CORROSION OF GLASS, CERAMICS AND CERAMIC SUPERCONDUCTORS
Principles, Testing, Characterization and Applications To order this title, and for more information, click here
By David E. Clark, University of Florida, Gainesville, USA Bruce K. Haber, University of Florida, Gainesville, USA
Description This volume presents a compilation of state-of-the-art understanding of ceramic corrosion. It reveals areas of deficiency and it suggests
future directions based on the studies of 33 leaders in the field. Significant progress has been made in defining corrosion processes
in ceramic materials. New theoretical approaches and improved analytical techniques have served to unify concepts developed in earlier
corrosion studies.
Audience
Materials scientists in the ceramics industry, with focus on ceramic superconductors.
Contents Section 1. Theory, Testing and Characterization
1. Theory of Corrosion of Glass and Ceramics
Introduction
Chemical Mechanisms of Dissolution
and Corrosion
Kinetics
Surfaces
System Variables
Effects of Temperature
Summary and Conclusions
References
2. Predicting
Corrosion
Introduction
Prerequisites
Methodology
Applications and Discussion
Summary
References
3. Corrosion Testing and
Characterization
Introduction
Methodology
Laboratory Tests
Field Tests
Characterization of Corrosion
Data Analysis and Reduction
Summary
References
4. Characterization of Corroded Ceramics by SIMS
Introduction
Main Principles of Functioning Instrumentation
Experimental Aspects of SIMS
Secondary Ion Emission and Quantitation
Applications to Corrosion Layers on Glasses
Applications
to Impurities and Corrosion Products in Ceramic Superconductors
Summary
References
Section 2. Corrosion of Glass
5. Geochemical Approach
to Glass Dissolution
Introduction
Short Overview on Concepts of Glass Dissolution
The Rate Limiting Step in the Glass/Water Reaction
Kinetic Equations for Glass Matrix Dissolution
Geochemical Modeling of Glass Dissolution
Validation Process for the Model
Summary
References
6. Thermodynamic Approach to Glass Corrosion
Introduction
Kinetics Versus Thermodynamic Approach to Glass Durability
Thermodynamic and Structural Basis of Glass Hydration
Experimental Techniques
Glass Dissolution: A Function of Thermodynamic Equilibria
Glass Dissolution: A Function of Kinetic Test Parameters
Glass Dissolution: A Function of Environmental Conditions
Conclusions
References
Appendix A
7. Nuclear Waste Glasses: Corrosion Behavior and Field Tests
Introduction
Background-High Level Waste (HLW)
Advantages of Glass
Chemical Durability of Nuclear Waste Glass-Testing and Evaluation
Chemical Durability of Nuclear Waste Glass-Performance
Nuclear Waste Glass Structure and Corrosion Processes
In-Situ Testing and Performance of SRS Waste Glass
Summary
References
8.
The Chemical and Environmental Stability of Optical Glasses
Introduction
Optical Glasses
Summary
References
9. Surface Modification
of Bioactive Glasses and Ceramics
Introduction
Bioactivity
Five Types of Glass Surfaces
Kinetics of Silicate Glass Surface Reactions
Type III Glass Surfaces
Type IIIA Bioactive Glass and Ceramic Surfaces
Bonding Mechanisms of Bioactive Ceramics
Compositional
Effects on Bioactivity
Soft Tissue Bending
Effect of Composition on Interfacial Strength
Conclusions
References
10. Corrosion
of Heavy-Metal Fluoride Glasses
Introduction
Glass Preparation
Test Methods
Aqueous Corrosion Processes
Surface Condition
Formation of Hydroxyl Species
Coatings
Summary
References
11. Corrosion of Geological and Archaeological Glasses
Introduction
The Occurrence of Natural Glasses
Geologic Systems
General Alteration and Corrosion Concepts as Applied to Natural Glasses
Alteration
of Low Silica Glass
Alteration of High Silica Glass
Implications
Summary
References
12. Corrosion of Glazes and Enamels
Introduction
Corrosion Processes
Corrosion by Hydrofluoric Acid
Effect of Coating Composition
Tests for Corrosion Resistance
Lead and Cadmium
Release from Ceramic Coatings
