Annual Reports in Inorganic and General Syntheses-1973

Annual Reports in Inorganic and General Syntheses-1973

1st Edition - January 1, 1974

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  • Editors: Kurt Niedenzu, Hans Zimmer
  • eBook ISBN: 9781483213880

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Description

Annual Reports in Inorganic and General Syntheses-1973 presents an organized annual summary of synthetic developments in inorganic chemistry and its related areas. The book covers the synthetic aspects and structural or mechanistic features of elements, including the main group hydrides, alkali and alkaline earth elements, boron, aluminium, gallium, indium, thallium, silicon, germanium, tin, and lead, nitrogen, phosphorus, arsenic, antimony, bismuth, chalcogens, halogens and pseudohalogens, and noble gases. The text also discusses the synthetic aspects and structural or mechanistic features of elements of yttrium, scandium, lanthanides, and actinides, titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, technetium, rhenium, iron, cobalt, and nickel. The chemistry of ruthenium, osmium, rhodium, iridium, palladium, platinum, copper, silver, gold, zinc, cadmium, and mercury is also encompassed. The book concludes by describing the synthesis and structures of metalloporphyrins. Chemists, chemistry students, and people working in chemical laboratories will find the book invaluable.

Table of Contents


  • Preface

    Main Group Hydrides, Alkali and Alkaline Earth Elements

    Simple Hydrides

    Complex Hydrides

    Alkali and Alkaline Earth Elements

    General

    Oxides

    Alkoxides

    Oxygen-Bonded Chelates

    Other Salts and Complexes of Oxy Compounds

    Sulfur-Containing Compounds

    Compounds with Group V Elements

    Organometallic Compounds

    References

    Boron

    General

    Novel Procedures

    Inorganic Boron Derivatives

    Metal-Boron Compounds

    Organoboranes

    Hydroboration

    Carboranes

    Boranes

    Ring Systems

    Four-Coordinate Boron

    BX3 Complexes

    BX4 Complexes

    References

    Aluminum, Gallium, Indium and Thallium

    Introduction

    Synthetic Methods

    Hydride Complexes

    Hydrogen-Bridged Transition Metal Compounds

    Reactions of Organometallic Compounds

    Insertion Reactions

    Exchange Reagents

    Cyclization Reactions

    Alkane Elimination Reactions

    Organohalides and Pseudo Halides

    Cyclopentadienyls and Related Complexes

    Complexes with O, N, S and P Ligands

    Donor-Acceptor Interactions with Metal Carbonyl and Metal Dinitrogen Complexes

    Metal-Metal Bonded Compounds

    Homonuclear Group III

    Group Ill-Main Group

    Group Ill-Transition Metal

    Complexes in Catalytic Systems

    Miscellaneous

    Halide and Addition Compounds

    Lower Oxidation States

    References

    Silicon

    General

    Silicon-Hydrogen

    Silicon-Halogen

    Silicon-Nonmetal

    Silicon-Oxygen

    Silicon-Nitrogen

    Silicon-Sulfur

    Silicon-Carbon

    Silicon-Metal

    Silicon-Silicon

    Silicon Containing Complexes

    References

    Germanium, Tin and Lead

    General

    MR4 Compounds

    Metal-Carbon Bonded Compounds

    Metal-Nitrogen Bonded Compounds

    Metal-Oxygen Bonded Compounds

    Metal-Halogen Bonded Compounds

    Compounds with More Than One Group IVa Metal Atom

    Reactions of MR4 Compounds

    Metal-Metal Bonded Compounds

    Organometallic Compounds

    Coordination Compounds

    Coordination Compounds of Ge, Sn, Pb

    Miscellaneous Compounds and Reactions

    References

    Nitrogen

    Compounds with no N-N Bonds

    Compounds with one N-N Bond

    Hydrazine Derivatives

    Azo and Diazo Compounds

    Nitrosamine and Nitramide Derivatives

    Compounds with Three or More Linked Nitrogens

    References

    Phosphorus

    Introduction

    Phosphides

    Phosphorus-Boron Compounds

    Phosphorus-Carbon Compounds

    Phosphorus-Si, Ge, Sn compounds

    Phosphorus-Nitrogen Compounds

    Cyclic Phosphazenes

    Heterocyclic Phosphazenes

    Linear Phosphazenes

    Cyclic Phosphazanes and Rings with P-N Bonds

    Amides and Amines of Phosphorus

