Bridged Aromatic Compounds - 1st Edition - ISBN: 9780123957481, 9780323163217

Bridged Aromatic Compounds

1st Edition

Authors: Brandes Smith
eBook ISBN: 9780323163217
Imprint: Academic Press
Published Date: 1st January 1964
Page Count: 566
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Organic Chemistry, Volume 2: Bridged Aromatic Compounds covers the research studies on cyclophane chemistry, bridged ferrocenes, and other similar compounds.
This volume contains 10 chapters. The first five chapters describe the nomenclature, synthesis, reactions, chemistry, and dissymmetry of bridged aromatic compounds. The subsequent four chapters discuss the application of selected analytical methods to delineate the chemistry of these compounds, including UV and infrared absorption spectroscopy, X-ray methods, and nuclear and electron magnetic resonance. The last chapter provides tabulations of the more common physical properties reported for bridged aromatic compounds. Organic chemists and researchers and undergraduate and graduate organic chemistry students will greatly appreciate this book.

Table of Contents

Preface Acknowledgments Nomenclature Polymethylene or Disubstituted Aromatic System Phenylene System Benzo System Ansa System Bicyclo System Cyclophane System A New System Preparation The Acyloin Cyclization Method The Friedel-Crafts Cyclization Method The Halo-Amine Cyclization Method The Halo-Ether Cyclization Method The Wurtz Reaction The Ziegler Cyclization Method Cyclization by Pyrolysis of Acids and Their Salts Pyrolysis of Hydrocarbons The Hofmann Elimination Reaction Method Cyclization by Pyrolysis of Other Compounds The Ring-Contraction Method Cyclization by Oxidative Coupling Nonaromatic Routes to Bridged Aromatics The Depolymerization Cyclization Method The Dieckmann Cyclization Method Cyclization by Amide Formation Cyclization by Imine Formation Miscellaneous Methods of Preparing Cyclophanes Porphyrins and Related Compounds Containing Bridged Aromatic Nuclei Natural Products Containing Cyclophane Links References Chemistry of the Bridged Nucleus Carbon-Hydrogen Substituents Halogen and Halogen-Containing Substituents Oxygen-Containing Substituents Nitrogen-Containing Substituents Sulfur-Containing Substituents Rearrangement of Cyclophane Bridges Hydrogenation of the Aromatic Nucleus Molecular Complexes of the Cyclophanes Inclusion Compounds of the Cyclophanes Photochemical Studies Dehydrogenation of Cyclophanes to Polycyclics Diels-Alder Reactions References Chemistry of the Bridge Carbon-Hydrogen Substituents Oxygen-Containing Substituents Halogen Substituents Nitrogen and Sulfur Substituents Methylene Acidity Bridgehead Oxidations References Dissymmetry of the Bridged Aromatics Text References Ult


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© Academic Press 1964
Academic Press
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Brandes Smith

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