Summary
References
13. Corrosion and Conservation of Ancient Glass and Ceramics
Introduction
Contributing
Factors
Case Studies in Corrosion
Treatments
Summary
References
Section 3. Corrosion of Ceramics
14. Corrosion of Glass-Ceramics
Introduction
Corrosion of a Model System
Summary
References
15. Corrosion of Ceramic Construction Materials in Acidic Environments
Introduction
Chemical and Physical Properties of Ceramic Materials
Acid Exposure Tests and Results
Summary
References
16. Degradation
of Ceramic Cutting Tools
Introduction
Brief History of Cutting Tool Materials
Degradation Mechanisms
Taylor's Tool Life Equation
Ceramic Cutting Tool Materials
Combating Degradation
The Future
References
17. Degradation of TZP Ceramics in Humid Atmospheres
Introduction
Zirconia Ceramics
Environment-Induced Phase Transformation
Effect of Environmental Factors on Phase Transformation
The Effect of Material Parameters on Phase Transformation
Effect of Aging on Material Properties
Proposed Methods to Avoid Phase
Transformation
Proposed Mechanism for Degradation
Summary
References
18. High Temperature Corrosion of Engineering Ceramics
Introduction
Test Methods
Thermodynamics of Corrosion
Kinetics of Corrosion
Microstructural and Mechanical Property Effects
Composites
Protective Coatings
Summary and Conclusions
References
Section 4. Corrosion of Ceramic Superconductors
19. Corrosion of Ceramic
Superconductors: An Overview
Introduction
Weathering in Moisture-Containing Environments
Decomposition upon Contact with Liquid
Water
Inherent Mechanism of Attack by Water: Ionic Mobility and Matrix Dissolution
Effects of Starting Materials
Acid/Base Aspects
of the Interaction of Ceramic Superconductors with Aqueous Environments
Oxidation/Reduction Aspects of the Interaction of Ceramic Superconductors
with Aqueous Environments
Effects of Presence of Moisture During Synthesis
Interaction of Superconducting Oxides with Nonaqueous
Solvents
Effects of Microstructure: Porosity and Grain Boundaries
Protection Against Environmental Attack
Summary
References
20. Role of Processing in the Corrosion of Ceramic Superconductors
Introduction
Reactivity with Water
Sample Preparation and Characterization
Effect of Particle Size on the Stability of YBa2Cu3O7-x in a Humid Environment
Effect of Sintering Temperature on the Stability of
YBa2Cu3O7-x in a Humid Environment
Proposed Model for the Role of Processing in the Corrosion of Ceramic Superconductors
References
21. Corrosion of YBa2Cu3O7-x in High and Low Humidity Environments
Introduction
YBa2Cu3O7-x in Liquid Water
Reaction of YBa2Cu3O7-x
in Saturated or High Humidity
Reaction of YBa2Cu3O7-x in Low Humidity
Summary
References
22. Surface Science Techniques for Analysis
of Corrosion of the Ceramic Superconductors
Introduction
X-Ray Photoelectron Spectroscopy
Application of XPS to 123 Compounds
Measurement of Surface Contamination Using XPS
Summary and Conclusions
References
23. Reducing Corrosion of Ceramic Superconductors
with Sol-Gel Coatings
Introduction
Moisture Degradation
Methods of Surface Passivation
Sol-Gel Coating of Powders
Experimental
Procedure
Characterization
Results and Discussion
Conclusions
References
24. Summary
Introduction
Zeta Potential and Its
Role in Glass Corrosion
Surface Passivation
Stress Corrosion
Glass and Ceramic Electrodes
Electrochemical Corrosion
References
Index
Bibliographic details
Hardbound, 698 pages, publication date: DEC-1992
ISBN-13: 978-0-8155-1283-7
ISBN-10: 0-8155-1283-X
Imprint: WILLIAM ANDREW
Price and Ordering
Price: GBP 141.99 USD 235 EUR 167.95
Books and book related electronic products are priced in US dollars (USD), euro (EUR), and Great Britain Pounds (GBP). USD prices apply to the Americas and Asia Pacific. EUR prices apply in Europe and the Middle East. GBP prices apply to the UK and all other countries.
Home | Elsevier Sites | Privacy Policy | Terms and Conditions | Feedback | Site Map | A Reed Elsevier Company