    Imides and Imines

    Hydrazine Derivatives

    Compounds with P-P Bonds

    Compounds of Phosphorus with Elements of Group VIA

    Phosphorus Oxides, Sulfides and Selenides

    Derivatives of Hypophosphoric Acid

    Derivatives of Hypodiphosphorous Acid

    Derivatives of Phosphorous Acid

    Hypodiphosphoric Acid

    Orthophosphates

    Derivatives of Orthophosphoric Acid

    Diphosphoric Acid

    Metaphosphates

    Halogenophosphoric Acids-Polyphosphates

    Spirocompounds

    Complexes with Phosphorus Ligands

    Phosphorus-Halogen Compounds

    Pure Phosphorus-Halogen Compounds

    Phosphorus-Chalcogen Halogenides

    Phosphorus-Halogen Compounds with Amino and Ester Groups

    Cage Compounds

    Radicals

    References

    Arsenic, Antimony and Bismuth

    Reviews

    Arsenic

    Tertiary Arsines

    Heteroatom-Arsenic Species

    Cyclic Compounds

    Acids, Esters, and Alcohols

    Arsenic (V) Compounds

    Antimony

    Antimony (III) as an Acceptor

    Antimony (III) as a Donor

    General (Tertiary Antimony)

    Antimony(V), General

    Antimony(V) as an Acceptor

    Bismuth

    Bismuth(III)

    Bismuth(V)

    References

    Chalcogens

    Oxygen

    Sulfur

    Polysulfur Compounds

    Sulfur(II) Compounds

    Cyclic Sulfur-Nitrogen Compounds

    Sulfur(IV) Compounds

    Sulfur(VI) Compounds

    Selenium

    Tellurium

    References

    Halogens and Pseudohalogens

    Halogens

    Interhalogen Ions

    Oxides and Oxo Cations

    Halogen Derivatives of Pentafluoroorthoselenic and Telluric Acids

    Fluorine

    Bromine

    Iodine

    Pseudohalogen Compounds of Main Group Elements

    Complexes of Gallium and Indium

    Compounds with Elements of Group V

    Compounds with Elements of Group VI

    Pseudohalo Complexes of Transition Metals

    Hafnium and Zirconium

    Chronium, Molybdenum, and Tungsten

    Manganese, Technetium, and Thenium

    Iron and Osmium

    Cobalt, Rhodium, and Iridium

    Nickel, Palladium, and Platinum

    Copper, Silver, and Gold

    Zinc, Cadmium, and Mercury

    Pseudohalo Complexes of Inner Transition Metals

    References

    Noble Gases

    Krypton

    Xenon

    Radon

    References

    Yttrium, Scandium, Lanthanides and Actinides

    The Elements

    New Method of Purification

    Lanthanide Ions as Reducing Agents

    Phase Relationships

    High Pressure synthesis

    Borides

    Fluorides

    Lanthanide Nitrates

    Double Oxides

    Carbides

    Mixed Carbides

    Isocyanate and Isothiocyanates

    Carboxylates

    Thiophosphates

    Alkoxides

    Fluorinated Acetonylpyrazolides

    Carbonyls

    References

    Titanium, Zirconium and Hafnium

    Bromides

    Alkoxides

    Cyclooctatetraenes

    Alkoxy Halo Complexes

    Oxotitanium Complexes

    Silylmethyl and Related Complexes

    Complexes Containing Methylbenzene

    Direct Synthesis

    Synthesis by Ligand Exchange

    β-DiKetonate Complexes

    Cyclopentadienyl Compounds

    Zirconium Hydrocarbyls

    Ferrocenyl Titanium

    References

    Vanadium, Niobium, Tantalum

    Vanadium

    Halides, Oxohalides, and Adducts

    Bronzes and Vanadites

    Oxides and Vanadates

    Other Simple Compounds

    Coordination Compounds

    Niobium and Tantalum

    General

    Halides, Oxohalides, and Adducts

    Oxides, Niobates, Tantalates, and Other Oxide Phases

    Other Simple Compounds

    Coordination Compounds

    References

    Chromium, Molybdenum, and Tungsten

    General

    Chromium

    Oxides and Hydroxides

    Chromâtes and Chromites

    Halogen-Containing Compounds of Chromium

    Refractory and Related Compounds

    Miscellaneous

    Molybdenum

    Oxides and Their Hydrates

    Simple Molybdates

    Isopoly Compounds

    Heteropoly Compounds

    Thiomolybdates and Chalcogenides

    Halogen-Containing Compounds

    Miscellaneous

    Tungsten

    Oxides

    Tungsten Bronzes and Simple Tungstates

    Isopoly and Heteropoly Tungstates

    Halogen-Containing Compounds

    Miscellaneous Compounds

    References

    Manganese, Technetium and Rhenium

    General

    Manganese

    Lower Oxidation States

    Manganese(II)

