulfurization of transportation fuels
- 14.4. Future trends
- 14.5. Conclusions
- 15. Electrocatalytic membrane reactors (eCMRs) for fuel cell and other applications
- 15.1. Introduction
- 15.2. Generic fuel cell electrocatalytic membrane reactor
- 15.3. Operating temperature versus overpotential in an electrocatalytic membrane reactor
- 15.4. The electrocatalytic membrane reactor modi operandi
- 15.5. The electrocatalytic membrane reactor performance characteristics
- 15.6. The electrocatalytic membrane reactor in the fuel cell mode: polymer-electrolyte membrane (PEM) fuel cell
- 15.7. The electrocatalytic membrane reactor in the fuel cell mode: cogeneration of chemicals and electric power
- 15.8. The electrocatalytic membrane reactor in the electrolytic mode
- 15.9. The electrocatalytic membrane reactor in the ion-pumping mode: gas enrichment and compression
- 15.10. Future trends
- 15.11. Conclusions
- 10. Membrane reactors for biodiesel production and processing
- Part Three. Membrane reactors for basic chemical production
- 16. Membrane reactors for the dehydrogenation of alkanes to alkenes
- 16.1. Introduction
- 16.2. Dehydrogenation of cyclohexane, methylcyclohexane, and the mixtures
- 16.3. Dehydrogenations in catalytic reforming of n-hexanes
- 16.4. Dehydrogenation of ethylbenzene
- 16.5. Conclusion
- 17. Membrane reactors for oxidative coupling of methane to produce syngas and other chemicals
- 17.1. Introduction
- 17.2. Oxygen-permeable membranes
- 17.3. Oxidative coupling of methane by using oxygen-permeable membranes
- 17.4. Membrane materials
- 17.5. Ceria-based oxygen-permeable membranes for oxidative coupling of methane
- 17.6. Development of tape-cast membranes
- 17.7. Fabrication of membrane-type partial oxidation reformer and its reforming properties
- 17.8. Exergy analysis of the membrane-type partial oxidation reformer
- 17.9. Conclusion
- 17.10. Future prospects
- 18. Membrane reactors for ammonia production
- 18.1. Introduction: chemical principles and industrial applications
- 18.2. Traditional reactors and membrane reactors for ammonia production
- 18.3. Electrocatalytic membrane reactor for ammonia production
- 18.4. Catalysts for ammonia production
- 18.5. Materials for electrolyte membrane
- 18.6. Factors affecting the ammonia formation rate
- 18.7. Conclusions and future trends
- 19. Pervaporation membrane reactors (PVMRs) for esterification
- 19.1. Introduction
- 19.2. Physicochemical properties of esters
- 19.3. Esterification reactions
- 19.4. Industrial relevance of esterification reactions
- 19.5. Reaction-separation coupled methodology
- 19.6. R2-type pervaporation reactors for esterification reaction
- 19.7. R1-type pervaporation membrane reactors (PVMRs) for esterification
- 19.8. Conclusions
- 19.9. Future trends
- 20. Photocatalytic hydrogenation of organic compounds in membrane reactors
- 20.1. Introduction
- 20.2. Fundamentals of photocatalysis and photocatalytic membrane reactors
- 20.3. Studies on the photocatalytic hydrogenation of organic compounds
- 20.4. Photocatalytic hydrogenation of carbon dioxide in membrane reactors
- 20.5. Advances and limitations of photocatalytic membrane reactors (PMRs) in the hydrogenation of organic compounds
- 20.6. Conclusion
- 20.7. Future trends
- 20.8. Sources of further information
- 21. Butene oligomerization, phenol synthesis from benzene, butane partial oxidation, and other reactions carried out in membrane reactors
- 21.1. Introduction
- 21.2. Butene oligomerization
- 21.3. Phenol synthesis from benzene
- 21.4. Butane partial oxidation
- 21.5. Cyclohexane dehydrogenation
- 21.6. Ethylbenzene dehydrogenation
- 21.7. Water splitting
- 21.8. Conclusion
- 16. Membrane reactors for the dehydrogenation of alkanes to alkenes
- Index
Product details
- No. of pages: 696
- Language: English
- Copyright: © Woodhead Publishing 2015
- Published: February 5, 2015
- Imprint: Woodhead Publishing
- Hardcover ISBN: 9781782422235
- eBook ISBN: 9781782422273
About the Editors
A Basile
Affiliations and Expertise
L Di Paola
Affiliations and Expertise
F Hai
Affiliations and Expertise
V Piemonte
Affiliations and Expertise
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