Cycloaddition Reactions of Heterocumulenes

Cycloaddition Reactions of Heterocumulenes

1st Edition - January 1, 1967

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  • Author: Henri Ulrich
  • eBook ISBN: 9780323162760

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Description

Cycloaddition Reactions of Heterocumulenes reviews cycloaddition reactions, particularly on hetercocumulenes having "four-electron" bonds. This book discusses the chemical relationship among the various classes of heterocumulenes, including their chemical reactivity which ranges from highly reactive species to nearly inert compounds. This text also investigates the nucleophilic reactions of ketenes and isocyanates with suitable substrates, and if possible, correlates available data with the reactivity of these species in cycloaddition reactions. This book also investigates the cycloaddition reactions of carbon suboxide and other aspects of its chemistry due to the presence of many other interrelated reactions. The synthetic organic chemist should also investigate the application of isocyanate reactions associated with the cumulative double bonds. This text investigates carbodiimides as useful reagents for peptide synthesis, and notes that the stability of carbodiimides increases significantly with sterical hindrance around the cumulative double bond system. This book discusses three compounds that have a central electrophilic carbon atom, namely, carbon dioxide, carbonyl sulfide, and carbon disulfide. The book also describes the cycloaddition reactions of sulfenes, of N-sulfinylamines, of N-sulfinylsulfonamides, and of sulfurdiimides. This book can prove useful for researchers, technicians, and scientists whose works involve organic chemistry, analytical chemistry, and other related fields of chemistry.

Table of Contents


  • Preface

    Chapter I. General Introduction

    I. Scope

    II. Reactivity

    III. Cycloaddition Reactions

    IV. Physiochemical Data

    References

    Chapter II. Ketenes

    I. Introduction

    II. Homopolymerization

    III. 1,2-Cycloaddition Reactions

    IV. 1,3-Cycloaddition Reactions

    V. 1,4-Cycloaddition Reactions

    References

    Chapter III. Carbon Suboxide

    I. Introduction

    II. Cycloaddition Reactions

    III. Nucleophilic Reactions

    IV. Photochemical Reactions

    References

    Chapter IV. Isocyanates

    I. Introduction

    II. Homopolymerization

    III. 1,2-Cycloaddition Reactions

    IV. 1,3-Cycloaddition Reactions

    V. 1.4-Cycloaddition Reactions

    References

    Chapter V. Isothiocyanates

    I. Introduction

    II. 1,2-Cycloaddition Reactions

    III. 1,3-Cycloaddition Reactions

    IV. 1,4-Cycloaddition Reactions

    References

    Chapter VI. Carbodiimides

    I. Introduction

    II. Homopolymerization

    III. 1,2-Cycloaddition Reactions

    IV. 1,3-Cycloaddition Reactions

    V. 1,4-Cycloaddition Reactions

    References

    Chapter VII. Carbon Dioxide, Carbonyl Sulfide, and Carbon Disulfide

    I. Introduction

    II. 1,2-Cycloaddition Reactions

    III. 1,3-Cycloaddition Reactions

    References

    Chapter VIII. Sulfenes

    I. Introduction

    II. 1,2-Cycloaddition Reactions

    III. 1,3-Cycloaddition Reactions

    IV. 1,4-Cycloaddition Reactions

    References

    Chapter IX. N-Sulfinylamines, N-Sulfinylsulfonamides, and Sulfurdiimides

    I. Introduction

    II. 1,2-Cycloaddition Reactions

    III. 1.3-Cycloaddition Reactions

    IV. 1,4-Cycloaddition Reactions

    V. Sulfurdiimide Reactions

    References

    Appendix

    Text

    References

    Author Index

    Subject Index

Product details

  • No. of pages: 374
  • Language: English
  • Copyright: © Academic Press 1967
  • Published: January 1, 1967
  • Imprint: Academic Press
  • eBook ISBN: 9780323162760

About the Author

Henri Ulrich

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