Gas Phase Ion Chemistry

Gas Phase Ion Chemistry

Volume 1

1st Edition - July 28, 1979

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  • Editor: Michael T. Bowers
  • eBook ISBN: 9781483216485

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Description

Gas Phase Ion Chemistry, Volume 1 covers papers on the advances of gas phase ion chemistry. The book discusses the advances in flow tubes and the measurement of ion-molecule rate coefficients and product distributions; the ion chemistry of the earth's atmosphere; and the classical ion-molecule collision theory. The text also describes statistical methods in reaction dynamics; the state selection by photoion-photoelectron coincidence; and the effects of temperature and pressure in the kinetics of ion-molecule reactions. The energy distribution in the unimolecular decomposition of ions, as well as the rapidity of ion-molecule reactions are also encompassed. Chemists, physicists, and people working in aeronomy laboratory and involved in space research will find the book invaluable.

Table of Contents


  • List of Contributors

    Preface

    Contents of Volume 2

    Chapter I Recent Advances in Flow Tubes: Measurement of Ion-Molecule Rate Coefficients and Product Distribution

    I. Introduction

    II. The Flowing Afterglow

    III. The Flow-Drift Tube

    IV. The Selected Ion Flow Tube (SIFT)

    V. Future Developments

    References

    Chapter 2 Ion Chemistry of the Earth's Atmosphere

    I. Introduction

    II. E- and F-Region Ion Chemistry

    III. D-Region Positive Ion Chemistry

    IV. D-Region Negative Ion Chemistry

    V. Stratospheric and Tropospheric Positive Ion Chemistry

    VI. Stratospheric and Tropospheric Negative Ion Chemistry

    VII. Summary

    References

    Chapter 3 Classical Ion-Molecule Collision Theory

    I. Introduction

    II. Pure Polarization Theory

    III. Ion-Dipole Theory

    IV. Ion-Quadrupole Theory

    V. Effect of Induced Dipole-Induced Dipole Forces on Ion-Molecule Collisions

    VI. Other Theories

    VII. Summary and Prognosis

    Appendix A. Calculation of θ(r) and dθ{r)ld for the ADO cos θ Model

    Appendix B. Calculation of cos θ(r) for the ADO cos θ Model

    Appendix C. Calculation of the r-Dependent Average Rotational Energy in the Plane of Collision in the AADO Theory

    References

    Chapter 4 Statistical Methods in Reaction Dynamics

    I. Introduction

    II. Statistical Theory

    III. The Orbiting Transition State

    IV. Application to Chemical Systems

    V. Conclusions

    References

    Chapter 5 State Selection by Photoion-Photoelectron Coincidence

    I. Introduction

    II. Experimental Considerations

    III. Applications

    IV. Future Developments

    References

    Chapter 6 Temperature and Pressure Effects in the Kinetics of Ion-Molecule Reactions

    I. Introduction

    II. Temperature Effects in Bimolecular Exchange Reactions

    III. Temperature and Pressure Effects in Association Reactions

    IV. Temperature and Pressure Effects in the Thermal Decomposition of Gaseous Ions

    V. Conclusions

    References

    Chapter 7 Energy Distribution in the Unimolecular Decomposition of Ions

    I. Introduction

    II. Theoretical Considerations

    III. Experimental Methods

    IV. Results and Discussions

    V. Summary

    References

    Chapter 8 On the Rapidity of Ion-Molecule Reactions

    I. Introduction

    II. Some Characteristic Features of Ion-Molecule Reactions

    III. Application of Orbital Symmetry Conservation Rules and Correlation Diagrams to Ion-Molecule Reactions

    IV. Isotope Exchange Reaction of Ion-Molecule Collisions

    V. Exchange Reactions of Ion Clusters

    VI. Vibronic-Translation Relaxation of Ion-Atom Collisions

    VII. Some Rules for Qualitative Estimation of Rate Constants of Exothermic and Thermoneutral Ion-Molecule Reactions

    References

    Index


Product details

  • No. of pages: 368
  • Language: English
  • Copyright: © Academic Press 1979
  • Published: July 28, 1979
  • Imprint: Academic Press
  • eBook ISBN: 9781483216485

About the Editor

Michael T. Bowers

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