Analytical Sample Preparation With Nano- and Other High-Performance Materials

1st Edition - October 22, 2021
Editors: Rafael Lucena, M. Soledad Cárdenas Aranzana
Language: English
Paperback ISBN:
9 7 8 - 0 - 1 2 - 8 2 2 1 3 9 - 6
eBook ISBN:
9 7 8 - 0 - 1 2 - 8 2 2 1 7 2 - 3

Analytical Sample Preparation With Nano- and Other High-Performance Materials covers advanced sample treatment techniques and the new materials that can be used to boost their per… Read more

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Analytical Sample Preparation With Nano- and Other High-Performance Materials covers advanced sample treatment techniques and the new materials that can be used to boost their performance. The evolution of sample treatment over the last two decades has resulted in the development of new techniques and application of new materials. This is a must-have resource for those studying advanced analytical techniques and the role of high-performance materials in analytical chemistry. The book explains the underlying principles needed to properly understand sample preparation, and also examines the latest materials - including nanomaterials - that result in greater sensitivity and specificity.

The book begins with a section devoted to all the various sample preparation techniques and then continues with sections on high-performance sorbents and high-performance solvents.

Cover image
Title page
Table of Contents
Copyright
List of contributors
Preface by Rafael Lucena
Preface by Elefteria Psillakis
1. Analytical sample treatment: basics and trends
Abstract
1.1 Introduction to analytical sample preparation
1.2 Fundament and classification
1.3 Main trends in the field
Acknowledgments
References
2. Miniaturized solid-phase extraction
Abstract
2.1 Introduction
2.2 Confined micro-solid phase extraction
2.3 Dispersive micro-solid phase extraction
2.4 Conclusions
Acknowledgments
References
3. Solid-phase microextraction
Abstract
3.1 Introduction
3.2 In-fiber and in-tube solid-phase microextraction
3.3 Thin-film microextraction
3.4 Stir-assisted solid-phase microextraction
3.5 Conclusions
Acknowledgments
References
4. Unconfined liquid-phase microextraction
Abstract
4.1 Introduction
4.2 Single-drop microextraction
4.3 Dispersive-based liquid-phase microextraction
4.4 Conclusion
Acknowledgments
References
5. Analytical microextraction with supported liquid membranes
Abstract
5.1 Introduction
5.2 Two-phase hollow-fiber liquid-phase microextraction
5.3 Three-phase hollow-fiber liquid-phase microextraction
5.4 96-Well liquid-phase microextraction
5.5 Solvent bar microextraction
5.6 Electromembrane extraction
5.7 Outlook
References
6. Solid–liquid extraction techniques
Abstract
6.1 Introduction
6.2 General aspects on SLE
6.3 Classical SLE processes
6.4 Superheated solvent extraction
6.5 Ultrasound-assisted extraction
6.6 Microwaves-assisted extraction
6.7 Comparison and applicability of SHSE, USAE, and MAE
6.8 Conclusions
References
7. Microextraction-based samplers for liquid and tissue analysis
Abstract
7.1 Introduction
7.2 Microextraction devices for convenient integration of sampling and extraction for liquid and tissues
7.3 Applications
7.4 Conclusion
List of Abbreviations
References
8. Direct coupling of microextraction with instrumental techniques
Abstract
8.1 Introduction
8.2 Coupling of microextraction with spectroscopic techniques
8.3 Coupling of microextraction with mass spectrometry
8.4 Overview of interfaces based on flow analysis, microfluidics, and 3D printing
8.5 Conclusion
Acknowledgments
References
9. Membrane sorptive phases
Abstract
9.1 Introduction
9.2 Polymeric membranes
9.3 Fabric phases
9.4 Paper-based sorptive phases
9.5 Conclusions
Acknowledgments
References
10. Selectivity-enhanced sorbents
Abstract
10.1 Introduction
10.2 Molecularly imprinted polymers
10.3 Restricted access materials
10.4 Selective biosorbents
10.5 Conclusions
Acknowledgments
References
11. Carbon nanoparticles
Abstract
11.1 Introduction
11.2 Carbon-based nanomaterials in sample preparation
11.3 Conclusions
Acknowledgments
References
12. Metal and metal oxide nanomaterials in sample preparation
Abstract
12.1 Introduction
12.2 MNs in sample preparation
12.3 MONs in sample preparation
12.4 Application of MONs in sample preparation
12.5 Conclusions
References
13. Reticular materials in sorbent-based extraction methods
Abstract
13.1 Introduction
13.2 Incorporation of reticular materials in analytical sample preparation methods
13.3 Concluding remarks
Acknowledgments
List of abbreviations
References
14. Polymeric nanocomposites
Abstract
14.1 Introduction
14.2 Magnetic polymeric nanocomposites
14.3 Carbon-based nanocomposites
14.4 Metal-based polymeric nanocomposites
14.5 Conclusions
Acknowledgments
List of abbreviations
References
15. Monolithic solids: synthesis and uses in microextraction techniques
Abstract
15.1 Introduction
15.2 Preparation of monolithic beds
15.3 Applications of monolithic materials in microextraction techniques
15.4 Conclusions and future perspectives
Acknowledgments
List of abbreviations
References
16. Ionic liquids
Abstract
16.1 Conventional ionic liquids
16.2 Magnetic ionic liquids
16.3 Polymeric ionic liquids
16.4 Conclusion
Acknowledgments
References
17. Switchable solvents
Abstract
17.1 Introduction
17.2 Applications of switchable solvents in sample preparation
17.3 Concluding remarks
Acknowledgments
References
18. Deep eutectic solvents in microextraction
Abstract
18.1 Introduction
18.2 Synthesis and physicochemical properties of DES
18.3 Classification and types of DES
18.4 Use of DES in microextraction
18.5 Factors affecting extraction efficiency with DES
18.6 Trends in DES-based microextractions
18.7 Conclusions and future perspectives
References
19. Supramolecular solvents in microextraction techniques
Abstract
19.1 Introduction
19.2 Supramolecular solvent formation
19.3 Supramolecular solvent properties relevant for microextraction
19.4 Microextraction formats
19.5 Concentration factors
19.6 Compatibility of supramolecular solvent with separation and detection techniques
19.7 Analytical applications
19.8 Conclusion
Acknowledgments
References
Index

