Advances in Magnetic Resonance - 1st Edition - ISBN: 9780120255061, 9781483281544

Advances in Magnetic Resonance

1st Edition

Volume 6

Editors: John S. Waugh
eBook ISBN: 9781483281544
Imprint: Academic Press
Published Date: 28th January 1973
Page Count: 324
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Advances in Magnetic Resonance, Volume 6 focuses on the theoretical and practical aspects of applying magnetic resonance methods to various problems in physical chemistry, emphasizing the different aspects of the exegesis of these problems. This book discusses the gas phase magnetic resonance of electronically excited molecules; techniques for observing excited electronic states; NMR studies in liquids at high pressure; and effect of pressure on self-diffusion in liquids. The nuclear magnetic resonance investigations of organic free radicals; measurement of proton coupling constants by NMR; and crystal point group symmetry and microscopic tensor properties in magnetic resonance spectroscopy are also elaborated. This text likewise deliberates the degeneracy of symmetry-related tensors; second and fourth moments in NQR spectroscopy for spins with I = 1; and fourth moment for equivalent nuclei with spins I = 1. This publication is valuable to physical chemists and students aiming to acquire knowledge on the application of magnetic resonance methods.

Table of Contents

Contributors Preface Contents of Previous Volumes Gas Phase Magnetic Resonance of Electronically Excited Molecules I. Introduction II. The Structural Problem III. Techniques for Observing Excited Electronic States IV. Observed Spectra NMR Studies in Liquids at High Pressure I. Introduction II. Experimental Techniques III. Effect of Pressure on Self-Diffusion in Liquids IV. Effect of Pressure on the Spin-Lattice Relaxation Times in Liquids V. Effect of Pressure on Chemical Shift VI. Conclusions Appendix: NMR Studies in Solids at High Pressure Nuclear Magnetic Resonance Investigations of Organic Free Radicals I. Introduction II. Relaxation Studies III. Measurement of Proton Coupling Constants by NMR IV. Deuterium NMR: Hyperfine and Quadrupole Coupling Constants V. Fluorine NMR: Fluorine Coupling Constants and Spin Densities VI. Alkali Metal NMR: Li-Cs Coupling Constants VII. Measurement of 13C Coupling Constants by NMR VIII. NMR Studies of Polyradicals IX. Conclusion Crystal Point Group Symmetry and Microscopic Tensor Properties in Magnetic Resonance Spectroscopy I. Tensor Properties of Microregions in Crystals II. Symmetry Related Tensors Ӯi III. Some Properties of Observable Tensor Projections Ӯ(η) IV. Degeneracy of Symmetry-Related Tensors V. Experimental Determination of Tensors Ӯi VI. Determination of Crystal Symmetry from Symmetry-Related Tensors Appendices Second and Fourth Moments in NQR Spectroscopy for Spins with I=1 I. Introduction II. Second Moments for Like Spins I=1 III. Contribution to the Second Moment for Spins I=1 from Unlike Spins IV. Fourth Moment for Equivalent Nuclei with Spins I=1 V. Examples Appendices Author Index Subject Index


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© Academic Press 1973
Academic Press
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About the Editor

John S. Waugh

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