Annual Reports in Inorganic and General Syntheses-1974

Preface

Simple and Complex Metal Hydrides of Main Groups I, II and III

Sodium Hydride

Beryllium Hydride

New Methods for Amorphous BeH2

Crystalline BeH2

Stabilization

Tertiary Amine Adducts of BeH2

Diethyleneglycoldimethylether Adduct of BeH2

Aluminum Hydride

Nonsolvated AlH3

Crystallized Phases of AlH3

Purification and Stabilization of AlH3

Tri(aluminumhydride)-trimethylamine (AIH3) :NMe3

Aluminum Chlorohydride

Hydridoaluminates

References

Boron

General

Novel Procedures

Inorganic Boron Derivatives

Metal-Boron Compounds

Organoboranes

Hydroboration

Carboranes

Boranes

Ring Systems

Four Coordinate Boron

BX3 Compounds

BX4- Compounds

References

Aluminum, Gallium, Indium and Thallium

Introduction

Synthetic Methods

Hydride Complexes

Activated Metals

Alkyl and Aryl Compounds

Perfluorophenyl Compounds

Organometallic

Reactions of Alkyl- or Arylmetal Halides

Alkane Elimination Reactions

Miscellaneous Complexes with O, N, S and P Ligands

Metal-Nitrogen Ring Systems

Halogen Bridged Compounds

Halide and Pseudohalide Complexes

Complexes with π Acid Ligands

Metal Carbonyl Complexes

Metal-Metal Bonded Compounds

References

Silicon Chemistry

General

Silicon-Hydrogen

Silicon-Group IV

Organometallic Reagents

SiCl/Li/THF and SiCl/Mg/HMPT

Hydrosilylation

Polysilanes

Silicon-Germanium

Silicon-Nitrogen

Silicon-Phosphorus

Silicon-Arsenic

Silicon-Oxygen

Silicon-Sulfur

Silicon-Selenium

Silicon-Group VII

Silicon-Transition Metal Bond

Molecular Rearrangements

References

Germanium, Tin, and Lead

General

MX4 Compounds

Metal-Carbon Bonded Compounds

Metal-Nitrogen Bonded Compounds

Metal-Oxygen and Metal-Sulfur Bonded Compounds

Metal-Halogen Bonded Compounds

Reactions of MX4 Compounds 57

Metal-Metal Bonded Compounds

Organometallic Compounds

Coordination Compounds with Ligands Containing Group IVA Elements

Coordination Compounds of Ge, Sn, Pb

Miscellaneous Compounds and Reactions

References

Phosphorus

Introduction

Elemental Phosphorus

Phosphides

Phosphoranes

Phosphines

Phosphorus-Boron Compounds

Phosphorus-Silicon Compounds

Phosphorus-Nitrogen Compounds

Cyclic Phosphazenes

Heterocyclic Phosphazenes

Linear Phosphazenes

Cyclic Phosphazanes and Rings with P-N Bonds

Linear Phosphazanes

Azides and Hydrazine Derivatives

Compounds with P-P Bonds

Phosphorus Compounds with Elements of the 6th Main Group

Phosphorus Sulfides and Selenides

Derivatives of Hypophosphorus Acid

Derivatives of Phosphorous and Phosphonic Acids

Orthophosphates and Derivatives of Orthophosphoric Acid

Diphosphates and Polyphosphates

Metaphosphates

Phosphorus - Halogen Compounds

Complexes with Phosphorus Ligands

References

Arsenic, Antimony and Bismuth

Reviews

Arsenic

Arsenic (III)

Arsenic Bound to Carbon

Cyclic Compounds

Arsenic Compounds Containing Boron

Compounds with As-Si Bonds

Compounds with As-N or As-P Bonds

Compounds Containing As-0 or As-S Bonds

Compounds Containing As-Hg Bonds

Miscellaneous

Arsenic (V)

Antimony

Antimony (III)

Antimony (V)

