Advances in Magnetic Resonance

Advances in Magnetic Resonance

Volume 4

1st Edition - January 28, 1970

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  • Editor: John S. Waugh
  • eBook ISBN: 9781483281513

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Description

Advances in Magnetic Resonance, Volume 4 deals with the relaxation, irradiation, and other dynamical effects that is specific to systems having resolved structure in their magnetic resonance spectra. This book discusses the anisotropic rotation of molecules in liquids by NMR quadrupolar relaxation; rotational diffusion constants; alternating linewidth effect; and theoretical formulations of the problem. The line shapes in high-resolution NMR; matrix representations of the equations of motion; matrix representations of the equations of motion; and intramolecular hydrogen bonds are also deliberated. This text likewise covers the nuclear spin relaxation by double resonance and methods of solution of the density matrix equations. This publication is valuable to physics and chemistry students, including those interested in magnetic resonance.

Table of Contents


  • Contributors

    Preface

    Contents of Previous Volumes

    The Study of Anisotropic Rotation of Molecules in Liquids by NMR Quadrupolar Relaxation

    I. Introduction

    II. Molecular Reorientation in Liquids

    III. The Rotational Diffusion Constants

    IV. Quadrupolar Relaxation and Rotational Diffusion

    V. Application of Quadrupolar Relaxation to the Study of Anisotropic Rotational Diffusion

    VI. Experimental Studies

    VII. Conclusion

    Appendix A

    Appendix B

    The Alternating Linewidth Effect

    I. Introduction

    II. The General Model

    III. Theoretical Formulations of the Problem

    IV. Applications

    V. Conclusion

    Appendix. A Computer Program Using the Modified Bloch Equations

    Addendum

    Line Shapes in High-Resolution NMR

    I. Introduction

    II. The Density Matrix. Equations of Motion

    III. Matrix Representations of the Equations of Motion

    IV. The Relaxation Matrix Γ

    V. Steady State Solutions of the Equations of Motion

    VI. The Slow Passage Spectrum

    VII. On the Selection of Basis for the Matrix Representations

    VIII. Incorporation of Chemical Exchange

    IX. Applications to a Two-Spin System

    X. Conclusion

    Appendix A

    Appendix B

    Analysis of Hydrogen Bonding and Related Association Equilibria by Nuclear Magnetic Resonance

    I. Introduction

    II. Analysis of Self-Association in Nonassociating Solvents

    III. Thermodynamic Parameters for Self-Association

    IV. Intramolecular Hydrogen Bonds

    V. Donor-Acceptor Interactions between Unlike Molecules

    VI. Contributions of NMR to Hydrogen Bonding Studies

    Nuclear Spin Relaxation by Double Resonance

    I. Introduction

    II. Density Matrix Theory of Double Resonance

    III. Methods of Solution of the Density Matrix Equations

    IV. Application to Specific Examples

    V. Conclusion

    Author Index

    Subject Index


Product details

  • No. of pages: 356
  • Language: English
  • Copyright: © Academic Press 1970
  • Published: January 28, 1970
  • Imprint: Academic Press
  • eBook ISBN: 9781483281513

About the Editor

John S. Waugh

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