Comprehensive Organometallic Chemistry III - 1st Edition - ISBN: 9780080446011

Comprehensive Organometallic Chemistry III

1st Edition

Volume 11: Applications III - Transition metal organometallics in organic synthesis 2

Series Volume Editors: Tamejiro Hiyama
Hardcover ISBN: 9780080446011
Imprint: Elsevier Science
Published Date: 21st November 2006
Page Count: 766
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Institutional Access

Table of Contents

C–C Bond Formation (Part 2) By Cross-Coupling
11.01 C–C Bond Formation by Cross-coupling
11.02 Reductive Coupling Reactions Promoted by Low-valent Early Transition Metals and Lanthanoids
C–C Bond Formation (Part 2) By Substitution Reactions
11.03 C–C Bond Formation (Part 2) by Substitution Reactions: Allylic Alkylation
11.04 C–C Bond Formation (Part 2) by Substitution Reactions: Substitution at Propargylic and Benzylic Positions Synthetic Reactions of MTC and MTN Bonds
11.05 Synthetic Reactions of MTC and MTN Bonds: Ylide Formation, Rearrangement, and 1,3-Dipolar Cycloaddition
Metathesis Reactions
11.06 Olefin Cross-Metathesis
11.07 Ring-closing Olefin Metathesis for Organic Synthesis
11.08 Ene–Yne and Alkyne Metathesis
Simultaneous C–C and Other Bond Formation
11.09 Sequential Formation of More than One C–C and Other Bonds by Multiple Heck-type Reactions
11.10 Pauson–Khand Reaction
11.11 Silane-initiated Carbocyclization Catalyzed by Transition Metal Complexes
11.12 Carbonylative Cross-coupling and Carbocyclization
11.13 Hydroformylation, Other Hydrocarbonylations, and Oxidative Alkoxycarbonylation
11.14 Silylformylation
11.15 Amidocarbonylation, Cyclohydrocarbonylation, and Related Reactions
Transition Metal Catalysts in Polymer Synthesis
11.16 Polymerization of Acetylenes
11.17 Polymerization of Epoxides
11.18 Ring-opening Metathesis Polymerization (ROMP)
11.19 Cross-coupling Polymerization
11.20 Polymerization of Alkenes


Along with volume 10, this volume reviews how transition metal organometallic compounds are used in organic synthesis. Chapters are organised by reaction type to be readily accessible by organic chemists. Classes of reactions reviewed include C-C bond formation, reaction of double bonds, metathesis reactions, carbonylation and polymer synthesis.

Key Features

  • valuable content available May 2009 as an individual volume
  • separate volumes will appeal to a wider chemistry and materials science audience
  • priced for individual researcher as well as library purchase
  • Readership

    Suitable for organic and inorganic chemists researchers and students in the fields of materials science and nanoscience. Practitioners working in industry who need to use or apply organometallic compounds.


    No. of pages:
    © Elsevier Science 2007
    Elsevier Science
    Hardcover ISBN:

    About the Series Volume Editors

    Tamejiro Hiyama Series Volume Editor

    Affiliations and Expertise

    Kyoto University, Kyoto, Japan