Bismuth

Arsenic, Antimony and Bismuth as Acceptors

As, Sb, Bi (III) Acceptors

As, Sb, Bi (V) Acceptors

References

Chalcogens

Oxygen

Sulfur

Polysulfur Compounds

Sulfur Halides

Sulfur-Nitrogen Compounds

Miscellaneous

Selenium

Tellurium

References

Halogens and Pseudohalogens

Halogens

Interhalogen Compounds and Ions

Oxides and Oxo Compounds

Fluorine

Bromine

Iodine

Pseudohalogen Compounds of Main Group Elements

Group II

Group III

Group IV

Group V

Group VI

Pseudohalo Complexes of Transition Metals

Titanium, Zirconium, Hafnium

Niobium and Tantalum

Chromium, Molybdenum, Tungsten

Manganese and Rhenium

Iron and Ruthenium

Cobalt, Rhodium, Iridium

Nickel, Palladium, Platinum

Copper and Silver

References

Scandium, Yttrium, Lanthanides and Actinides

Scandium

Yttrium and Lanthanides

Actinides

References

Titanium, Zirconium, and Hafnium

General

Group VI Compounds

Simple Compounds with Bonds to O, S, Se

Complexes with O-Donors

Complexes with O- and N-Donors

Complexes with S-, Se- and Te-Donors

Group V Compounds

Nitrides and Amides

Complexes

Group IV Compounds

Group III Compounds

Hydrides

References

Vanadium, Niobium and Tantalum

General

Vanadium

Oxides, Hydroxides, and Oxygen-Containing Compounds

Halogen Containing Compounds

Refractory and Related Compounds

Coordination Compounds

Niobium and Tantalum

General

Oxides and Oxygen Containing Phases

Halides and Halogen Containing Compounds

Refractory and Related Compounds

Coordination Compounds

References

Chromium, Molybdenum and Tungsten

General

Chromium

Oxides and Hydroxides

Chromates and Chromites

Halogen-Containing Compounds of Chromium

Refractory and Related Compounds

Miscellaneous

Molybdenum

Oxides and Their Hydrates

Simple Molybdates

Isopoly Compounds

Heteropoly Compounds

Thiomolybdates and Chalcogenides

Halogen-Containing Compounds

Miscellaneous

Tungsten

Oxides

Tungsten Bronzes and Simple Tungstates

Isopoly and Heteropoly Tungstates

Halogen-Containing Compounds

Miscellaneous

References

Manganese, Technetium and Rhenium

General

Manganese

Lower Oxidation States

Manganese (II)

Higher Oxidation States

Technetium

Radiopharmaceuticals

Other Complexes

Rhenium

Rhenium (I)

Rhenium (II)

Rhenium (III)

Rhenium (IV)

Rhenium (V)

Rhenium (VI)

Rhenium (VII)

References

Iron

General

Compounds with Carbon Donors

Compounds with Nitrogen Donors

Compounds with Oxygen Donors

Compounds with Sulfur Donors

Compounds with Halogen Donors

Miscellaneous

References

Cobalt and Nickel

General

Low-Valent Cobalt Complexes

Carbonyls

Phosphine and Phosphite Complexes

Other Complexes

Low-Valent Nickel Complexes

Carbonyls

Phosphine and Phosphite Complexes

Cobalt(II) and Nickel(II) Complexes

Complexes with Heavy Donor Atoms

Binuclear and Oligonuclear Complexes

Oxidative and Reductive Syntheses

Cobalt(III) Complexes

Syntheses in Non-Aqueous Solvents

Syntheses from Carbonato, Sulphito, and Nitro Intermediates

Binuclear and Polynuclear Complexes

Complexes with Heavy Donor Atoms

Complexes of Polydentate Ligands

Modification of Coordinated Ligands

Separation and Resolution

Higher Oxidation States

Cobalt (IV)

References

The Platinum Metals. Part I: Ruthenium, Osmium, Rhodium and Iridium

Introduction

Group VII Donors

Group VI Donors

Oxygen Donors

Sulfur Donors

Group V Donors

Nitrogen Donors

Phosphorus, Arsenic and Antimony Donors

Group IV Donors

Carbon Dioxide and Carbonyl Complexes

Olefin Complexes

Alkynes

π-Allyl and π-Cyclopentadiene Complexes

Iso-Nitrile and Carbenoid Complexes

Metalation Reactions and Metal-Carbon Bonds

References

The Platinum Metals. Part II: Palladium and Platinum

Introduction

Group VII Donors

Group VI Donors

Oxygen Donors

Sulfur Donors

Group V Donors

Nitrogen Donors

Phosphorus, Arsenic and Antimony Donors

Group IV Donors

Carbonyl Complexes

Mono- and Di-Olefin Complexes

π-Allyl Complexes

Acetylene Complexes

Isocyanide and Carbenoid Complexes

Ylides

Alkyl, Aryl and Related Complexes

Heterometallic Complexes

References

Copper

General

Copper(I) Compounds

Copper(II) Compounds

Dimeric and Polymeric Compounds

References

Silver and Gold

Introduction

Compounds Containing (Ag,Au)-C Bonds

Alkyl, Aryl, and Related Groups

Isocyanide, Carbene, and Related Complexes

Phosphines and Related Ligands

Simple Salts and Other Complexes

Simple Salts

Nitrogen Donors

Chalcogen Donors

Miscellaneous Compounds

References

Zinc, Cadmium and Mercury

General Inorganic Compounds

Complex and Coordination Compounds

Organometallic Compounds

Organo-Cadmium and Zinc

Organomercury

Compounds with Metal-Metal Bonds

Group IV Metals

Other Groups

References

Photochemical Syntheses of Inorganic Compounds

Introduction

The Literature

Experimental Techniques

Photochemical Reactions and Syntheses

Lithium

Group IIIA Elements

Group IVA Elements

Group VA Elements

Group VIA Elements

Group VIIA Elements

Group VIB Elements

Group VIIB Elements

Iron, Ruthenium and Osmium

Cobalt, Rhodium and Iridium

Nickel, Palladium and Platinum

Miscellaneous

Concluding Remarks

References

Index

Actinides

Aluminum

Antimony

Arsenic

Bismuth

Boron

Cadmium

Chalcogens

Chromium

Cobalt

Copper

Gallium

Germanium

Gold

Hafnium

Halogens

Hydrides

Indium

Iron

Lanthanides

Lead

Manganese

Mercury

Molybdenum

Nickel

Palladium

Platinum

Platinum Metals

Phosphorus

Pseudohalogen Compounds

Rhenium

Silicon

Silver

Tantalum

Technetium

Thallium

Tin

Titanium

Tungsten

Vanadium

Zinc

Zirconium