Annual Reports in Organic Synthesis—1977 - 1st Edition - ISBN: 9780120408085, 9781483104003

Annual Reports in Organic Synthesis—1977

1st Edition

Editors: R. Bryan Miller L. G. Wade
eBook ISBN: 9781483104003
Imprint: Academic Press
Published Date: 28th January 1978
Page Count: 472
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Description

Annual Reports in Organic Synthesis—1977 presents an annual review of synthetically useful information that would prove beneficial to nearly all organic chemists, both specialist and nonspecialist in synthesis. It should help relieve some of the information storage burden of the specialist and should aid the nonspecialist who is seeking help with a specific problem to become rapidly aware of recent synthetic advances. In producing this volume the editors abstracted 47 primary chemistry journals, selecting useful synthetic advances. All reactions and methods which are new, synthetically useful, and reasonably general are included. Each entry is comprised primarily of structures accompanied by very few comments. The purpose of this is to aid the reader in rapidly scanning the book.

Chapters I-III are organized by reaction type and constitute the major part of the book. Chapter IV deals with methods of synthesizing heterocyclic systems. Chapter V covers the use of new protecting groups. Chapter VI is divided into three main parts and covers those synthetically useful transformations that do not fit easily into the first three chapters. The first part deals only with functional group synthesis. The second part covers ring expansion and contraction, and the third part involves useful multistep sequences.

Table of Contents


Preface

Journals Abstracted

I. Carbon—Carbon Bond Forming Reactions

A. Carbon—Carbon Single Bonds (see also: I.E., I.F., I.G.)

1. Alkylation of Aldehydes, Ketones, and Their Derivatives (see also: I. A.7)

2. Alkylations of Nitriles, Acids, and Acid Derivatives

3. Alkylation of ß-Dicarbonyl and ß-Cyano-carbonyl Systems

4. Alkylation of N, S, or Se Stabilized Carbanions

5. Alkylation of Organometallic Reagents (see also: I.F.2, I.G.)

6. Other Alkylation Procedures and Reviews

7. Nucleophilic Addition of Electron Deficient Carbon (see also: I.G.)

8. Other Carbon—Carbon Single Bond Forming Reactions

B. Carbon—Carbon Double Bonds (see also: III.G)

1. Wittig-Type Olefination Reactions

2. Eliminations

3. Other Carbon—Carbon Double Bond Forming Reactions

4. Allene Forming Reactions

C. Carbon—Carbon Triple Bonds

D. Cyclopropanations

1. Carbene or Carbenoic Addition to a Multiple Bond

2. Other Cyclopropanations

E. Thermal Reactions (see also: VI.B)

1. Cycloadditions

2. Other Thermal Reactions

F. Aromatic Substitutions Forming a New Carbon—Carbon Bond

1. Friedel—Crafts-Type Reactions

2. Coupling Reactions (see also: I.G)

3. Other Aromatic Substitutions

G. Synthesis via Organometallics

1. Organoboranes

2. Carbonylation Reactions

3. Other Syntheses via Organometallics

4. Reviews

II. Oxidations

A. C—O Oxidations

1. Alcohol → Ketone, Aldehyde

2. Alcohol, Aldehyde → Acid, Acid Derivative

B. C—H Oxidations

1. C—H → C—O

2. C—H → C—Hal

3. Other C—H Oxidations

C. C—N Oxidations

D. Amine Oxidations

E. Sulfur Oxidations

F. Oxidative Additions to C—C Multiple Bonds

1. Epoxidations

2. Hydroxylation

3. Other

G. Phenol → Quinone Oxidation

H. Oxidative Cleavages

I. Photosensitized Oxygenations

J. Dehydrogenation

K. Other Oxidations and Reviews

III. Reductions

A. C = O Reductions

B. Nitrile Reductions

C. Reduction of Sulfur Compounds

D. N—O Reductions

E. C—C Multiple Bond Reductions

1. C=C Reductions

2. C≡C Reductions

3. Reduction of Aromatic Rings

F. Hydrogenolysis of Hetero Bonds

1. C—O → C—H

2. C—Hal → C—H

3. C—S → C—H

4. C—N → C—H (see also: III.H)

G. Reductive Eliminations

H. Reductive Cleavages

I. Hydroboration (reduction only)

J. Other Reductions and Reviews

IV. Synthesis of Heterocycles

A. Aziridines

B. Furans, etc.

C. Indoles

D. Lactams

E. Lactones

F. Pyridines, Quinolines, etc.

G. Pyrroles, etc.

H. Other Heterocycles with One Heteroatom

I. Heterocycles with Two or More Heteroatoms

1. Heterocycles with 2 N's

2. Heterocycles with 1 N and 1 O

3. Heterocycles with 1 N and I S

4. Heterocycles with 1 S and 1 O

5. Heterocycles with 3 N's

6. Other Heterocycles

J. General Reviews

V. Protecting Groups

A. Hydroxyl

B. Amine

C. Sulfhydryl

D. Carboxyl

E. Ketone, Aldehyde

F. Phosphate

G. Pi Bond

H. Miscellaneous Protecting Groups

VI. Useful Synthetic Preparations

A. Functional Group Preparations

1. Acids, Acid Halides, etc. (see also: II.A.2)

2. Alcohols, Phenols (see also: III.A)

3. Alkyl, Aryl Halides (see also: II.B.2)

4. Amides (see also: IV.D, VI.A.17)

5. Amines (see also: III.B, III.D)

6. Amino Acids and Derivatives

7. Carbenes (see also: I.D)

8. Enamines

9. Epoxides (see also: II.F.1)

10. Esters (see also: IV.E)

11. Ethers

12. Ketones and Aldehydes (see also: II.A.1, III.F.1, III.F.4)

13. Nitriles (see also: II.D, II.J)

14. Nitro (see also: II.D)

15. Nucleotides, etc. (see also: IV.1.1a,b)

16. Olefins, Acetylenes (see also: I.B, I.C, II.J, III.G)

17. Peptides (see also: V.B, V.D)

18. Vinyl Halides, Vinyl Ethers, Vinyl Esters

19. Sulfur Compounds (see also: II.E, III.C)

B. Ring Enlargement and Contraction

1. Enlargement

2. Contraction

C. Multi-Step Transformations

1. Masked-Carbonyl Systems

2. Other

VII. Other Completely Miscellaneous Reactions

VIII. Miscellaneous Reviews

Author Index

Details

No. of pages:
472
Language:
English
Copyright:
© Academic Press 1978
Published:
Imprint:
Academic Press
eBook ISBN:
9781483104003

About the Editor

R. Bryan Miller

L. G. Wade