Electrodeposition of Alloys

Preface Acknowledgments Contents of Volume I Part III Practical Considerations and Specific Information on the Electrodeposition of Alloys (Continued) Alloy Group B. Mutual Alloys of Cadmium, Lead, Tin, and Zinc 22. Electrodeposition of Lead-Tin Alloys 22.1 Introduction 22.2 Literature 22.3 Electrodeposition of Lead-Tin Alloys from the Fluoborate Bath 22.4 Electrodeposition of Lead-Tin Alloys from Baths Other Than the Fluoborate 22.5 Curves of Current Density vs. Cathode Potential in the Electrodeposition of Lead-Tin Alloys 22.6 Appearance and Structure of Electrodeposited Lead-Tin Alloys 22.7 Properties of Electrodeposited Lead-Tin Alloys 22.8 Protective Value of Coatings of Lead-Tin Alloys 22.9 Reclamation of Lead and Tin as the Alloy 22.10 Miscellaneous Applications of Electrodeposited Lead-Tin Alloys 22.11 Electrodeposition of Ternary Alloys from a Modified Lead-Tin Fluoborate Bath References 23. Electrodeposition of Tin-Zinc Alloys 23.1 Introduction 23.2 Early Literature 23.3 Types of Baths 23.4 The Stannate-Cyanide Tin-Zinc Alloy Plating Bath 23.5 Electrodeposition of Tin-Zinc Alloys from the Complexone Bath 23.6 Pyrophosphate Bath 23.7 Acid Baths 23.8 Passivation of Tin-Zinc Coatings 23.9 Structure and Appearance of Electrodeposited Tin-Zinc Alloys 23.10 Properties of Electrodeposited Tin-Zinc Alloys 23.11 Corrosion Resistance and Protective Value of Tin-Zinc Coatings 23.12 Uses of the Alloy 23.13 Stripping of Deposits 23.14 Analysis of Deposits and Plating Baths and Measurement of Thickness of Deposits 23.15 Specification 23.16 Electrodeposition of Lead-Zinc Alloys References 24. Electrodeposition of Cadmium-Tin Alloys 24.1 Introduction 24.2 Literature 24.3 Types of Baths 24.4 Electrodeposition of Cadmium-Tin Alloys from Acid Baths 24.5 Electrodeposition of Cadmium-Tin Alloys from the Stannate-Cyanide Bath 24.6 Structure of Cadmium-Tin Alloys 24.7 Static Potentials of Alloys 24.8 Protective Value and Corrosion Resistance of Electrodeposited Cadmium-Tin Alloys 24.9 Some Miscellaneous Properties of the Alloy 24.10 Electrodeposition of Cadmium-Lead Alloys References 25. Electrodeposition of Cadmium-Zinc and Related Ternary Alloys 25.1 Introduction 25.2 Electrodeposition of Cadmium-Zinc Alloys from Cyanide Baths 25.3 Electrodeposition of Cadmium-Zinc Alloys from Simple Salt Baths 25.4 Appearance and Structure of Electrodeposited Cadmium-Zinc Alloys 25.5 Properties and Protective Value of Cadmium-Zinc Alloys 25.6 Electrodeposition of Ternary Alloys Containing Cadmium, Zinc, and Tin or Mercury ReferencesAlloy Group C. Electrodeposition of Alloys of Chromium, Indium, Thallium, Manganese, and Some of the Other Less Noble Metals 26. Electrodeposition of Chromium Alloys 26.1 Introduction 26.2 Electrodeposition of Chromium Alloys from the Chromic Acid Bath 26.3 Electrodeposition of Chromium Alloys from Baths Containing Trivalent Chromium Salts References 27. Electrodeposition of Manganese Alloys 27.1 Introduction 27.2 Literature 27.3 Problems in the Electrodeposition of Manganese and Its Alloys 27.4 Electrodeposition of Alloys of Manganese Containing Iron, Nickel, or Cobalt 27.5 Electrodeposition of Manganese-Copper Alloys 27.6 Electrodeposition of Manganese-Zinc Alloys 27.7 Electrodeposition of Manganese-Tin Alloys 27.8 Electrodeposition of Manganese-Selenium Alloys 27.9 Electrodeposition of Other Manganese Alloys