This handbook is a comprehensive summary of the science, technology and manufacturing of semiconductor silicon materials. Every known property of silicon is detailed. A complete set of binary phase diagrams is included. Practical aspects such as materials handling, safety, impurity and defect reduction are also discussed in depth. Fundamentals in the areas of silicon precursor compounds, polysilicon, silicon crystal growth, wafer fabrication, epitaxial and CVD deposition are addressed by experts in these fields. Materials properties covered include electrical, optical and mechanical properties, deep level impurities and carrier lifetime, and thermochemistry, as well as specific sections on oxygen, carbon, and nitrogen impurities. The book contains an extensive set of references, tables of materials constants, and silicon properties, and a presentation on the state of the art of materials manufacturing.


Engineers and technologists in the semiconductor, optoelectronic, optics, cutting tool, refractory fibers, filter and other industries.

Table of Contents

1. Silicon Precursors: Their Manufacture and Properties 1.1 Introduction 1.2 Precursor Manufacture 1.3 Physical Properties and Critical Constants 1.4 Safety Appendix References 2. Polysilicon Preparation 2.1 The Technical History of Polycrystalline Silicon 2.2 Polysilicon Production Technology (Most Practiced) 2.3 Alternative Chlorine-Based, Semiconductor-Grade Polysilicon Feedstocks 2.4 Alternate Polysilicon Reactor Selections 2.5 Evaluation of Semiconductor-Grade Polysilicon 2.6 Future of Polysilicon References 3. Crystal Growth of Silicon 3.1 Introduction 3.2 Melt Growth Theory 3.3 Practical Aspect of Cz Crystal Growth 3.4 Novel Czochralski Crystal Growth 3.5 Trends in Silicon Crystal Growth 3.6 Summary and Conclusion References 4. Silicon Wafer Preparation 4.1 Introduction 4.2 Crystal Shaping 4.3 Wafering 4.4 Edge Contouring 4.5 Lapping 4.6 Polishing 4.7 Cleaning 4.8 Miscellaneous Operations 4.9 In-Process Measurements 4.10 Discussion References 5. Silicon Epitaxy 5.1 Introduction 5.2 Techniques for Silicon Epitaxy 5.3 Surface Preparation for Silicon Epitaxial Growth 5.4 Growth of Silicon Epitaxy by CVD 5.5 Dopant Incorporation 5.6 Surface Morphology and Epitaxial Defects 5.7 Pattern Shift and Distortion 5.8 Equipment for Epitaxy by CVD 5.9 Trends for the Future in Silicon Epitaxy References 6.


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© 1990
William Andrew
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"...comprehensive, up-to-date book..." - SAMPE Journal