Fundamentals of Carbanion Chemistry - 1st Edition - ISBN: 9780123957603, 9780323162449

Fundamentals of Carbanion Chemistry

1st Edition

Authors: Donald J. Cram
eBook ISBN: 9780323162449
Imprint: Academic Press
Published Date: 1st January 1965
Page Count: 298
Sales tax will be calculated at check-out Price includes VAT/GST
25% off
25% off
25% off
25% off
25% off
20% off
20% off
25% off
25% off
25% off
25% off
25% off
20% off
20% off
25% off
25% off
25% off
25% off
25% off
20% off
20% off
54.95
41.21
41.21
41.21
41.21
41.21
43.96
43.96
43.99
32.99
32.99
32.99
32.99
32.99
35.19
35.19
72.95
54.71
54.71
54.71
54.71
54.71
58.36
58.36
Unavailable
Price includes VAT/GST
× DRM-Free

Easy - Download and start reading immediately. There’s no activation process to access eBooks; all eBooks are fully searchable, and enabled for copying, pasting, and printing.

Flexible - Read on multiple operating systems and devices. Easily read eBooks on smart phones, computers, or any eBook readers, including Kindle.

Open - Buy once, receive and download all available eBook formats, including PDF, EPUB, and Mobi (for Kindle).

Institutional Access

Secure Checkout

Personal information is secured with SSL technology.

Free Shipping

Free global shipping
No minimum order.

Description

Organic Chemistry, Volume 4: Fundamentals of Carbanion Chemistry provides information pertinent to carbanion chemistry. This book explores several topics, including carbonium ions, carbanions, carbenes, and carbon radicals. Comprised of six chapters, this volume starts with an overview of the variation of the kinetic and thermodynamic acidities of carbon acids with substituents and environments. This text then explores the methods of carbanion stabilization by substituents and discusses the various types of stabilization. Other chapters explain the stereochemistry of hydrogen–deuterium exchange and examine the stereochemistry of substitution reactions of organometallic compounds. This book discusses as well the structure and immediate environment of reaction intermediates through the use of stereochemical techniques. The final chapter considers the unsaturated anionic rearrangements of carbanions, carbonium ions, as well as carbon radicals and other rearrangements. Chemists, organic chemists, researchers, and graduate students interested in the field of carbanion chemistry will find this book extremely useful.

Table of Contents


Preface

Chapter I Carbon Acids

Thermodynamic Acidity Scales

Correlations between Thermodynamic and Kinetic Acidity

Kinetic Acidities of Weak Hydrocarbon Acids

Effect of Medium on Kinetic and Equilibrium Acidity of Carbon Acids

Chapter II Carbanion Structure and Mechanism of Stabilization

s-Character Effects

Conjugative Effects

Inductive Effects

Homoconjugative Effects

Aromatization Effects

Negative Hyperconjugative Effects

d-Orbital Effects

Chapter III Stereochemistry of Substitution of Carbon Acids and Organometallic Compounds

Carbon Acids That Form Symmetrical or near Symmetrical Carbanions

Systems That Form Unsymmetrical Carbanions

Special Case of Carbanions Confined in Three-Membered Rings

Homoconjugated Carbanions

Stereochemistry of Substitution of Organometallic Compounds

Chapter IV Stereochemistry of Carbanions Generated with Different Leaving Groups

Carbon as Leaving Group in Electrophilic Substitution at Saturated Carbon

Other Leaving Groups in Electrophilic Substitution at Saturated Carbon

Comparison of the Stereochemical Capabilities of Carbanions and Carbonium Ions

Chapter V Isomerization by Proton Transfer in Unsaturated Systems

Intramolecularity

Geometric Stability of Allylic Anions

Hydrocarbon Substituent Effects on the Rates of Allylic Rearrangements of Alkenes

Olefin Equilibria

Collapse Ratios for Allylic Anions

Chapter VI Molecular Rearrangements

Ring-Chain Anionic Rearrangements

1,2-Rearrangements

Rearrangements with 1,3-Elimination Reaction Stages

Author Index

Subject Index

Details

No. of pages:
298
Language:
English
Copyright:
© Academic Press 1965
Published:
Imprint:
Academic Press
eBook ISBN:
9780323162449

About the Author

Donald J. Cram

Ratings and Reviews