References 28. Electrodeposition of Alloys of Indium, Thallium, and Gallium 28.1 General Survey 28.2 Electrodeposition of Alloys of Indium 28.3 Electrodeposition of Alloys of Thallium 28.4 Electrodeposition of Gallium Alloys References 29. Attempts to Electrodeposit Alloys of Some of the More Active Metals 29.1 General Discussion 29.2 Factors That Aid the Codeposition of the More Active Metals 29.3 Paucity of Examples of Individual Deposition or Codeposition of Active Metals 29.4 Attempts to Electrodeposit Alloys of Magnesium 29.5 Attempts to Codeposit Aluminum 29.6 Attempts to Deposit Alloys Containing Titanium or Zirconium 29.7 Attempts to Codeposit Miscellaneous Other Active Metals References Alloy Group D . Electrodeposition of Some of the More Important Alloys of the Iron-Group Metals, With Special Reference to Anomalous Codeposition 30. Electrodeposition of Alloys Containing an Iron-Group Metal and Zinc or Cadmium 30.1 Zinc Alloys of the Iron-Group Metals 30.2 Electrodeposition of Cadmium-Nickel Alloys References 31. Electrodeposition of the Mutual Alloys of the Iron-Group Metals 31.1 General Survey 31.2 Literature 31.3 Survey of the Plating Processes for Depositing Mutual Alloys of the Iron-Group Metals 31.4 Electrodeposition of Cobalt-Nickel Alloys from Simple Salt Baths 31.5 Electrodeposition of Cobalt-Nickel Alloys from Baths of Complex Ions 31.6 Notes on the Analysis of the Cobalt-Nickel Plating Bath and the Testing of the Deposits 31.7 Electrodeposition of Iron-Nickel Alloys from Simple Salt Baths 31.8 Electrodeposition of Iron-Nickel Alloys from Baths of Complex Ions 31.9 Electrodeposition of Iron-Cobalt Alloys from Simple Salt Baths 31.10 Electrodeposition of Cobalt-Iron-Nickel Alloys from Simple Salt Baths 31.11 Potentials Involved in the Codeposition of the Metals of the Iron-Group from Simple Salt Solutions 31.12 The Anomalous Nature of the Mutual Codeposition of the Iron-Group Metals 31.13 Structure of the Electrodeposited Mutual Alloys of the Iron-Group Metals 31.14 Properties of Electrodeposited Iron-Group Metals 31.15 Uses of the Electrodeposited Alloys of the Iron-Group Metals References 32. Electrodeposition of Alloys of the Iron-Group Metals Containing Tin or Lead 32.1 Survey 32.2 Electrodeposition of Nickel-Tin Alloys 32.3 Electrodeposition of Nickel-Lead Alloys 32.4 Electrodeposition of Cobalt-Tin Alloys References Alloy Group E. Induced Codeposition of Alloys Containing Tungsten, Molybdenum, Germanium, or Phosphorus 33. Electrodeposition of Tungsten Alloys Containing Cobalt, Nickel, and/or Iron 33.1 Introduction 33.2 Literature 33.3 Electrodeposition of Alloys from Acid Solutions 33.4 Electrodeposition of Tungsten Alloys of the Iron-Group Metals from Alkaline Baths 33.5 Relation between Cathode Potentials and Current Density in the Deposition of Tungsten Alloys 33.6 Nonmetallic Inclusions in the Deposits 33.7 Appearance of Electrodeposited Tungsten Alloys 33.8 Structure of Electrodeposited Tungsten Alloys 33.9 Properties of Electrodeposited Tungsten Alloys 33.10 Potential Uses of Electrodeposited Tungsten Alloys 33.11 Electrodeposition of Tungsten Alloys Containing Metals Other Than the Iron-Group Metals 33.12 Attempts to Explain the Mechanism and the Characteristics of the Induced Codeposition of Tungsten References 34. Electrodeposition of Alloys Containing Molybdenum and Nickel, Cobalt, or Iron 34.1 Introduction 