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Critical Evaluation of Some Equilibrium Constants Involving Organophosphorus Extractants is a supplementary text to the compilation "Equilibrium Constants of Liquid-Liquid Distribution Reactions (Introduction, and Part I: Organophosphorus Extractants).
The book contains a number of well documented chemical reactions that are critically evaluated. The reactions evaluated comprise those from List 1 for which data are available. There are, however, a great variety of reactions that cannot be critically evaluated due to lack of experimental data and unverifiable results.
Chemists will find this compendium very useful.
I H+ + DBP- = HDBP
II HDBP = HDBP
III 2 HDBP = (HDBP)2
IV 1/2 (HDBP)2 + TBP = HDBP · TBP and (HDBP)2 + TBP = (HDBP)2 · TBP
VI H2O + TBP = H2O · TBP
VII H+ + NO-3 + TBP = HNO3 · TBP
VIII H+ + Cl- + TBP = HC1 · TBP
IX H+ + DE-HP- = HDE-HP; HDE-HP = HDE-HP; 2 HDE-HP = (HDE-HP)2
X 1/2(HDE-HP)2 + TBP (or TOPO) = HDE-HP · TBP (or TOPO); (HDE-HP)2 + TBP (or TOPO) = (HDE-HP)2 · TBP (or TOPO)
XI UO2+ 2 + 2NO-3 + 2 TBP = UO2(NO3)2(TBP)2
XII Pu4+ + 4NO-3 + 2 TBP = Pu(NO3)4(TBP)2
XIII H+ + NO-3 + TOPO = HNO3 · TOPO
XIV UO2+ 2 + 2NO-3 + 2TBPO = UO2(NO3)2(TB'PO)2
XV H+ + NO-3 + DBB'P = HNO3 · DBB'P
XVI UO2+ 2 + 2NO-3 + 2 DBB'P = UO2(NO3)2(DBB'P)2
- No. of pages:
- © Butterworth-Heinemann 1974
- 1st January 1974
- eBook ISBN: