Introduction to Magnetochemistry

Introduction to Magnetochemistry

1st Edition - January 1, 1968

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  • Author: Alan Earnshaw
  • eBook ISBN: 9781483270692

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Description

Introduction to Magnetochemistry provides an introduction to the more important aspects of magnetochemistry. The measurement of magnetic moment has been one of the most consistently useful to coordination chemists. For teaching purposes it provides a simple method of illustrating the ideas of electronic structure, and in research it can provide fundamental information about the bonding and stereochemistry of complexes. The book contains six chapters covering topics such as free atoms and ions, transition metal complexes, crystal field theory, second and third row transition metal complexes, antiferromagnetism, and spin-pairing of electrons. The final chapter describes important experimental methods and then to shows briefly the way in which the problems of interpretation may be tackled.

Table of Contents


  • Preface

    Definitions of Symbols

    I. Introduction

    Diamagnetic Corrections

    II. Free Atoms and Ions

    Single Electron System

    Multi-Electron System

    III. Transition Metal Complexes

    Valence Bond Theory

    Crystal Field Theory

    IV. Crystal Field Theory

    Van Vleck'S Formula for Susceptibility

    Strength of Ligand Fields

    Weak Field Case

    Strong Field Case

    Term Splitting and Electron Configuration

    Spin-Orbit Coupling A and E Terms

    Spin-Orbit Coupling on T Terms

    Second Order Zeeman Effect

    V. Further Topics

    Second and Third Row Transition Metal Complexes

    Antiferromagnetism

    Spin Free-Spin Paired Equilibria

    VI. Experimental

    Measurements

    Interpretation

    Appendix

    References

    Index

Product details

  • No. of pages: 126
  • Language: English
  • Copyright: © Academic Press 1968
  • Published: January 1, 1968
  • Imprint: Academic Press
  • eBook ISBN: 9781483270692

About the Author

Alan Earnshaw

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