34.2 Literature 34.3 General Survey of Baths for Electrodepositing Molybdenum Alloys 34.4 Acid Baths for Electrodepositing Molybdenum Alloys 34.5 Electrodeposition of Molybdenum Alloys from Ammoniacal Baths 34.6 Electrodeposition of Molybdenum Alloys from the Pyrophosphate Bath 34.7 Electrodeposition of Cobalt-Molybdenum Alloys from the Carbonate Bath 34.8 Electrodeposition of Iron-Molybdenum Alloy from a Caustic Bath 34.9 Electrodeposition of Cobalt- or Iron-Molybdenum Alloys from Miscellaneous Alkaline Baths Containing Organic Compounds 34.10 Appearance, Structure, and Properties of Electrodeposited Alloys of Molybdenum and the Iron-Group Metals 34.11 Electrodeposition of Other Molybdenum Alloys 34.12 Mechanism of the Induced Codeposition of Molybdenum References 35. Electrodeposition of Alloys Containing Phosphorus and Nickel or Cobalt 35.1 Introduction 35.2 Composition of Plating Baths and Conditions of Plating 35.3 Effect of Plating Variables on Composition of Electrodeposited Phosphorus Alloys 35.4 Induced Codeposition and the cd-ptl Relations of the Phosphorus Alloys 35.5 Properties of Electrodeposited Phosphorus Alloys 35.6 Protective Value Afforded to Steel by Coatings of Phosphorus Alloys 35.7 Applications of Electrodeposited Phosphorus Alloys 35.8 Analyses of Baths and Deposits References 36. Electrodeposition of Germanium Alloys 36.1 Introduction 36.2 Electrodeposition of Copper-Germanium Alloy 36.3 Electrodeposition of Alloys of Germanium Containing Nickel, Cobalt, or Silver 36.4 Electrodeposition of Tin and Zinc Alloys of Germanium 36.5 Gallium-Germanium Alloy References Alloy Group F. Electrodeposition of Alloys of Several Metals More Noble than Hydrogen 37. Electrodeposition of Gold Alloys 37.1 Background 37.2 Literature 37.3 Principles of Gold Plating from the Cyanide Bath 37.4 The Electrodeposition of Decorative Gold Alloys of Various Colors 37.5 Electrodeposition of Gold-Copper Alloys 37.6 Electrodeposition of Gold-Silver Alloys 37.7 Electrodeposition of Gold-Nickel and Gold-Cobalt Alloys 37.8 Electrodeposition of Ternary and Quaternary Alloys Containing Gold and Copper, Silver, or Nickel 37.9 Electrodeposition of Gold-Antimony Alloys 37.10 Electrodeposition of Miscellaneous Alloys of Gold 37.11 Thick Gold Alloy Deposits 37.12 Electrodeposition of Gold Alloys from Acid Baths 37.13 Analysis of Gold Alloy Plating Baths References 38. Electrodeposition of Alloys of the Platinum Metals 38.1 General 38.2 Alloys of the Platinum Metals with the Iron-Group Metals and Other Base Metals 38.3 Mutual Alloys of the Platinum Metals 38.4 Summary References 39. Electrodeposition of Alloys Containing Antimony or Arsenic 39.1 Alloys of Antimony 39.2 Electrodeposition of Alloys of Arsenic References 40. Electrodeposition of Alloys of Bismuth 40.1 Introduction 40.2 Electrodeposition of Bismuth-Copper Alloys 40.3 Electrodeposition of Bismuth-Silver Alloys 40.4 Electrodeposition of Bismuth-Lead Alloys References 41. Electrodeposition of Alloys Containing Rhenium and the Iron-Group Metals 41.1 Background 41.2 Electrodeposition of Alloys of Rhenium 41.3 Properties of Electrodeposited Rhenium Alloys 41.4 Miscellaneous References 42. Electrodeposition of Alloys Containing Sulfur 42.1 Introduction 42.2 Electrodeposition of Nickel-Sulfur Alloys 42.3 Miscellaneous Sulfur Alloys References Author Index Subject Index Patent Index-Volumes I and II