Activation Of Small Inorganic Molecules - 1st Edition - ISBN: 9780124061019, 9780323150385

Activation Of Small Inorganic Molecules

1st Edition

Authors: M.M. Taqui Khan
eBook ISBN: 9780323150385
Imprint: Academic Press
Published Date: 28th January 1974
Page Count: 436
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Description

Homogeneous Catalysis by Metal Complexes, Volume I: Activation of Small Inorganic Molecules reviews and systematizes the chemistry of the metal ion activation of the small diatomic molecules. The book discusses the activation of molecular hydrogen, molecular oxygen, molecular nitrogen, carbon monoxide, and nitric oxide.

Table of Contents


Preface

Contents of Volume II

1 Activation of Molecular Hydrogen

I. Introduction

II. Structure and Reactivity in Metal Hydride Complexes

III. Activation of Hydrogen by Copper and Silver Ions

IV. Activation by Transition Metal Halides

V. Activation of Alkyl and Acyl Halides

VI. Activation of the Carbon-Hydrogen Bond by Platinum Group Metal Complexes

VII. Activation of Molecular Hydrogen by Pentacyanocobaltate (II)

VIII. Hydrogenation of π Complexes

References

2 Activation of Molecular Oxygen

I. Introduction

II. Reaction Types

III. Energy Requirements of Oxygen Reduction

IV. Non-Insertion Reactions Involving the Reduction of Oxygen to Hydrogen Peroxide

V. Non-Insertion Reactions Involving Complete Reduction of Oxygen to Water

VI. Non-Insertion Reactions of Hydrogen Peroxide

VII. Partial Insertion Reactions

VIII. Total Insertion Reactions

References

3 Activation of Molecular Nitrogen

I. Introduction

II. Activation by Microorganisms

III. Transition Metal Complexes of Molecular Nitrogen

IV. Fixation of Molecular Nitrogen by Metal Ions and Metal Complexes

V. Summary

References

4 Activation of Carbon Monoxide

I. Introduction

II. Carbon Monoxide Exchange Reactions

III. Carbon Monoxide Insertion Reactions

IV. Synthetic Applications of Carbonyl Insertion Reactions

V. Catalysis of Oxidation of Carbon Monoxide by Metal Ions and Metal Complexes

VI. Reactions of Coordinated Carbon Monoxide

References

5 Activation of Nitric Oxide

I. Introduction

II. Transition Metal Nitrosyls

III. Nitrosation of Organic Compounds

IV. Applications of Metal-Catalyzed Nitrosation Reactions

References

Appendix I Formulas, Bonding, and Formal Charges

Appendix II Glossary of Terms and Abbreviations

Author Index

Subject Index

Details

No. of pages:
436
Language:
English
Copyright:
© Academic Press 1974
Published:
Imprint:
Academic Press
eBook ISBN:
9780323150385

About the Author

M.M. Taqui Khan

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