Iodine-assisted Synthesis of Six-and Seven-Membered Heterocycles

Iodine-assisted Synthesis of Six-and Seven-Membered Heterocycles

1st Edition - February 1, 2023

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  • Author: Navjeet Kaur
  • Paperback ISBN: 9780443152252

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Description

Iodine-assisted Synthesis of Six- and Seven-Membered Heterocycles covers both the existing and the latest methods for the synthesis of various six and seven membered heterocycles using iodine. Iodine has been reported as a potent catalyst for numerous organic conversions and is an excellent substitute for heavy metal reagents making the research in this area of interest to those looking to synthesize heterocycles in more efficient, cost-effective and environmentally friendly ways. Covering an important and rapidly growing branch of heterocyclic chemistry, this book allows users easy access to the synthetic protocols for the synthesis of heterocycles, acting as a guide for how to make these important compounds employed as agrochemicals, pharmaceuticals and veterinary products, using particular reagents. This book will therefore be of interest to students, pharmacologists, biochemists, organic and medicinal chemists.

Key Features

  • Covers the different methodologies for the synthesis of six and seven membered heterocycles using iodine
  • Includes the applications of six and seven membered heterocycles
  • Includes reactions schemes, mechanisms and illustrations of the structure of reactive intermediates

Readership

Synthetic and organic chemists, students, researchers and professionals in catalytic and organic chemistry

Table of Contents

  • Chapter-1: Six-membered N-heterocycles: alkenes and alkynes
    1.1 Introduction
    1.2 Synthesis of six-membered N-heterocycles from alkenes
    1.2.1 Synthesis of piperidines
    1.2.2 Synthesis of quinolines
    1.2.3 Synthesis of indolizines
    1.2.4 Synthesis of fused six-membered N-heterocycles
    1.3 Synthesis of six-membered N-heterocycles from alkynes
    1.3.1 Synthesis of pyridines
    1.3.2 Synthesis of quinolines
    1.3.3 Synthesis of isoquinolines
    1.3.4 Synthesis of fused six-membered N-heterocycles
    References
    Chapter-2: Six-membered N-heterocycles: amines and carbonyl compounds
    2.1 Introduction
    2.2 Synthesis of six-membered N-heterocycles from amines and carbonyl compounds
    2.2.1 Synthesis of quinolines
    2.2.2 Synthesis of fused six-membered N-heterocycles
    2.3 Synthesis of six-membered N-heterocycles from amines and more than one carbonyl compounds
    2.3.1 Synthesis of pyridines
    2.3.2 Synthesis of quinolines
    2.3.3 Synthesis of fused six-membered N-heterocycles
    References
    Chapter-3: Six-membered N,N-heterocycles
    3.1 Introduction
    3.2 Synthesis of quinazolines
    3.3 Synthesis of fused quinazolines
    3.4 Synthesis of quinoxalines
    3.5 Synthesis of fused quinoxalines
    References
    Chapter-4: Six-membered N-, N,N-, N,N,N-, and N,N,N,N-heterocycles
    4.1 Introduction
    4.2 Synthesis of piperidines
    4.3 Synthesis of quinolines
    4.4 Synthesis of fused quinolines
    4.5 Synthesis of pyrimidines
    4.6 Synthesis of piperazines
    4.7 Synthesis of fused pyrimidines
    4.8 Synthesis of triazines and tetrazines
    References
    Chapter-5: Six-membered O-heterocycles
    5.1 Introduction
    5.2 Synthesis of pyrans
    5.2.1 Synthesis of pyrans from CHO and ene/yne group containing compounds
    5.2.2 Synthesis of pyrans from OH and ene/yne group containing compounds
    5.3 Synthesis of benzopyrans
    References
    Chapter-6: Six-membered O-heterocycles: cyclization of ene and OH moieties
    6.1 Introduction
    6.2 Synthesis of pyrans
    6.3 Synthesis of benzopyrans
    6.4 Synthesis of fused pyrans
    References
    Chapter-7: Six-membered O,O-, O,O,O-, and O,N-heterocycles
    7.1 Introduction
    7.2 Synthesis of dioxanes
    7.3 Synthesis of fused dioxanes
    7.4 Synthesis of trioxanes
    7.5 Synthesis of oxazines
    7.6 Synthesis of benzoxazines
    7.7 Synthesis of fused oxazines
    References
    Chapter-8: Six-membered S-heterocycles
    8.1 Introduction
    8.2 Synthesis of benzothiopyrans
    8.3 Synthesis of dithiolanes
    8.4 Synthesis of benzothiazines
    8.5 Synthesis of thiadiazines
    References
    Chapter-9: Seven-membered heterocycles
    9.1 Introduction
    9.2 Synthesis of seven-membered N-heterocycles
    9.3 Synthesis of seven-membered O-heterocycles
    9.4 Synthesis of seven-membered S-heterocycles
    References

Product details

  • Language: English
  • Copyright: © Elsevier 2023
  • Published: February 1, 2023
  • Imprint: Elsevier
  • Paperback ISBN: 9780443152252

About the Author

Navjeet Kaur

Dr. Navjeet Kaur received her BSc from Panjab University Chandigarh (Panjab, India) in 2008. In 2010, she completed her MSc in Chemistry from Banasthali Vidyapith. She was awarded with PhD in 2014 by the same university. In 2021, Dr. Kaur was chosen as a candidate for membership by Royal Society of Research, London, England. She is the Editor-in-Chief for “Advanced Chemicobiology Research” journal.

Affiliations and Expertise

Department of Chemistry, Banasthali Vidyapith University, India

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