Activation Of Alkenes And Alkynes

Activation Of Alkenes And Alkynes

1st Edition - January 28, 1974

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  • Author: M.M. Taqui Khan
  • eBook ISBN: 9780323160162

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Description

Homogeneous Catalysis by Metal Complexes, Volume II: Activation of Alkenes and Alkynes reviews and systematizes the chemistry of metal ion activation of alkenes and alkynes. The book presents the migration of ? bonds; the oxo reaction; and the hydrosilation of alkenes and alkynes. The text also covers topics on the oxidation of alkenes and alkynes, as well as the multiple insertion reactions of alkenes and alkynes.

Table of Contents


  • Preface

    Contents of Volume I

    1 Introduction

    2 Migration of π Bonds

    I. π-Bond Migration Catalyzed by Metal Carbonyls

    II. Metal Complex-Catalyzed π-Bond Migration

    3 The Oxo Reaction

    I. Introduction

    II. Reactions of Alkenes

    III. Hydroformylation of Alkynes

    IV. Hydrogenation under Oxo Conditions

    V. Applications of the Oxo Reaction

    4 Hydrosilation of Alkenes and Alkynes

    I. Catalysis by Platinum (II) and Rhodium (II)

    II. Catalysis of Hydrosilation by Metal Carbonyls

    5 Oxidation of Alkenes and Alkynes

    I. Oxidation of Alkenes

    II. Hydration of Alkynes

    III. Alkene or Alkyne Insertion into Metal-Carbon Bonds

    6 Multiple Insertion Reactions of Alkenes and Alkynes

    I. Introduction

    II. Polymerization of Ethylene and α-Olefins

    III. Polymerization of Dienes

    IV. Polymerization of Alkynes

    V. Oligomerization of Ethylene and α-Olefins

    VI. Oligomerization of Alkynes

    VII. Cyclic Oligomerization of Alkynes

    Bibliography

    Appendix I Formulas, Bonding, and Formal Charges

    Appendix II Glossary of Terms and Abbreviations

    Author Index

    Subject Index

Product details

  • No. of pages: 208
  • Language: English
  • Copyright: © Academic Press 1974
  • Published: January 28, 1974
  • Imprint: Academic Press
  • eBook ISBN: 9780323160162

About the Author

M.M. Taqui Khan

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