Advances in Magnetic Resonance - 1st Edition - ISBN: 9780120255092, 9781483281551

Advances in Magnetic Resonance

1st Edition

Volume 9

Editors: John S. Waugh
eBook ISBN: 9781483281551
Imprint: Academic Press
Published Date: 28th January 1977
Page Count: 440
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Advances in Magnetic Resonance, Volume 9 describes the magnetic resonance in split constants and dipolar relaxation. This book discusses the temperature-dependent splitting constants in the ESR spectra of organic free radicals; temperature-dependent splittings in ion pairs; and magnetic resonance induced by electrons. The electron impact excitation of atoms and molecules; intramolecular dipolar relaxation in multi-spin systems; and dipolar cross-correlation problem are also elaborated. This text likewise covers the NMR studies of molecules oriented in thermotropic liquid crystals and diffusion coefficients of the molecules dissolved in liquid crystals. This publication is beneficial to students and researchers interested in split constants and dipolar relaxation.

Table of Contents


Contents of Previous Volumes

Temperature-Dependent Splitting Constants in the ESR Spectra of Organic Free Radicals

I. Introduction

II. Temperature-Dependent Splittings of Protons

III. Temperature-Dependent Splittings of Other Nuclei

IV. Temperature-Dependent Splittings in Ion Pairs

V. Conclusion

Magnetic Resonance Induced by Electrons: Studies of the Simplest Atomic and Molecular Systems

I. Introduction

II. Electron Impact Excitation: Atoms and Molecules

III. Magnetic Resonance Methods

IV. Detection

V. The Hamiltonian

VI. One-Electron Atoms

VII. The Helium Atom

VIII. Other Atoms

IX. The Hydrogen and Deuterium Molecules

X. The He2 Molecule

XI. Heavier Molecules

XII. Conclusion

Intramolecular Dipolar Relaxation in Multispin

I. Introduction

II. The Dipolar Cross-Correlation Problem

III. Mathematical Treatment of Multispin Relaxation

IV. The Dipolar Correlation Function

V. Relaxation Equations for Systems Composed of Two, Three, and Four Equivalent Nuclei

VI. Relaxation Equations for Systems Composed of Two, Three, and Four Nonequivalent Nuclei

VII. Hybrid Spin Systems

VIII. Other Multispin Systems

IX. Effects of Multispin Correlations in the Presence of Secondary Saturating Fields

X. Summary

Appendix A

Appendix Β

Summary of Notation

Note Added in Proof

NMR Studies of Molecules Oriented in Thermotropic Liquid Crystals

I. Introduction

II. Basic Theory

III. Experimental Details

IV. Spectral Analysis

V. Factors Limiting the Precision of the Derived Information

VI. Orientation of the Solute Molecules

VII. Shielding Anisotropics

VIII. Studies in a Smectic Phase

IX. Diffusion Coefficients of the Molecules Dissolved in Liquid Crystals

X. Intramolecular Motion

XI. Inorganic Complexes

XII. Compounds Studied and Information Derived

Appendix A: Compounds Investigated in Thermotropic Liquid Crystals and Reported Earlier

Appendix B: Liquid Crystal Solvents Used

Appendix C: Additional Literature

Subject Index


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© Academic Press 1977
Academic Press
eBook ISBN:

About the Editor

John S. Waugh

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