- Print ISBN 9780444512239
- Electronic ISBN 9780080529172
Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.
Synthesis of Clathrochelates. Synthesis of macrobicyclic tris-dioximates. Synthesis of macrobicyclic phosphorus-containing d-metal tris-diiminates. Synthesis of sepulchrates and sarcophaginates. Synthesis of polyene and other types of clathrochelate complexes.
Spatial and Electronic Structure of Clathrochelates. Sarcophaginates and sepulchrates. Macrobicyclic phosphorus-containing d-metal tris-diiminates. Macrobicyclic d-metal tris-dioximates. Polyene and other types of clathrochelate complexes.
Kinetics and Mechanism of Synthesis and Decomposition of Clathrochelates. Experimental approaches. Reactions of boron-capped iron(II) dioximates. Reactions of sarcophaginates and sepulchrates.
Properties of Clathrochelates. Ion association of clathrochelates in solution. Electron-transfer processes in macrobicyclic complexes. Photochemical properties of macrobicyclic complexes.
Application Possibilities of Clathrochelate Chemistry.
New Types of Clathrochelates: Perspectives of Synthesis. Ribbed-functionalized d-metal tris-dioximates. Mononuclear and polynuclear &agr;-dioximates and -&agr;oximehydrazonates obtained by capping with several p-block elements (arsenic, bismuth, and some others), d- and f-elements. Macrobicyclic Schiff bases formed by capping with Lewis acids. Clathrochelate complexes formed by the analogs of &agr;-dioximes and &agr;-oximehydrazones. Superclathrochelate structures.