Copper(I) Chemistry of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles - 1st Edition - ISBN: 9780128150528

Copper(I) Chemistry of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles

1st Edition

Editors: Maravanji Balakrishna
Paperback ISBN: 9780128150528
Imprint: Elsevier
Published Date: 1st May 2019
Page Count: 470
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Copper(I) Complexes of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles is a comprehensive guide to one of the most widely used and extensively studied metals: copper. The numerous practical applications of copper compounds are discussed, including homogeneous and heterogeneous catalysis and their use as fungicides, pesticides, pigments for paints, resins and glasses, and in high-temperature superconductors. The remarkable structural flexibility of simple copper(I) complexes, such as cuprous halides is covered, including numerous structural motifs that, when combined with different ligand systems, exhibit linear, trigonal planar or tetrahedral geometries.

This work is an essential reference for inorganic and coordination chemists, as well as researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects.

Key Features

  • Discusses the properties of copper and similarities to noble metals, such as their corrosion resistance, high thermal and electrical conductivity and rich coordination chemistry
  • Includes the copper(I) coordination chemistry of tertiary phosphines, bisphosphines and phosphines containing other donor atoms and their potential application in catalysis, biosystems and photochemical areas
  • Features a discussion of the rich photochemistry exhibited by some mixed-ligand copper(I) complexes (phosphines with heteroaromatic ligands) which can exhibit coprophilic interactions, photoluminescence and thermochromic properties


Inorganic and Organic chemists, Coordination Chemists, Researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects

Table of Contents

  1. Copper chemistry of tertiary phosphines
    2. Copper chemistry of triphenylphosphine
    3. Copper chemistry of bis(diphenylphosphino)methane
    4. Copper chemistry of bis(dimethylphosphino)ethane
    5. Copper chemistry of functionalized phosphines
    6. Copper chemistry of cyclodiphosphazanes
    7. Copper chemistry of pyridylphosphines
    8. Copper chemistry of large bit bisphosphines
    9. Copper chemistry of phosphorous based pincer ligands
    10. Copper chemistry of phosphines appended with nitrogen containing heterocycles
    11. Photophysical aspects of copper(I)-phosphines complexes
    12. Catalytic applications of copper(I)-phosphine complexes
    13. Structure and bonding aspects of copper(I)-phosphines compelxes
    14. Copper(I)-phosphines complexes as anticancer reagents
    15. Copper(I)-phosphines in material and electronic devices
    16. Copper chemistry of rare and unusual bisphosphines


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© Elsevier 2019
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About the Editor

Maravanji Balakrishna

Maravanji S. Balakrishna has been teaching inorganic chemistry since 1996 and currently is Professor at the Indian Institute of Technology Bombay. He has published more than 170 papers in international journals on phosphorus-based ligands and their metal complexes and various applications. His research interests include main group chemistry, coordination and organometallic chemistry of mono-, bis-, tris- and polyphosphines, and functionalized phosphines, homogeneous catalysis, and anticancer studies.

Affiliations and Expertise

Professor, Indian Institute of Technology, Bombay

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