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Charge and Energy Storage in Electrical Double Layers presents the basic scientific concepts and implementation of procedures devised to obtain capacitive energy from changes i… Read more
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Charge and Energy Storage in Electrical Double Layers presents the basic scientific concepts and implementation of procedures devised to obtain capacitive energy from changes in the potential of electrical double layers when the salinity of solutions is changed. Capacitive deionization— the closely connected reciprocal process—is also considered. The book covers the fundamentals of electrical double layers and ions transport in porous media, the description of promising techniques of energy extraction, and the practical problems involved in each. It is written for scientists in academia and industry, and for graduate students working in supercapacitors, capacitive mixing and deionization.
Scientists in academia and industry, chemical engineers, and graduate students working in the field of supercapacitors, capacitive mixing, and capacitive deionization
Section 1. Fundamentals of the Electrical Double Layer
1. Charge and potential distribution in the electrical double layer of porous materials
2. The electrical double layer as a capacitor
3. Kinetics of ion transport in a porous electrode
Section 2. Materials
4. Materials selection for capacitive electrodes
Section 3. Capacitive Energy Extraction from Double Layer Expansion (CDLE)
5. Fundamentals of the method
6. Implementation
Section 4. Capacitive Energy Extraction by Donnan Potential (CDP)
7. Fundamentals of the method
8. Cell design and membrane selection
Section 5. Capacitive Deionization (CDI)
9. Principles and theoretical models of CDI
10. Experimental approaches. Use of membranes for improved deionization
Section 6. Conclusions
11. Future and perspectives of the capacitive techniques
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