Base-Catalyzed Reactions of Hydrocarbons and Related Compounds - 1st Edition - ISBN: 9780125571500, 9780323144827

Base-Catalyzed Reactions of Hydrocarbons and Related Compounds

1st Edition

Authors: Herman Pines
eBook ISBN: 9780323144827
Imprint: Academic Press
Published Date: 1st January 1977
Page Count: 602
Sales tax will be calculated at check-out Price includes VAT/GST
25% off
25% off
25% off
25% off
25% off
20% off
20% off
25% off
25% off
25% off
25% off
25% off
20% off
20% off
25% off
25% off
25% off
25% off
25% off
20% off
20% off
72.95
54.71
54.71
54.71
54.71
54.71
58.36
58.36
54.95
41.21
41.21
41.21
41.21
41.21
43.96
43.96
43.99
32.99
32.99
32.99
32.99
32.99
35.19
35.19
Unavailable
Price includes VAT/GST
× DRM-Free

Easy - Download and start reading immediately. There’s no activation process to access eBooks; all eBooks are fully searchable, and enabled for copying, pasting, and printing.

Flexible - Read on multiple operating systems and devices. Easily read eBooks on smart phones, computers, or any eBook readers, including Kindle.

Open - Buy once, receive and download all available eBook formats, including PDF, EPUB, and Mobi (for Kindle).

Institutional Access

Secure Checkout

Personal information is secured with SSL technology.

Free Shipping

Free global shipping
No minimum order.

Description

Base-Catalyzed Reactions of Hydrocarbons and Related Compounds focuses on the use of bases as catalysts for the conversion of hydrocarbons and related compounds. In order to emphasize the broad scope of base-catalyzed reactions, examples dealing with the conversion of non-hydrocarbons are given.

Comprised of 14 chapters, this book begins with a historical overview of base-catalyzed conversions of hydrocarbons, followed by a discussion on the isomerization of olefins, acetylenes, and allenes, as well as the dimerization and oligomerization of hydrocarbons. The reader is then introduced to a variety of reactions, including those between aromatic hydrocarbons and olefins and between alkylpyridines and alkenylpyridines; homogeneous carbon-carbon addition reactions; and reactions of aprotic solvents with olefins. Subsequent chapters explore carbon-carbon addition of olefins with miscellaneous compounds; addition of ammonia, amines, and anilines to olefinic hydrocarbons; hydrogenation and oxygenation; dehydrogenation, aromatization, and hydrogen transfer; and dehydration of alcohols.

This monograph will be of interest to chemists.

Table of Contents


Preface

Abbreviations Used

1 Introduction

1.1 Historical Background

1.2 Acidity of Weak Acids

1.3 Catalysts

References

2 Isomerization of Olefins

2.1 Introduction

2.2 Isomerization of Monoalkenes

2.3 Dienes and Polyenes

2.4 Isomerization of Heterosubstituted Monoalkenes

2.5 Cycloisomerization

References

3 Isomerization of Acetylenes and Allenes

3.1 Introduction

3.2 Aliphatic Monoacetylenes

3.3 Cycloalkynes

3.4 Isomerization to Terminal Acetylenes

3.5 Isomerization of Polyfunctional Acetylenic Hydrocarbons

3.6 Isomerization of Heterosubstituted Monoacetylenes

3.7 Cycloisomerization

References

4 Dimerization and Oligomerization

4.1 Introduction

4.2 Hydrocarbons

4.3 α,β-Unsaturated Esters and Nitriles

References

5 Reactions of Aromatic Hydrocarbons with Olefins

5.1 Introduction

5.2 Alkylation of Aromatic Hydrocarbons

5.3 Alkenylation of Alkylbenzenes

5.4 Aralkylation of Alkylbenzenes

5.5 Aralkylation of Polycyclic Aromatic Hydrocarbons

References

6 Reactions of Alkylpyridines and Alkenylpyridines

6.1 Introduction

6.2 Alkylation

6.3 Alkenylation

6.4 Aralkylation of Alkylpyridines with Styrenes

6.5 Disproportionation and Transaralkylation Reactions

6.6 Reactions of 2- and 4-Alkylpyridines with 2- and 4-Vinylpyridine

6.7 Cyclization of ω-Pyridyl-1-alkenes

References

7 Homogeneous Carbon-Carbon Addition Reactions

7.1 Introduction

7.2 Addition of Alkylaromatic Compounds to Conjugated Hydrocarbons

7.3 Reactions of Butadiene with Nitriles, Carbonyl Compounds and Aromatic Hydrocarbons

7.4 Dimerization of 1,4-Dihydronaphthalene

References

8 Reactions of Aprotic Solvents with Olefins

8.1 Introduction

8.2 N-Methyl-2-pyrrolidone and N-Methyl-2-piperidone with Olefins and Diolefins

8.3 Dimethyl Sulfoxide with Hydrocarbons and Related Compounds

8.4 Ethers

References

9 Carbon-Carbon Addition of Olefins with Miscellaneous Compounds

9.1 Saturated Carboxylic Acid Salts with Ethylene

9.2 Cyanoethylation of Cyclic Dienic Hydrocarbons

9.3 Alkenylation and Aralkylation of Aldimines

References

10 Addition of Ammonia, Amines, and Anilines to Olefinic Hydrocarbons

10.1 Introduction

10.2 Amination of Olefins

10.3 Amination of Conjugated Dienes and Vinylaromatics

10.4 Anilination of Olefins

References

11 Hydrogenation

11.1 Introduction

11.2 Hydrogenation of Ethylene

11.3 Hydrogenation of Higher Hydrocarbons

11.4 Hydrogen-Deuterium Exchange Reactions

References

12 Dehydrogenation, Aromatization, and Hydrogen Transfer

12.1 Introduction

12.2 Aromatization

12.3 Aromatization of Germinal Alkylcyclohexadienes and Their Isomers

12.4 Hydrogen Transfer

12.5 Hydrogen Transfer Accompanying Miscellaneous Reactions

References

13 Oxidation

13.1 Introduction

13.2 Triton B Catalyst

13.3 Alumina-Sodium Methoxide Catalyst

13.4 Alkali Metal Alkoxide-Solvent Catalyst Systems

References

14 Dehydration of Alcohols

14.1 Introduction

14.2 β,γ- and γ,δ-Unsaturated Alkanols

14.3 β,γ- and γ,δ-Unsaturated Cycloalkanols

14.4 Unsaturated Sesqui- and Diterpeneols

14.5 Aromatic Alcohols

References

Author Index

Subject Index

Details

No. of pages:
602
Language:
English
Copyright:
© Academic Press 1977
Published:
Imprint:
Academic Press
eBook ISBN:
9780323144827

About the Author

Herman Pines

Northwestern University Evanston, Illinois

Affiliations and Expertise

Northwestern University

Ratings and Reviews