Bridged Aromatic Compounds - 1st Edition - ISBN: 9780123957481, 9780323163217

Bridged Aromatic Compounds

1st Edition

Authors: Brandes Smith
eBook ISBN: 9780323163217
Imprint: Academic Press
Published Date: 1st January 1964
Page Count: 566
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Description

Organic Chemistry, Volume 2: Bridged Aromatic Compounds covers the research studies on cyclophane chemistry, bridged ferrocenes, and other similar compounds.
This volume contains 10 chapters. The first five chapters describe the nomenclature, synthesis, reactions, chemistry, and dissymmetry of bridged aromatic compounds. The subsequent four chapters discuss the application of selected analytical methods to delineate the chemistry of these compounds, including UV and infrared absorption spectroscopy, X-ray methods, and nuclear and electron magnetic resonance. The last chapter provides tabulations of the more common physical properties reported for bridged aromatic compounds. Organic chemists and researchers and undergraduate and graduate organic chemistry students will greatly appreciate this book.

Table of Contents


Preface

Acknowledgments

Nomenclature

Polymethylene or Disubstituted Aromatic System

Phenylene System

Benzo System

Ansa System

Bicyclo System

Cyclophane System

A New System

Preparation

The Acyloin Cyclization Method

The Friedel-Crafts Cyclization Method

The Halo-Amine Cyclization Method

The Halo-Ether Cyclization Method

The Wurtz Reaction

The Ziegler Cyclization Method

Cyclization by Pyrolysis of Acids and Their Salts

Pyrolysis of Hydrocarbons

The Hofmann Elimination Reaction Method

Cyclization by Pyrolysis of Other Compounds

The Ring-Contraction Method

Cyclization by Oxidative Coupling

Nonaromatic Routes to Bridged Aromatics

The Depolymerization Cyclization Method

The Dieckmann Cyclization Method

Cyclization by Amide Formation

Cyclization by Imine Formation

Miscellaneous Methods of Preparing Cyclophanes

Porphyrins and Related Compounds Containing Bridged Aromatic Nuclei

Natural Products Containing Cyclophane Links

References

Chemistry of the Bridged Nucleus

Carbon-Hydrogen Substituents

Halogen and Halogen-Containing Substituents

Oxygen-Containing Substituents

Nitrogen-Containing Substituents

Sulfur-Containing Substituents

Rearrangement of Cyclophane Bridges

Hydrogenation of the Aromatic Nucleus

Molecular Complexes of the Cyclophanes

Inclusion Compounds of the Cyclophanes

Photochemical Studies

Dehydrogenation of Cyclophanes to Polycyclics

Diels-Alder Reactions

References

Chemistry of the Bridge

Carbon-Hydrogen Substituents

Oxygen-Containing Substituents

Halogen Substituents

Nitrogen and Sulfur Substituents

Methylene Acidity

Bridgehead Oxidations

References

Dissymmetry of the Bridged Aromatics

Text

References

Ultraviolet Absorption Spectroscopy

Text

References

Infrared Absorption Spectroscopy

Text

References

X-Ray and Other Structural Studies

Text

References

Nuclear and Electron Magnetic Resonance Studies

Nuclear Magnetic Resonance

Electron Paramagnetic Resonance

References

Tables of Compounds

Tables

References

Author Index

Subject Index


Details

No. of pages:
566
Language:
English
Copyright:
© Academic Press 1964
Published:
Imprint:
Academic Press
eBook ISBN:
9780323163217

About the Author

Brandes Smith