Advances in Organometallic Chemistry

Advances in Organometallic Chemistry

1st Edition - April 19, 2022

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  • Editor: Pedro Pérez
  • eBook ISBN: 9780323990899
  • Hardcover ISBN: 9780323990882

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Description

Advances in Organometallic Chemistry, Volume 77, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, with this updated release including chapters on Organometallic-like reactivity of group 10 metal-heteroatom sigma bonds, Organometallic interactions between metal nanoparticles and carbon-based molecules: a surface reactivity rationale, Group VI Allenylidene Complexes, and more.

Key Features

  • Contains contributions from leading authorities in the field of organometallic chemistry
  • Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more
  • Informs and updates readers on the latest developments in the field
  • Carefully edited to provide easy-to-read material

Readership

Researchers involved in Organometallic Chemistry from a wide perspective, including synthetic protocols, mechanistic studies and practical applications and to those involved in the use of organometallic complexes in homogeneous catalysis

Table of Contents

  • Cover image
  • Title page
  • Table of Contents
  • Copyright
  • Contributors
  • Preface
  • Chapter One: Gold-catalyzed enantioselective cyclizations and cycloadditions
  • Abstract
  • 1: Introduction
  • 2: Initial approaches to enantioselective gold(I)-catalyzed transformations
  • 3: On the origins of enantioselectivity in gold(I)-catalyzed reactions
  • 4: New approaches to enantioselective gold(I) catalysis
  • 5: Enantioselective gold(III) catalysis
  • 6: Conclusions and outlook
  • Acknowledgments
  • References
  • Chapter Two: Organometallic interactions between metal nanoparticles and carbon-based molecules: A surface reactivity rationale
  • Abstract
  • 1: Introduction
  • 2: CC homo-coupling reactions
  • 3: CC cross-coupling reactions
  • 4: C-heteroatom cross-couplings
  • 5: Fischer–Tropsch reaction
  • 6: Conclusions and perspectives
  • Acknowledgments
  • References
  • Chapter Three: Iminophosphoranes (R3PNR′): From terminal to multidentate ligands in organometallic chemistry
  • Abstract
  • 1: Introduction
  • 2: Iminophosphoranes (R3PNR′) as ligands in coordination chemistry: Fundamentals
  • 3: Coordination of neutral iminophosphoranes (R3PNR′) as σ-donors or anionic iminato-phosphoranes (R3PN−) as bridging ligands
  • 4: Polydentated iminophosphorane ligands (R3PNR′) in coordination chemistry
  • 5: Conclusions
  • Acknowledgments
  • References
  • Chapter Four: Water-soluble transition-metal complexes with hydrophilic N-heterocyclic carbene ligands for aqueous-phase applications
  • Abstract
  • 1: Introduction
  • 2: Water-soluble metal NHC complexes
  • 3: Aqueous-phase chemistry
  • 4: Main applications
  • 5: Conclusions and outlook
  • Acknowledgments
  • References
  • Chapter Five: Organo-phosphanide and -phosphinidene complexes of Groups 8–11
  • Abstract
  • 1: Introduction
  • 2: Synthetic methods
  • 3: Dynamic processes
  • 4: Reactivity
  • 5: Catalytic aspects
  • 6: Concluding remarks
  • Acknowledgments
  • Appendix
  • References
  • Chapter Six: Advances in the synthesis and reactivity of group 6 metal allenyls
  • Abstract
  • 1: Introduction
  • 2: Group 6 metal allenyls from alkynyl Fischer carbene complexes and nucleophiles
  • 3: Group 6 metal allenyls from 1,3-metal migrations
  • 4: Group 6 metal allenyls from metal allenylidenes
  • 5: Thermal and photochemical reactivity of group 6 metal allenyls
  • 6: Concluding remarks
  • Acknowledgments
  • References

Product details

  • No. of pages: 378
  • Language: English
  • Copyright: © Academic Press 2022
  • Published: April 19, 2022
  • Imprint: Academic Press
  • eBook ISBN: 9780323990899
  • Hardcover ISBN: 9780323990882

About the Editor

Pedro Pérez

Pedro Pérez
Pedro J. Pérez (FRSC) graduated in 1991 under the supervision of Prof. Ernesto Carmona (Univ. Sevilla, Spain). As a Fulbright Scholar, he then joined Prof. Brookhart's group at UNC-Chapel Hill (USA). He started an appointment as Assistant Professor at the Universidad de Huelva (Spain) in 1993, where he has been promoted several times until the current position of Professor in Inorganic Chemistry (since 2005). His work is devoted to the development of organometallic complexes of late transition-metal as well as their use as catalysts for transformations involving hydrocarbons, including olefin modification, carbon-hydrogen bond functionalization, and click chemistry. He has been recognized by the RSC with the 2015 Homogeneous Catalysis Award, and by the RSEQ (Spain) with the 2007 Inorganic Chemistry Award and the 2016 Gold Medal Award. In 2014 he joined the National Academy of Sciences of Spain as Corresponding Member.

Affiliations and Expertise

Professor in Inorganic Chemistry, Homogeneous Catalysis Laboratory, Center for Research in Sustainable Chemistry, Universidad de Huelva, Huelva, Spain

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