Analytical Applications of 1,10-Phenanthroline and Related Compounds - 1st Edition - ISBN: 9780080128771, 9781483156569

Analytical Applications of 1,10-Phenanthroline and Related Compounds

1st Edition

International Series of Monographs in Analytical Chemistry

Authors: Alfred A. Schilt
Editors: R. Belcher H. Freiser
eBook ISBN: 9781483156569
Imprint: Pergamon
Published Date: 1st January 1969
Page Count: 202
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Analytical Applications of 1,10-Phenanthroline and Related Compounds, Volume 32 presents the significance of 1,10-phenanthroline in chemical analysis. This book discusses the varied other uses for 1,10-phenanthroline or of the distinctive advantages afforded by certain related compounds.
Organized into eight chapters, this volume begins with an overview of the planar structure of 1,10-phenanthroline. This text then examines the relative inertness of phenanthroline towards chemical reaction other than chelation or salt-formation, which is an essential asset in its analytical applications. Other chapters consider the coordination chemistry of phenanthroline and bipyridine in detail. This book discusses as well the metal ions chelated, the features of the chelates, and the influence of substituent groups or other changes in the ligands on the properties of the chelates. The final chapter examines the scientific and commercial uses for 1,10-phenanthroline and related compounds, which have increased in number and importance. This book is a valuable resource for analytical chemists.

Table of Contents


  1. Introduction Historical Perspective Terms and Nomenclature Properties of 1,10-Phenanthroline Properties of 2,2'-Bipyridine Related Compounds References
  2. Metal Chelates Group 1 Metals Group 2 Metals Group 3 Metals Group 5 Metals Group 6 Metals Group 7 Metals Group 8 Metals Stabilities of Metal Chelates Liabilities of Metal Chelates Spectral Characteristics Influence of Substituent Groups and Other Modifications Steric Effects Electronic Effects Miscellaneous Effects References
  3. Colorimetric Reagents Determination of Iron Use of 1,10-Phenanthroline Use of Bathophenanthroline Use of Bathophenanthrolinedisulfonic Acid Use of 4,7-Dihydroxy-1,10-Phenanthroline Use of Other Ferroin Reagents Applications Determination of Copper Use of Cuproine Use of Neocuproine Use of Bathocuproine Use of Other Cuproine Compounds Applications Simultaneous Determination of Copper and Iron Determination of Ruthenium Determination of Cobalt Determination of Nickel Determination of Palladium Determination of Silver Determination of Molybdenum Determination of Zinc and Cadmium Direct Determination of Cyanide Indirect Determination of Anions by Solvent Extraction Indirect Determination of Reductants Indirect Determination of Oxidants Miscellaneous Indirect Methods References
  4. Oxidation-Reduction Indicators Ferroin Formal Potentials Practical Titrations Substituted Ferroin Derivatives Nitroferroin Methyl Derivatives Sulfonated Derivatives Bipyridine and Terpyridine Analogs of Ferroin Other Metal Chelates of the Ferroin Type Ruthenium Osmium Vanadium Chromium, Cobal


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© Pergamon 1969
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About the Author

Alfred A. Schilt

About the Editor

R. Belcher

H. Freiser

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