Chemistry and Application of H-Phosphonates - 1st Edition - ISBN: 9780444527370, 9780080476490

Chemistry and Application of H-Phosphonates

1st Edition

Authors: Kolio D. Troev
Hardcover ISBN: 9780444527370
eBook ISBN: 9780080476490
Imprint: Elsevier Science
Published Date: 19th July 2006
Page Count: 336
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Description

Chapter 1. Methods for preparation and physical properties of H-phosphonates
1.1. From phosphorus trichloride and alcohols
1.2. From H-phosphonic acid
1.3. From white phosphorus and alcohols

1.4. Others
1.5. Physical properties

1.6. Thermal stability

Chapter 2. Structure and spectral characteristics of H-phosphonates 2.1. Electronic structure of phosphorus atom
2.2. Nature of the chemical bonds in phosphoryl group
2.3. Molecular structure of dimethyl H-phosphonate
2.4. Tautomerization of dialkyl H-phosphonates
2.5. Spectral characteristics

Chapter 3. Reactivity of H-phosphonates 3.1. Acidity of H-phosphonate diesters
3.2. Disproportionation

3.3. Reduction
3.4. Hydrolysis

3.5. Acidolysis

3.6. Substitution reactions at the phosphorus atom

Chapter 4. Important classes of compounds 4.1. Aminophosphonic acids

4.2. Bisphosphonates
4.3. Nucleoside H-phosphonates
4.4. Epoxyalkylphosphonates
4.5. Poly(alkylene H-phosphonate)s

4.6. Metal salts of dialkyl H-phosphonates

4.7. Complexes of dialkyl H-phosphonates

Chapter 5. Application of H–phosphonates and their derivatives 5.1. Physiologically-active substances
5.2. Polymer additives
5.3. Degrading and alkylating agents of polymers
5.4. Heat, light and UV stabilizers

5.5. Catalysts
5.6. Corrosion inhibitors

5.7. Scale inhibitors

5.8. Lubricants

Key Features

  • provides ideas for the synthesis of phosphonates, phosphoramides and diesters of phosphonic acid (new phosphorus-containing compounds)
  • reviews structure, spectra and biological activity of H-phosphonates and their derivatives
  • examines new areas of application of phosphorus-containing compounds

Readership

For Professors, researchers, students and practitioners working in the fields of organophosphorus Chemistry, Organic Chemistry, Polymer Chemistry, Pharmacy, Production of polymers with reduced flammability, Production of agrochemicals, Medicinal Chemistry

Table of Contents

Chapter 1. Methods for preparation and physical properties of H-phosphonates
1.1. From phosphorus trichloride and alcohols
1.2. From H-phosphonic acid
1.3. From white phosphorus and alcohols

1.4. Others
1.5. Physical properties

1.6. Thermal stability

Chapter 2. Structure and spectral characteristics of H-phosphonates 2.1. Electronic structure of phosphorus atom
2.2. Nature of the chemical bonds in phosphoryl group
2.3. Molecular structure of dimethyl H-phosphonate
2.4. Tautomerization of dialkyl H-phosphonates
2.5. Spectral characteristics

Chapter 3. Reactivity of H-phosphonates 3.1. Acidity of H-phosphonate diesters
3.2. Disproportionation

3.3. Reduction
3.4. Hydrolysis

3.5. Acidolysis

3.6. Substitution reactions at the phosphorus atom

Chapter 4. Important classes of compounds 4.1. Aminophosphonic acids

4.2. Bisphosphonates
4.3. Nucleoside H-phosphonates
4.4. Epoxyalkylphosphonates
4.5. Poly(alkylene H-phosphonate)s

4.6. Metal salts of dialkyl H-phosphonates

4.7. Complexes of dialkyl H-phosphonates

Chapter 5. Application of H–phosphonates and their derivatives 5.1. Physiologically-active substances
5.2. Polymer additives
5.3. Degrading and alkylating agents of polymers
5.4. Heat, light and UV stabilizers

5.5. Catalysts
5.6. Corrosion inhibitors

5.7. Scale inhibitors

5.8. Lubricants

Details

No. of pages:
336
Language:
English
Copyright:
© Elsevier Science 2006
Published:
Imprint:
Elsevier Science
eBook ISBN:
9780080476490
Hardcover ISBN:
9780444527370

About the Author

Kolio D. Troev

Kolio Dimov Troev completed his undergraduate work at Higher Institute of Chemical Technology, Sofia; received his doctorate in the field of organophosphorus chemistry in 1974 from the Institute of Organic Chemistry, Bulgarian Academy of Sciences with Prof. Georgy Borissov; and was awarded the scientific degree “Doctor of Science” in 1985 from the Institute of Polymers. In 1988, he became Professor of Chemistry at the same Institute. He has been the founding head of the laboratory “Phosphorus-containing monomers and polymers” since 1989. His research interests are the areas of organophosphorus chemistry, especially esters of H-phosphonic acid; aminophosphonates; biodegradable, biocompatible phosphorus-containing polymers; polymer conjugates; drug delivery systems. He has been a visiting professor/lecturer in the USA (Marquette University, Tulane University), Japan (Tokyo Institute of Technology, University of Tokyo, Tohoku University, Tokyo University of Science), and Germany (Duesseldorf University). He is the author of more than 150 papers in this field published in the Phosphorus, Sulfur, Silicon and Related Elements, Heteroatom Chemistry, Journal of American Chemical Society, European Polymer Journal, Polymer, Bioorganic & Medicinal Chemistry, Journal of Medicinal Chemistry, Macromolecular Rapid Communication, Polymer Degradation and Stability, Journal of Polymer Science, Part A: Polymer Chemistry, European Journal of Medicinal Chemistry, Amino Acids, Tetrahedron Letters, Macromolecules, and RSC Advances. He is also the author of two other Elsevier books, Chemistry and Application of H-phosphonates (2006) and Polyphosphoesters: Chemistry and Application (2012).

He was a director of the Institute of Polymers, Bulgarian Academy of Sciences from November 2003 to February 2012.

Affiliations and Expertise

Institute of Polymers, Bulgarian Academy of Sciences, Sofia, Bulgaria