Rafael Lucena

Prof. Dr. Rafael Lucena has been a professor of Analytical Chemistry since 2010. He has coauthored more than 100 scientific articles on different analytical aspects, with microextraction techniques being the core of his research. He co-edited a special volume in the journal Analytical and Bioanalytical Chemistry and an e-book on the topic. In addition, he is editing a blog (Microextraction Tech) focused on sample treatment techniques. Rafael has directed 8 Ph.D. theses and several master and degree theses. He is the secretary of the Research Institute of Fine Chemistry and Nanochemistry, an organization involving more than 125 researchers in different areas of chemistry. He has also been involved in organizing several meetings such as NANOUCO, a monographic conference on nanochemistry. He also acts as a reviewer in many journals and project evaluator for organizations such as Fondecyt (Chile). He is currently member of the editorial board of Molecules.

Affiliations and expertise

Associate Professor, Analytical Chemistry, University of Cordoba, Spain

M. Soledad Cárdenas Aranzana

Prof. Dr. M. Soledad Cárdenas Aranzana has been a full professor of Analytical Chemistry since 2009. Her research interests comprise microextraction techniques, including developing new approaches, synthesizing novel nanomaterials based on carbon, metallic nanoparticles and polymers. She has co-authored 202 scientific articles and contributed to 16 book chapters and an ebook (Microextraction Analytical Techniques, 2017, Bentham. She has presented 170 conference communications, co-supervised 16 doctoral theses, and participated in 7 contracts and 1 patent. She has acted as regular reviewer of the Spanish National Evaluation and Foresight Agency (ANEP) and external reviewer for the Portuguese Foundation of Science and Technology and the Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT, Argentina). She has also been member of the expert panel for the evaluation of researchers in various national programs. Currently, she is president of the A3 Committee (Chemistry) of the Spanish National Agency for Quality Assessment and Accreditation (ANECA)

Affiliations and expertise

Full Professor, Analytical Chemistry, University of Córdoba, Spain