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Fundamentals of Carbanion Chemistry
- 1st Edition - January 1, 1965
- Author: Donald J. Cram
- Language: English
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 1 6 2 4 4 - 9
Organic Chemistry, Volume 4: Fundamentals of Carbanion Chemistry provides information pertinent to carbanion chemistry. This book explores several topics, including carbonium ions,… Read more
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Request a sales quoteOrganic Chemistry, Volume 4: Fundamentals of Carbanion Chemistry provides information pertinent to carbanion chemistry. This book explores several topics, including carbonium ions, carbanions, carbenes, and carbon radicals. Comprised of six chapters, this volume starts with an overview of the variation of the kinetic and thermodynamic acidities of carbon acids with substituents and environments. This text then explores the methods of carbanion stabilization by substituents and discusses the various types of stabilization. Other chapters explain the stereochemistry of hydrogen–deuterium exchange and examine the stereochemistry of substitution reactions of organometallic compounds. This book discusses as well the structure and immediate environment of reaction intermediates through the use of stereochemical techniques. The final chapter considers the unsaturated anionic rearrangements of carbanions, carbonium ions, as well as carbon radicals and other rearrangements. Chemists, organic chemists, researchers, and graduate students interested in the field of carbanion chemistry will find this book extremely useful.
PrefaceChapter I Carbon Acids Thermodynamic Acidity Scales Correlations between Thermodynamic and Kinetic Acidity Kinetic Acidities of Weak Hydrocarbon Acids Effect of Medium on Kinetic and Equilibrium Acidity of Carbon AcidsChapter II Carbanion Structure and Mechanism of Stabilization s-Character Effects Conjugative Effects Inductive Effects Homoconjugative Effects Aromatization Effects Negative Hyperconjugative Effects d-Orbital EffectsChapter III Stereochemistry of Substitution of Carbon Acids and Organometallic Compounds Carbon Acids That Form Symmetrical or near Symmetrical Carbanions Systems That Form Unsymmetrical Carbanions Special Case of Carbanions Confined in Three-Membered Rings Homoconjugated Carbanions Stereochemistry of Substitution of Organometallic CompoundsChapter IV Stereochemistry of Carbanions Generated with Different Leaving Groups Carbon as Leaving Group in Electrophilic Substitution at Saturated Carbon Other Leaving Groups in Electrophilic Substitution at Saturated Carbon Comparison of the Stereochemical Capabilities of Carbanions and Carbonium IonsChapter V Isomerization by Proton Transfer in Unsaturated Systems Intramolecularity Geometric Stability of Allylic Anions Hydrocarbon Substituent Effects on the Rates of Allylic Rearrangements of Alkenes Olefin Equilibria Collapse Ratios for Allylic AnionsChapter VI Molecular Rearrangements Ring-Chain Anionic Rearrangements 1,2-Rearrangements Rearrangements with 1,3-Elimination Reaction StagesAuthor IndexSubject Index
- No. of pages: 298
- Language: English
- Edition: 1
- Published: January 1, 1965
- Imprint: Academic Press
- eBook ISBN: 9780323162449
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