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Asymmetrie Synthesis, Volume 2: Stereodifferentiating Addition Reactions, Part A is concerned with asymmetric addition reactions.
This volume contains chapters that cover B-H additions across carbon-carbon and carbon-oxygen double bonds; carbonyl reductions using chiral modifications of lithium aluminum hydride and chiral dihydropyridines; additions of achiral and chiral nucleophiles to chiral and achiral aldehydes and ketones; organometal additions to chiral vinylic sulfoxides; and description of imine and enamine alkylations.
Chemists will find the book interesting.
1. Asymmetric Hydroboration
2. Reductions with Chiral Boron Reagents
II. Chirally Modified Boranes
III. Chirally Modified Borohydrides
3. Reductions with Chiral Modifications of Lithium Aluminum Hydride
II. Alcohol-Modified Lithium Aluminum Hydride
III. Amine-Modified Lithium Aluminum Hydride
IV. Amino Alcohol-Modified Lithium Aluminum Hydride
V. Aminodiol-Modified Lithium Aluminum Hydride
4. Reductions with Chiral Dihydropyridine Reagents
II. Summary of the Mechanistic Studies of NADH Model Reactions
III. Asymmetric Reductions with Chiral NADH Model Compounds
IV. Factors Affecting Product Stereochemistry in Asymmetric Reductions with Chiral NADH Model Compounds
V. Approach to Chiral NADH Models of Higher Stereoselectivity
VI. Simulation of Enzyme Active Site Composed of Peptide Chain
VII. Concluding Remarks
5. Application of Cram's Rule: Addition of Achiral Nucleophiles to Chiral Substrates
II. Variation of Reaction Conditions
III. Application of Cram's Rule to Asymmetric Synthesis
IV. Remote Stereochemical Control
6. Addition of Chiral Nucleophiles to Aldehydes and Ketones
II. Organometallic Reagents Used in a Chiral Environment
III. Addition of Carbanions a to a Chiral Sulfoxide Group
IV. Chiral Ester Enolates
7. Noncatalytic Additions to α,β-Unsaturated Carbonyl Compounds
II. Conjugate Additions of Chiral α,β-Unsaturated Carbonyl Derivatives
III. Conjugate Additions with Chiral Nucleophiles
8. Addition of Organometallic Reagents to Chiral Vinylic Sulfoxides
II. 1-Alkenyl Sulfoxides
III. 2-Alkenyl Sulfoxides
IV. 2-Cycloalkenone Sulfoxides
9. Alkylation of Imine and Enamine Salts
II. Formation of Azaallyl Metal Reagents and Enamines
III. Structure of Azaallyl Metal Reagents
IV. Electrophilic Substitution of Azaallyl Metal Regents and Enamines
V. Asymmetric Syntheses Employing Chiral Azaallyl Metal Reagents
VI. Asymmetric Syntheses Employing Chiral Enamines
- No. of pages:
- © Academic Press 1983
- 1st December 1983
- Academic Press
- eBook ISBN:
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