    Higher Oxidation States

    Technetium

    Rhenium

    Rhenium(I)

    Rhenium(II)

    Rhenium(III)

    Rhenium(IV)

    Rhenium(V)

    Rhenium(VI)

    Rhenium(VII)

    References

    Iron

    General

    Compounds with Carbon Donors

    Compounds with Nitrogen Donors

    Compounds with Oxygen Donors

    Compounds with Sulfur Donors

    Compounds with Halogen Donors

    Miscellaneous

    References

    Cobalt and Nickel

    General

    Low Oxidation States - Cobalt(-I), Cobalt(O), and Cobalt(I)

    Carbonyls

    Phosphine Complexes

    Nitrosyls

    Other Low-Valent Cobalt Complexes

    Low-Valent Nickel Complexes

    Carbonyls

    Phosphine Complexes

    Nitrosyls

    Other Low-Valent Nickel Complexes

    Cobalt(II) and Nickel(II) Complexes

    Complexes with Heavy Donor Atoms

    Dimeric and Oligomeric Complexes

    Complexes of Macrocyclic Ligands

    Oxidative and Reductive Syntheses

    Cobalt(III) Complexes

    Synthesis by Displacement of Labile Ligands

    Binuclear and Oligonuclear Complexes

    Unusual Monomeric Cobalt(lll) Complexes

    Separation of Cobalt(III) Complexes

    Higher Oxidation States

    Nickel(III)

    Cobalt(V)

    References

    The Platinum Metals. Part I: Ruthenium, Osmium, Rhodium and Iridium

    Introduction

    The Chemistry of Ruthenium and Osmium

    Group VII Donors

    Group VI Donors

    Group V Donors

    Group IV Donors

    Metallation Reactions

    The Chemistry of Rhodium and Iridium

    Group VII Donors

    Group VI Donors

    Group V Donors

    Group IV Donors

    Metallation Reactions and Complexes Containing Metal-Carbon σ-Bonds

    References

    The Platinum Metals. Part II: Palladium and Platinum

    Introduction

    Group VII Donors

    Group VI Donors

    Group V Donors

    Group IV Donors

    Metallation Reactions and Complexes Containing Metal-Carbon σ-Bonds

    References

    Copper

    General

    Copper(I) Compounds

    Copper(II)

    Copper(II) - Dimers and Polymers

    Miscellaneous

    References

    Silver and GOld

    General

    Compounds Containing (Ag,Au)-C Bonds

    Alkyl, Aryl, and Related Groups

    Isocyanide and Carbene Complexes

    Other Compounds

    Simple Salts and Other Complexes

    Simple Salts

    Nitrogen Donors

    Chalcogen Donors

    Miscellaneous Compounds

    References

    Zinc, Cadmium and Mercury

    General Inorganic Compounds

    Complex and Coordination Compounds

    Organometallic Compounds

    Organoadmium

    Organomercury

    Organozinc

    Compounds with Metal-Metal Bonds

    References

    Metalloporphyrin Synthesis

    Some Common Metalloporphyrins

    Methods of Metalloporphyrin Synthesis

    Group I A

    Group II A

    Group III A

    Group IV A

    Group V A

    Groups IIIB, IV B, V B

    Group VI B

    Group VII B

    Iron

    Cobalt

    Ruthenium, Rhodium, Iridium, Osmium

    Nickel, Palladium, Platinum

    Group I B

    Group II B

    References




Product details

  • No. of pages: 332
  • Language: English
  • Copyright: © Academic Press 1974
  • Published: January 1, 1974
  • Imprint: Academic Press
  • eBook ISBN: 9781483213880

About the Editors

Kurt Niedenzu

Hans Zimmer

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