Interpreting Infrared, Raman, and Nuclear Magnetic Resonance Spectra

Interpreting Infrared, Raman, and Nuclear Magnetic Resonance Spectra

1st Edition - April 6, 2001

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  • Author: Richard Nyquist
  • eBook ISBN: 9780080535135

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Description

This book teaches the analyst why it is advantageous to obtain vibrational data under different physical phases. Molecular vibrations are affected by change in physical phase, and knowledge of how certain molecular vibrations are affected by change in the chemical environment improves the analyst's ability to solve complex chemical problems.This book is invaluable for students and scientists engaged in analytical and organic chemistry, since application of IR and Raman spectroscopy is essential in identifying and verifying molecular structure.This reference provides analysts with information that enables them to acquire the maximum amount of information when sampling molecular vibrations via IR and Raman spectroscopy.

Key Features

@introbul:Key Features
@bul:* Explains why it is advantageous to obtain vibrational data under different physical phases
* Compiles many vibrational studies into a single compendium
* Lists group frequencies in different physical phases
* Reveals that some group frequencies are more affected than others by changes in the physical phase
* Demonstrates that in-phase and out-of-phase vibrations of the same functional group are not equally affected
* Describes how solute-solvent complexes differ with changes in the solvent system
* Shows that the amount of Fermi resonance between a fundamental vibration and a combination or overtone is altered with change of physical phase
* Written by an internationally recognized expert

Readership

Spectroscopists, analytical and organic chemists, chemical physicists, both in academia and especially industry.

Table of Contents

  • Volume 1:
    Theory of Vibrational Spectroscopy
    Experimental
    Alkyl Carbon-Hydrogen Vibrations
    Alkenes and Other Compounds Containing C=C Double Bonds
    Alkynes and Compounds Containing C=C Groups
    Carboxamides, Ureas, Thioureas,
    Imidazolidinones, Caffeine, Isocaffeine, Uracils,
    Imides, Hydantoins, and s-Triazine (1H, 3H, 5H)-
    Triones
    Aldehydes
    Ketones
    Carboxylic Acid Esters
    Organic Carbonates, Thiol Carbonates, Chloroformates, Thiol Chloroformates, Acetyl
    Chloride, Benzoyl Chloride, Carbamates, and an
    Overview of Solute-Solvent Effects Upon Carbonyl Stretching Frequencies

    Volume 2:
    Epoxides and Ethers
    Nitriles, Isonitriles, and Dialkyl Cyanamides
    Azines, Isocyanates, Isothiocyanates, and
    Carbodiimides
    Thiols, Sulfides and Disulfides, Alkanethiols, and
    Alkanedithiols (S--H stretching)
    Sulfoxides, Sulfones, Sulfates, Monothiosulfates,
    Sulfonyl Halides, Sulfites, Sulfonamides,
    Sulfonates, and N-Sulfinyl Anilines
    Halogenated Hydrocarbons
    Nitroalkanes, Nitrobenzenes, Alkyl Nitrates,
    Alkyl Nitrites, and Nitrosamines
    Phosphorus Compounds
    Benzene and Its Derivatives
    The Nyquist Vibrational Group Frequency Rule
    Infrared Raman and Nuclear Magnetic Resonance
    (NMR) Spectra-Structure Correlations for Organic
    Compounds

Product details

  • No. of pages: 1068
  • Language: English
  • Copyright: © Academic Press 2001
  • Published: April 6, 2001
  • Imprint: Academic Press
  • eBook ISBN: 9780080535135

About the Author

Richard Nyquist

Richard A. Nyquist has been recognized for his contributions to the field of Spectroscopy and Analytical Chemistry with the following awards: Williams-Wright Award from the Coblentz Society, ANACHEM Award from the Association of Analytical Chemists, V.A. Stenger Award and Water Graf European Award from Dow Chemical Company, and the ASTM Award of Appreciation. He was also named an honorary member of the Coblentz Society, and was a national tour speaker for the Society of Applied Spectroscopy. Nyquist received his B.S. in Chemistry from Augustan College, Rock Island, Illinois, his M.S. from Oklahoma State University, and his Ph.D. from Utrecht University, The Netherlands. He is currently president of Nyquist Associates, and is the author or co-author of over 160 scientific articles including books, book chapters, and patents.

Affiliations and Expertise

Nyquist Associates, Midland, Michigan, U.S.A.

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