Additions to C-X ?-Bonds - 1st Edition - ISBN: 9780080405926, 9780080912448

Additions to C-X ?-Bonds

1st Edition

1

Editors: Barry M. Trost
Hardcover ISBN: 9780080405926
eBook ISBN: 9780080912448
Imprint: Pergamon
Published Date: 20th January 1992
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Description

Nonstabilized Carbanion Equivalents. Carbanions of alkali and alkaline earth cations: (i) synthesis and structural characterization. Carbanions of alkali and alkaline earth cations: (ii) selectivity of carbonyl addition reactions. Organoaluminum reagents. Organocopper reagents. Organo-titanium and organo-zirconium reagents. Organochromium reagents. Organo-zinc, -cadmium and -mercury reagents. Organocerium reagents. Samarium and ytterbium reagents. Lewis acid carbonyl complexation. Lewis acid promoted addition reactions of organometallic compounds. Nucleophilic addition to imines and imine derivatives. Nucleophilic addition to carboxylic acid derivatives. Heteroatom-Stabilized Carbanion Equivalents. Nitrogen stabilization. Boron stabilization. Sulfur stabilization. The Benzoin and related reactions. Silicon stabilization. Selenium stabilization. Transformation of the Carbonyl Group into Nonhydroxylic Groups. Alkene synthesis. Epoxidation and related processes. Skeletal reorganizations: chain extension and ring expansion. Author index. Subject index.

Table of Contents

Nonstabilized Carbanion Equivalents. Carbanions of alkali and alkaline earth cations: (i) synthesis and structural characterization. Carbanions of alkali and alkaline earth cations: (ii) selectivity of carbonyl addition reactions. Organoaluminum reagents. Organocopper reagents. Organo-titanium and organo-zirconium reagents. Organochromium reagents. Organo-zinc, -cadmium and -mercury reagents. Organocerium reagents. Samarium and ytterbium reagents. Lewis acid carbonyl complexation. Lewis acid promoted addition reactions of organometallic compounds. Nucleophilic addition to imines and imine derivatives. Nucleophilic addition to carboxylic acid derivatives. Heteroatom-Stabilized Carbanion Equivalents. Nitrogen stabilization. Boron stabilization. Sulfur stabilization. The Benzoin and related reactions. Silicon stabilization. Selenium stabilization. Transformation of the Carbonyl Group into Nonhydroxylic Groups. Alkene synthesis. Epoxidation and related processes. Skeletal reorganizations: chain extension and ring expansion. Author index. Subject index.

Details

Language:
English
Copyright:
© Pergamon 1991
Published:
Imprint:
Pergamon
eBook ISBN:
9780080912448
Hardcover ISBN:
9780080405926

About the Editor

Barry M. Trost