Alkylation of Carbon. Alkylations of enols and enolates. Alkylations of nitrogen-stabilized carbanions. Alkylations of sulphur-and selenium-stabilized carbanions. Alkylations of other heteroatom-stabilized carbanions. Alkylations of nonstabilized carbanions. Alkylations of vinyl carbanions. Alkylations of alkynyl carbanions. Friedel-Crafts alkylations. Polyene cyclizations. Transannular electrophilic cyclizations. Coupling Reactions. Coupling reactions between sp3 carbon centers. Coupling reactions between sp3 and sp2 carbon centers. Coupling reactions between sp2 carbon centers. Coupling reactions between sp2 and sp carbon centers. Coupling reactions between sp carbon centers. Pinacol coupling reactions. Acyloin coupling reactions. Kolbe reactions. Oxidative coupling of phenols and phenol ethers. Rearrangement Reactions. Wagner-Meerwein rearrangements. The Pinacol rearrangement. Acid-catalyzed rearrangements of epoxides. The semipinacol and other rearrangements. Dienone-phenol rearrangements and related reactions. Benzil-benzilic acid rearrangements. The Favorskii rearrangement. The Ramberg-Bäcklund rearrangement. The Wolff rearrangement. The Stevens and related rearrangements. The Wittig rearrangement. Other Carbon-Carbon Bond Forming Reactions. Carbonylation and decarbonylation reactions. Carbon-carbon bond formation by C-H insertion. Author index. Subject index.