Excited States - 1st Edition - ISBN: 9780122272066, 9781483275482

Excited States

1st Edition

Volume 6

Editors: Edward C. Lim
eBook ISBN: 9781483275482
Imprint: Academic Press
Published Date: 28th November 1982
Page Count: 236
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Description

Excited States, Volume 6 is a collection of papers that discusses the excited states of molecules. The first paper discusses the linear polyene electronic structure and potential surfaces, considering both the theoretical and experimental approaches in such electronic states. This paper also reviews the theory of electronic structure and cites some experimental techniques on polyene excitations, polyene spectroscopic phenomenology, and those involving higher states of polyenes and their triplet states. Examples of these experimental studies of excited states involve the high-resolution one-photon absorption spectroscopy, two photon spectroscopy, electron-impact spectroscopy, radiationless decay rates, and radiative fluorescence lifetimes. Some unresolved issues remain such as the resolution of the excited-state order in butadiene and the two isomers of hexatriene. The second paper describes the energetics and scattering of mixed exciton-photon states in organic crystals that should form part of future research in the field of organic solids. This paper also describes mixed exciton-photon states, exciton-phonon, and polariton-phonon scattering. This book will prove invaluable for researchers and scientists working in the field of micro-chemistry and solid-state physics.

Table of Contents


Contributors

Contents of Previous Volumes

Linear Polyene Electronic Structure and Potential Surfaces

I. Introduction

II. Ground-State Geometry

III. Electronic States

IV. Electronic Structure: Theory

V. Linear Polyene s-cis, s-trans Isomerization

VI. Polyene Vibrational Spectroscopy and Force Fields

VII. Experimental Studies of Excited States

VIII. Infinite Polyenes: Bond Alternation and Spectral Convergence

IX. Conclusions

References

Energetics and Scattering of Mixed Exciton-Photon States in Organic Crystals

I. Mixed Exciton-Photon States: Introduction

II. Classical Theory of Excitons Coupled to the Radiation Field

III. Second-Quantization Theory of Polaritons

IV. Exciton- Phonon and Polariton-Phonon Scattering

V. Nonlinear Polariton Effects

References

Index


Details

No. of pages:
236
Language:
English
Copyright:
© Academic Press 1982
Published:
Imprint:
Academic Press
eBook ISBN:
9781483275482

About the Editor

Edward C. Lim