Electron Transfer Reactions of Complex Ions in Solution
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Electron Transfer Reactions of Complex Ions in Solution covers the significant development of some important area of electron transfer reactions of complex ions. This four-chapter book emerged from a series of lectures at the Polytechnic Institute of Brooklyn in November and December 1967. Chapter I presents research studies in cation hydration. This chapter describes principal methods for composition determination of the first coordination spheres of the aquo ions. Chapter II examines the distinction between reactions in which electron transfer takes place from one primary bond system to another. Chapter III discusses some aspects of ligand effects in electron-transfer reactions. This chapter demonstrates that differences in the behavior of systems can be expected at least in the extremes of mechanisms. Chapter IV deals with the history, principles and applications of the induced electron-transfer effect. This book is of great value to electrochemists, students, and researchers.
Table of Contents
Foreword
Chapter I. Introduction Of The Reagents: Studies In Hydration Of Cations
I. Introduction
II. Summary of Results
III. Application of the Methods
IV. Relations Between Substitution Rates
V. Comments on Rates Summarized in Table 1-1
VI. Problems
References
Chapter II. Description Of The Activated Complexes For Electron Transfer
I. Introduction
II. The Outer-Sphere Activated Complex
III. The Inner-Sphere Activated Complex
References
Chapter III. Some Aspects Of Ligand Effects In Electron Transfer Reactions
I. Introduction
II. Simple Ligands
III. Activation Parameters
IV. The Mechanism of Electron Transfer
V. Conclusion
References
Chapter IV. Induced Electron Transfer
I. Introduction
II. History
III. Evidence for the Formation of an Intermediate
IV. The Oxidation of Pentaamminepyridinemethanolcobalt (III) by Ce(IV)
V. Low-Spin Co(II) as an Intermediate
VI. Other Systems
References
Subject Index
Product details
- No. of pages: 112
- Language: English
- Copyright: © Academic Press 1970
- Published: January 28, 1970
- Imprint: Academic Press
- eBook ISBN: 9780323161138
About the Author
Henry Taube
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