Direct Synthesis of Coordination and Organometallic Compounds - 1st Edition - ISBN: 9780444720009, 9780080530444

Direct Synthesis of Coordination and Organometallic Compounds

1st Edition

Authors: A.D. Garnovskii B.I. Kharisov
Hardcover ISBN: 9780444720009
eBook ISBN: 9780080530444
Imprint: Elsevier Science
Published Date: 13th August 1999
Page Count: 244
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Description

Preface

Chapter 1 - Cryosynthesis of Metal Complexes
Introduction 1. Methods, Conditions, Equipment, Reagents 2. Synthesis of Metal Complexes with Simple Inorganic Ligands 3. Cryosynthesis of &pgr; and &sgr; Metal Complexes 4. Vapor Synthesis of Metal Chelates.

Chapter II - Electrochemical Synthesis of Metal Complexes
Introduction 1. General Concepts about Electrochemical Synthesis, a) Practical Aspects b) Solvent and Supporting Electrolyte c) Types of Cells d) Electrolytic Parameters 2. Electrosynthesis at Sacrificial Anode a) Synthesis of Molecular Complexes (Adducts) b) Synthesis of Metal Chelates c) Synthesis of Di- and Polymetallic Complexes d) Synthesis of &sgr; and &pgr; Organometallic Complexes 3. Electrosynthesis at Sacrificial Cathode.

Chapter III - Oxidative Dissolution of Metals and Metal Oxides in a Liquid Phase
Introduction 1. Kinetics of Dissolution of Metal Powders and Metal Oxides 2. Direct Synthesis Using Halogenated Hydrocarbon 3. Direct Synthesis in Solutions of Proton-Donor Reagents 4. Direct Synthesis with Ammonium Salts Solutions a) Complexes Containing Ammonia and Solvent Molecules b) Compounds Containing Complex Anions c) Complexes with Pyridine d) Complexes with Ethylenediamine and its Derivatives e) Complexes with Aminoalcohols 5. Interaction of Metals with Quinones and Phthalocyanine Precursors.

Chapter IV - Mechanosynthesis of Coordination Compounds
Introduction 1. Complex-Formation in the System "Metal-CC14-DMSO" 2. Interaction Between Copper and Salycilaldehyde 3. Interaction Between Copper and Azomethinic Ligands 4. Interaction Between Copper and Schiff Bases of 1-phenyl-3-methylpyrasolone-5 and its S- and Se-Containing Analogues 5. Interaction Between Copper and Oxyazo Compounds 6. Interaction Between Copper and Nickel with 8-Oxyquinoline and its Derivatives 7. Interaction Between Copper and Iron with Acetylacetone and 1-(Tenoil-2)-3, 3, 3-Trifluoroacetone 8. Interaction Between Copper with N-Acylsalicylamide Solutions 9. Interaction Between Copper with Disalicylamide 10. Formation of Coordination Metal-Polymers.

Chapter V - Some Peculiarities of Crystal Structure of Complexes Obtained by the Direct Synthesis

Table of Contents

Preface

Chapter 1 - Cryosynthesis of Metal Complexes
Introduction 1. Methods, Conditions, Equipment, Reagents 2. Synthesis of Metal Complexes with Simple Inorganic Ligands 3. Cryosynthesis of &pgr; and &sgr; Metal Complexes 4. Vapor Synthesis of Metal Chelates.

Chapter II - Electrochemical Synthesis of Metal Complexes
Introduction 1. General Concepts about Electrochemical Synthesis, a) Practical Aspects b) Solvent and Supporting Electrolyte c) Types of Cells d) Electrolytic Parameters 2. Electrosynthesis at Sacrificial Anode a) Synthesis of Molecular Complexes (Adducts) b) Synthesis of Metal Chelates c) Synthesis of Di- and Polymetallic Complexes d) Synthesis of &sgr; and &pgr; Organometallic Complexes 3. Electrosynthesis at Sacrificial Cathode.

Chapter III - Oxidative Dissolution of Metals and Metal Oxides in a Liquid Phase
Introduction 1. Kinetics of Dissolution of Metal Powders and Metal Oxides 2. Direct Synthesis Using Halogenated Hydrocarbon 3. Direct Synthesis in Solutions of Proton-Donor Reagents 4. Direct Synthesis with Ammonium Salts Solutions a) Complexes Containing Ammonia and Solvent Molecules b) Compounds Containing Complex Anions c) Complexes with Pyridine d) Complexes with Ethylenediamine and its Derivatives e) Complexes with Aminoalcohols 5. Interaction of Metals with Quinones and Phthalocyanine Precursors.

Chapter IV - Mechanosynthesis of Coordination Compounds
Introduction 1. Complex-Formation in the System "Metal-CC14-DMSO" 2. Interaction Between Copper and Salycilaldehyde 3. Interaction Between Copper and Azomethinic Ligands 4. Interaction Between Copper and Schiff Bases of 1-phenyl-3-methylpyrasolone-5 and its S- and Se-Containing Analogues 5. Interaction Between Copper and Oxyazo Compounds 6. Interaction Between Copper and Nickel with 8-Oxyquinoline and its Derivatives 7. Interaction Between Copper and Iron with Acetylacetone and 1-(Tenoil-2)-3, 3, 3-Trifluoroacetone 8. Interaction Between Copper with N-Acylsalicylamide Solutions 9. Interaction Between Copper with Disalicylamide 10. Formation of Coordination Metal-Polymers.

Chapter V - Some Peculiarities of Crystal Structure of Complexes Obtained by the Direct Synthesis

Details

No. of pages:
244
Language:
English
Copyright:
© Elsevier Science 1999
Published:
Imprint:
Elsevier Science
eBook ISBN:
9780080530444
Hardcover ISBN:
9780444720009

About the Author

A.D. Garnovskii

Affiliations and Expertise

Rostov State University, Russia

B.I. Kharisov

Boris I. Kharisov

Master Researcher, Chemistry Department

University of Nuevo León, Monterrey, México

Dr. Boris I. Kharisov (born in 1964, in Russia, has lived in Mexico from 1994, and naturalized in Mexico in 2003) is currently a Professor and Researcher at the Universidad Autónoma de Nuevo León (UANL). He took part in the liquidation of the consequences of the Chernobyl accident, working in the contaminated zone in 1987. Degrees: An MS in 1986, in radiochemistry and a PhD in inorganic chemistry in 1993, from the Moscow State University, Russia; Dr. Hab. in physical chemistry in 2006 from Rostov State University, Russia. Memberships: Mexican Academy of Science, National Researchers System (SNI, Level II), Materials Research Society. He is the co-author of nine books, 151 articles, eight book chapters, and holds four patents. Co-editor: Three invited special issues of international journals. He is the member of the Editorial board of three journals. Specialties: Coordination and inorganic chemistry, phthalocyanines, ultrasound, nanotechnology, chemical treatment of petroleum, environmental remediation.

Dr. Kharisov also co-edited 1999 Elsevier publication, Direct Synthesis of Coordination and Organometallic Compounds, with Dr. Garnovskii.

Affiliations and Expertise

Universidad Autónoma de Nuevo León, Mexico