Advances in High Temperature Chemistry V3

Advances in High Temperature Chemistry V3

1st Edition - January 1, 1971

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  • Editor: Leroy Eyring
  • eBook ISBN: 9780323156967

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Advances in High Temperature Chemistry, Volume 3 reviews and evaluates some techniques in high temperature chemistry. Comprised of six chapters, this volume first discusses the principles concerned with high temperature chemistry. After introducing short-range ordering in crystals, this book shows how to interpret liquid alloy activity measurements. It also covers various techniques such as photoionization mass spectroscopy, photoelectron spectroscopy, and microwave spectroscopy. This book ends with a discussion on oxahalides and other transition elements. Researchers and high temperature chemists will find this book useful.

Table of Contents

  • Contributors


    Contents of Previous Volumes

    Some Theoretical Significances of High Temperature Chemistry

    I. Some Pertinent Activities in High Temperature Chemistry

    II. Concepts and Definitions

    III. Probability Densities; Significance of ß = 0; High Temperature Physics

    IV. Discontinuities and Turning Points; High Temperature Chemistry


    Short-Range Ordering in Crystals

    I. Introduction

    II. Order Parameters

    III. The Measurement of Order Parameters

    IV. Ordering Energies and the Statistical Mechanics of Ordering

    V. The Short-Range Ordered State

    VI. Long-Range Periodicities and Superlattices

    VII. Applications to Nonmetals

    VIII. Outstanding Problems


    Interpreting Liquid Alloy Activity Measurements: A Changing Scientific Paradigm

    I. Introduction

    II. Thermodynamic Measurements on Liquid Alloys

    III. Some Solution Theories


    Photoionization Mass Spectrometry and Photoelectron Spectroscopy of High Temperature Vapors

    I. Introduction

    II. Historical Development

    III. Modern Photoionization Mass Spectrometry

    IV. Comparison of Electron and Photon Impact

    V. Interpretation of Threshold Behavior

    VI. Results of Recent Photoionization Studies of High Temperature Vapors

    VII. Photoelectron Spectroscopy of High Temperature Vapors

    VIII. Kinetic Studies—An Aside


    Microwave Spectroscopy of High Temperature Gases

    I. Introduction

    II. Experimental Techniques

    III. Results for Diatomic Molecules

    IV. Comparison of Experimentally Determined Molecular Parameters of Diatomics with ab Initio Results

    V. Results on Triatomic Molecules

    VI. Prospects for Future Research


    Gaseous Oxohalides, Hydroxides, and Complex Oxides of Group III and Transition Elements

    I. Introduction

    II. Metal Mono-oxohalides

    III. Metal Dioxohalides

    IV. Metal Trioxohalides

    V. Complex Binary Oxides : Mn Ox (n ≥ 2)

    VI. Conclusion


    Author Index

    Subject Index

Product details

  • No. of pages: 300
  • Language: English
  • Copyright: © Academic Press 1971
  • Published: January 1, 1971
  • Imprint: Academic Press
  • eBook ISBN: 9780323156967

About the Editor

Leroy Eyring

Affiliations and Expertise

Department of Chemistry and the Center for Solid State Science, Arizona State University, Tempe, Arizona, USA

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